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林产化学与工业 ›› 2013, Vol. 33 ›› Issue (2): 144-150.doi: 10.3969/j.issn.0253-2417.2013.02.026

• 综述评论 • 上一篇    

松节油中主要单萜烯的异构方法综述

王婧1, 赵振东1,2, 毕良武1,2, 李冬梅1,2   

  1. 1. 中国林业科学研究院 林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省 生物质能源与材料重点实验室, 江苏 南京 210042;2. 中国林业科学研究院 林业新技术研究所, 北京 100091
  • 收稿日期:2012-12-03 修回日期:1900-01-01 出版日期:2013-04-30 发布日期:2013-04-30
  • 通讯作者: 赵振东,男,研究员,博士生导师,主要从事萜类化学、天然产物化学、应用化学等方面的研究与利用;E-mail:zdzhao@189.cn。

Review on Isomerization of the Major Monoterpenes in Turpentine

WANG Jing1, ZHAO Zhen-dong1,2, BI Liang-wu1,2, LI Dong-mei1,2   

  1. 1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;2. Institute of New Technology of Forestry, CAF, Beijing 100091, China
  • Received:2012-12-03 Revised:1900-01-01 Online:2013-04-30 Published:2013-04-30

摘要: 综述了比较常用的α-蒎烯、β-蒎烯以及3-蒈烯的异构方法。α-蒎烯、β-蒎烯以及3-蒈烯是松节油中含量较高的3种单萜烯烃,这3种单萜烯都可以在加热或者催化剂存在下,尤其是二者的共同作用下发生异构转化,生成苧烯、莰烯、月桂烯、对伞花烃等烯烃类化合物,可以作为原料或中间体而被进一步利用。

关键词: 松节油, α-蒎烯, β-蒎烯, 3-蒈烯, 异构方法

Abstract: It was reviewed according to the home and aboard literatures on the isomerization of main terpenes in turpentine, which are α-pinene, β-pinene and 3-carene. All these terpenes could be transformed by thermal energy or catalysis, especially the combined effect by both factors. They could give a complicated product which consisted of limonene, camphene, myrcene and p-cymene and so on. They would be used as materials or intermediates for further applications.

Key words: turpentine, α-pinene, β-pinene, 3-carene, isomerization

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