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林产化学与工业 ›› 2014, Vol. 34 ›› Issue (2): 51-55.doi: 10.3969/j.issn.0253-2417.2014.02.009

• 研究报告 • 上一篇    下一篇

枫香树脂对SIS型热熔胶增黏性能的研究

邢珍珍, 吴维茜, 曾韬   

  1. 南京林业大学 化学工程学院;江苏省生物质绿色燃料与化学品重点实验室, 江苏 南京 210037
  • 收稿日期:2013-05-28 出版日期:2014-04-25 发布日期:2014-04-26
  • 通讯作者: 曾韬,教授,博士生导师,从事林产化工教学和科研工作;E-mail:zengtao@njfu.edu.cn。 E-mail:zengtao@njfu.edu.cn
  • 作者简介:邢珍珍(1989-),女,江苏南京人,硕士生,主要从事林产精细化学品及胶黏剂研究;E-mail:njxzz19890210@163.com
  • 基金资助:
    林业公益性行业科研专项(200704033);江苏省高校优势学科建设工程项目资助(无编号)

Tackifying Effect of Sweetgum Resin in SIS Hot Melt Adhesive

XING Zhen-zhen, WU Wei-qian, ZENG Tao   

  1. College of Chemical Engineering, Nanjing Forestry University; Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing 210037, China
  • Received:2013-05-28 Online:2014-04-25 Published:2014-04-26

摘要: 研究了枫香树脂在苯乙烯-异戊二烯-苯乙烯三嵌段共聚物(SIS)型热熔胶(HMA)中的增黏应用,探讨了枫香树脂的用量、软化点以及与萜烯树脂的共混比例等因素,对HMA外观、初黏力、持黏力、软化点、剥离强度和玻璃化转变温度等性能的影响。结果表明,随着枫香树脂的用量的增加,HMA玻璃化转变温度提高,初黏力和180°剥离强度是先增大后减小,持黏力随之降低;中低软化点的枫香树脂的共混可以使HMA达到更好的黏接性能,不同种类树脂的共混也可以使HMA达到更好的黏接性能,在SIS-1105、环烷油4010、增黏树脂(m(92℃枫香树脂)与m(94℃萜烯树脂)2:1)与抗氧化剂质量分数比为38%:32%:30%:0.5%的条件下,HMA综合性能最佳,外观透明,无残胶现象,此时初黏力为14#,180°剥离强度>600 N/m,持黏力≥72 h。

关键词: 枫香树脂, SIS型热熔胶, 初黏力, 剥离强度, 持黏力

Abstract: This article introduced the tackifying effect of Chinese sweetgum resin in styrene-three block copolymer of styrene isoprene-(SIS) hot melt adhesive (HMA). At the same time, the influence of some factors including the content, softening point, and the mixture ratio with terpene resin produced on the appearance, tack, retained adhesion, softening point, peeling strength, and glass-transition temperature of hot melt adhesive were discussed. The results showed that with the increase of content of sweetgum resin, the glass-transition temperature became high, the tack and 180°peeling strength increased firstly and then decreased and the retained adhesion decreased. The mixture of sweetgum resin of low-middle temperature could make the bonding better, and blending of different kinds of resins can achieve better adhesion properties. Under the condition of m(SIS):m(naphthenic 4010):m(tackifying resin):m(antioxidants)=38%:32%:30%:0.5%,including m(92℃sweetgum resin):m(94℃terpene resin)=2:1, hot melt adhesive had transparent appearance with no residue phenomenon, and the comprehensive performance of hot melt adhesive is the best. At the condition, the tack is 14#, peeling strength is over 600 N/m, and retained adhesion is over 72 h.

Key words: sweetgum resin, SIS-hot melt sensitive adhesive, tack, peel strength, retained adhesion

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