含松香的聚苯乙烯/Fe3O4磁性微球的制备与表征

doi:10.3969/j.issn.0253-2417.2015.05.007

林产化学与工业 ›› 2015, Vol. 35 ›› Issue (5): 37-44.doi: 10.3969/j.issn.0253-2417.2015.05.007

含松香的聚苯乙烯/Fe₃O₄磁性微球的制备与表征

余彩莉¹, 任鹏¹, 王孝磊¹, 陈传伟¹, 张发爱²

1. 桂林理工大学化学与生物工程学院, 广西桂林 541004;
2. 桂林理工大学材料科学与工程学院, 广西桂林 541004

收稿日期:2014-08-30 出版日期:2015-10-25 发布日期:2015-10-24
通讯作者: 张发爱(1964—),男,甘肃武威人,教授,博士,博士生导师,从事聚合物纳米复合材料和天然产物化学研究;E-mail:zhangfaai@163.com E-mail:zhangfaai@163.com
作者简介:余彩莉(1965—),女,甘肃兰州人,教授,硕士生导师,从事天然产物化学研究
基金资助:
国家自然科学基金资助项目(31160148);广西自然科学基金重点项目(2012GXNSFDA053006)

Preparation and Characterization of Magnetic Polystyrene/Fe₃O₄ Microspheres with Rosin Moiety

YU Cai-li¹, REN Peng¹, WANG Xiao-lei¹, CHEN Chuan-wei¹, ZHANG Fa-ai²

1. College of Chemical and Biology Engineering, Guilin University of Technology, Guilin 541004, China;
2. College of Material Science and Engineering, Guilin University of Technology, Guilin 541004, China

Received:2014-08-30 Online:2015-10-25 Published:2015-10-24

摘要/Abstract

摘要： 以松香与甲基丙烯酸-2-羟乙酯反应得到酯化物(RH)为聚合单体,代替部分苯乙烯(St),二乙烯基苯(DVB)为交联剂,明胶作分散剂,偶氮二异丁腈为引发剂,采用悬浮聚合法在油酸改性Fe₃O₄的存在下制备了磁性聚合物微球,并研究了油酸改性Fe₃O₄的用量对微球性能的影响。采用红外光谱、热重分析、X射线衍射分析、光学显微镜、扫描电镜、透射电镜、X射线光电子能谱等方法对微球进行结构表征,通过磁性测量系统测试了微球的磁滞回线。结果表明:在单体配比m(RH):m(St):m(DVB)=1:1.5:0.4,引发剂和分散剂用量分别为单体总量的1%和6%,制备的含松香的磁性聚合物微球球形好、磁性强,微球具有顺磁性。当油酸改性Fe₃O₄的用量增大时,微球颗粒粒径逐渐增大,粒径分布变宽,饱和磁强度增大。

关键词: 松香, 磁性聚合物微球, 四氧化三铁, 悬浮聚合

Abstract: Rosin was reacted with 2-hydroxyethyl methacrylate and an ester (denoted as RH) was formed. Then polymerization was carried out in the presence of oleic acid-modified Fe₃O₄ magnetic fluid, with RH and styrene (St) as monomers, divinylbenzene (DVB) as cross-linking monomer, gelatin as dispersant, 2,2-azobisiso-butyronitrile (AIBN) as initiator. The magnetic polymer microspheres with rosin moiety were prepared by suspension polymerization and the effect of the magnetic fluid content on the magnetic polymer microspheres was investigated. The structures and properties of the magnetic polymer microspheres were characterized by Fourier transform-infrared spectroscopy, thermogravimetry, X-ray powder diffraction, optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectrometer. Hysteresis loops of the microspheres were tested by magnetic measuring system. The results indicated that at a monomer ratio of m(RH):m(St):m(DVB)=1:1.5:0.4, and the amounts of AIBN and gelatin about 1% and 6% of the total monomers, respectively, the products were spherical with high superparamagnetism. When the amount of oleic acid-modified Fe₃O₄ increased, the particle sizes of microspheres were gradually increased, the particle size distribution was broadened, and the saturation magnetic intensity increased.

Key words: rosin, magnetic polymer microspheres, ferroferric oxide, suspension polymerization

中图分类号:

TQ351.0

余彩莉, 任鹏, 王孝磊, 陈传伟, 张发爱. 含松香的聚苯乙烯/Fe₃O₄磁性微球的制备与表征[J]. 林产化学与工业, 2015, 35(5): 37-44.

YU Cai-li, REN Peng, WANG Xiao-lei, CHEN Chuan-wei, ZHANG Fa-ai. Preparation and Characterization of Magnetic Polystyrene/Fe₃O₄ Microspheres with Rosin Moiety[J]. Chemistry and Industry of Forest Products, 2015, 35(5): 37-44.

参考文献

[1] WANG Qiang,GUAN Yue-ping,LIU Xiang,et al.Micron-sized magnetic polymer microspheres for adsorption and separation of Cr(VI) from aqueous solution[J].Chinese Journal of Chemical Engineering,2012,20(1):105-110.
[2] DI Hong-wei,LUO Yan-ling,XU Feng,et al.Fabrication and caffeine release from Fe₃O₄/P(MAA-co-NVP) magnetic microspheres with controllable core-shell architecture[J].Journal of Biomaterials Science-Polymer Edition,2011,22(4/5/6):557-576.
[3] YAN Hong-yuan,CHENG Xiao-ling,SUN Ning.Synthesis of multi-core-shell magnetic molecularly imprinted microspheres for rapid recognition of dicofol in tea[J].Journal of Agricultural and Food Chemistry,2013,61(11):2896-2901.
[4] LIU Qing-quan,WANG Li,XIAO An-guo,et al.Templated preparation of porous magnetic microspheres and their application in removal of cationic dyes from wastewater[J].Journal of Hazardous Materials,2010,181(1/2/3):586-592.
[5] ZHANG Han,YANG Xin-ling.Magnetic polymer microsphere stabilized gold nanocolloids as a facilely recoverable catalyst[J].Chinese Journal of Polymer Science,2011,29(3):342-351.
[6] ZHANG Jing,YU De-mei,CHEN Wei,et al.Preparation of poly(styrene-glucidylmethacrylate)/ Fe₃O₄ composite microspheres with high magnetite contents[J].Journal of Magnetism and Magnetic Materials,2009,321(6):572-577.
[7] 张星,郑玉婴,玄泽亮,等.分散共聚法制备窄分布P(St-co-nBA)微球[J].高分子学报,2011(2):166-172. ZHANG Xing,ZHENG Yu-ying,XUAN Ze-liang,et al.Preparation of narrow-disperse poly(styrene-co-n-butyl acrylate) microspheres by dispersion copolymerization[J].Acta Polymerica Sinica,2011(2):166-172.
[8] ZHANG He-peng,ZHANG Qiu-yu,ZHANG Bao-liang,et al.Preparation of inner asymmetric composite microspheres[J].Polymer International,2012,61(6):990-993.
[9] DOU Jin-bo,ZHANG Qiu-yu,MA Ming-liang,et al.Fast fabrication of epoxy-functionalized magnetic polymer core-shell microspheres using glycidyl methacrylate as monomer via photo-initiated miniemulsion polymerization[J].Journal of Magnetism and Magnetic Materials,2012,324(19):3078-3082.
[10] WANG Peng,ZHAO Zhen-dong,BI Liang-wu,et al.Synthesis of mesoporous γ-Al₂O₃ using rosin-based quaternary ammonium salt as template agent[J].Chemistry and Industry of Forest Products,2012,32(2):87-91.
[11] 崔淑芹,王丹,商士斌,等.松香基水性聚氨酯丙烯酸酯复合乳液的研制[J].林产化学与工业,2012,32(3):61-65. CUI Shu-qin,WANG Dan,SHANG Shi-bin,et al.Study on synthesis of hybrid emulsion of rosin-based waterborne polyurethane-acrylate[J].Chemistry and Industry of Forest Products,2012,32(3):61-65.
[12] YEBRA D M,KIIL S,DAM K,et al.Reaction rate estimation of controlled-release antifouling paint binders:Rosin-based systems[J].Progress in Organic Coatings,2005,53(4):256-275.
[13] MA Guo-zhang,ZHANG Tong,WU Jian-bing,et al.Preparation and properties of glycerin ester of tung oil modified rosin[J].Journal of Applied Polymer Science,2013,130(3):1700-1706.
[14] AHN B K,SUNG J,KIM N,et al.UV-curable pressure-sensitive adhesives derived from functionalized soybean oils and rosin ester[J].Polymer International,2013,62(9):1293-1301.
[15] WILBON P A,CHU F,TANG C.Progress in renewable polymers from natural terpenes,terpenoids,and rosin[J].Macromolecular Rapid Communications,2013,34(1):8-37.
[16] YU Cai-li,WANG Xiao-lei,CHEN Chuan-wei,et al.Porogen on the rosin-based porous polymer microspheres and adsorptions for phenol solution[J].Journal of Bio-based Materials and Bio-energy,2014,8(1):59-68.
[17] YU Cai-li,CHEN Chuan-wei,GONG Qin-hai,et al.Preparation of polymer microspheres with a rosin moiety from rosin ester,styrene,and divinylbenzene[J].Polymer International,2012,61(11):1619-1626.
[18] MA Qiang-qiang,LIU Xiao-qing,ZHANG Ruo-yu,et al.Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil:The role of rosin acid derivatives[J].Green Chemistry,2013,15(5):1300-1310.
[19] 林广沅,吴国民,孔振武.表面活性剂对有机硅包覆松香基环氧树脂微胶囊的影响[J].林产化学与工业,2014,34(1):25-30. LIN Guang-yuan,WU Guo-min,KONG Zhen-wu.Effects of surfactants on silica encapsulating maleopimaric acid glycidyl ester type epoxy resin[J].Chemistry and Industry of Forest Products,2014,34(1):25-30.
[20] YU Cai-li,WANG Xiao-lei,CHEN Chuan-wei,et al.Preparation of polystyrene microspheres using rosin-acrylic acid diester as a cross-linking agent[J].Industrial and Engineering Chemistry Research,2014,53(6):2244-2250.
[21] LI Bao-qiang,JIA De-chang,ZHOU Yu,et al.In situ hybridization to chitosan/magnetite nanocomposite induced by the magnetic field[J].Journal of Magnetism and Magnetic Materials,2006,306(2):223-227.

含松香的聚苯乙烯/Fe₃O₄磁性微球的制备与表征

Preparation and Characterization of Magnetic Polystyrene/Fe₃O₄ Microspheres with Rosin Moiety

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