液相沉积法制备尺寸可控木质素纳米粒子及其表征

doi:10.3969/j.issn.0253-2417.2015.05.014

林产化学与工业 ›› 2015, Vol. 35 ›› Issue (5): 85-92.doi: 10.3969/j.issn.0253-2417.2015.05.014

液相沉积法制备尺寸可控木质素纳米粒子及其表征

熊凯, 金灿, 刘贵锋, 吴国民, 陈健, 孔振武

中国林业科学研究院林产化学工业研究所; 生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2015-03-20 出版日期:2015-10-25 发布日期:2015-10-24
通讯作者: 孔振武,研究员,博士,博士生导师,主要从事生物质基聚合物材料研究;E-mail:kongzwlhs@163.com E-mail:kongzwlhs@163.com
作者简介:熊凯(1989—),男,湖北宜昌人,硕士生,主要从事生物质材料研究
基金资助:
国家自然科学基金资助项目(31400516);中国林科院中央级公益性科研院所基本科研业务费专项资金项目(CAFYBB2014QB043)

Preparation and characterization of lignin nanoparticles with controllable size by nanoprecipitation method

XIONG Kai, JIN Can, LIU Gui-feng, WU Guo-ming, CHEN Jian, KONG Zhen-wu

Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab.for Biomass Chemical Utilization;Key and Open Lab.of Forest Chemical Engineering, SFA;Key Lab.of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2015-03-20 Online:2015-10-25 Published:2015-10-24

摘要/Abstract

摘要： 以乙酸木质素为原料,采用液相沉积法制备了木质素纳米粒子。考察了制备过程中制备条件对形成木质素纳米粒子的影响,得到最佳制备条件为搅拌速率300 r/min、滴加速度5~40 mL/h、四氢呋喃(THF)/H₂O体积比5:100~10:100、木质素质量浓度10~20 g/L。通过电子显微镜、红外光谱、X射线衍射、元素分析、X射线光电子能谱和水接触角测试等分析方法研究了木质素纳米粒子的结构形貌和表界面性质。结果表明,制得的木质素纳米粒子平均粒径约为150 nm,保持非晶形态,其亲水内核形成过程增加了木质素纳米粒子的稳定性。

关键词: 木质素, 纳米粒子, 纳米沉积, 疏水表面

Abstract: Lignin nanoparticles (NPs) with controlled particle size were prepared by a nanoprecipitation method from acetic acid lignin, where the lignin was not modified particularly by any functional group. The preparation conditions, which could affect the size and feature of lignin NPs, were investigated in detail. The most suitable conditions were stirring rate above 300 r/min, dropping rate 5-40 mL/h, volume ratio of tetrahydrofuran (THF) to H₂O 5:100-10:100 and concentration of lignin solution 10-20 g/L. The chemical structure, morphology and physicochemical properties of lignin NPs were characterized by electronic microscope, infrared spectroscopy, X-ray diffraction, elemental analysis, X-ray photoelectron spectroscopy and contact angle measurements, respectively. The results indicated that the average diameter of lignin NPs was 150 nm approximately, and the lignin NPs neither chemically changed on their structures nor formed crystalline particle. The lignin NPs with a hydrophilic core and a hydrophobic surface would enhance their stability.

Key words: lignin, nanoparticle, nano precipitiation, hydrophobic surface

中图分类号:

TQ35

熊凯, 金灿, 刘贵锋, 吴国民, 陈健, 孔振武. 液相沉积法制备尺寸可控木质素纳米粒子及其表征[J]. 林产化学与工业, 2015, 35(5): 85-92.

XIONG Kai, JIN Can, LIU Gui-feng, WU Guo-ming, CHEN Jian, KONG Zhen-wu. Preparation and characterization of lignin nanoparticles with controllable size by nanoprecipitation method[J]. Chemistry and Industry of Forest Products, 2015, 35(5): 85-92.

参考文献

[1] LIU Xiao-huan,WANG Ji-fu,YU Juan,et al.Preparation and characterization of lignin based macromonomer and its copolymers with butyl methacrylate[J].International Journal of Biological Macromolecules,2013,60:309-315.
[2] PAN Hong,SUN Gang,ZHAO Tao.Synthesis and characterization of aminated lignin[J].International Journal of Biological Macromolecules,2013,59:221-226.
[3] MOTSNFIM-GIANETTI A A,AGNELLI J A M,LANCAS B Z,et al.Lignin as additive in polypropylene/coir composites:Thermal,mechanical and morphological properties[J].Carbohydrate Polymers,2012,87(4):2563-2568.
[4] THAKUR V K,THAKUR M K,RAGHAVAN P,et al.Progress in green polymer composites from lignin for multifunctional applications:A review[J].ACS Sustainable Chemistry & Engineering,2014,2(5):1072-1092.
[5] ADHIKARI B B,GURUNG M,ALAM S,et al.Kraft mill lignin:A potential source of bio-adsorbents for gold recovery from acidic chloride solution[J].Chemical Engineering Journal,2013,231:190-197.
[6] BRDAR M,C'IBAN M,TAKAI A,et al.Comparison of two and three parameters adsorption isotherm for Cr (VI) onto Kraft lignin[J].Chemical Engineering Journal,2012,183:108-111.
[7] HE Zhi-wei,LV Qiu-feng,ZHANG Jia-yin.Facile preparation of hierarchical polyaniline-lignin compostie with a reactive siliver-ion adsorbability[J].ACS Applied Materials & Interfaces,2011,4(1):369-374.
[8] LIANG Feng-bing,SONG Yan-lei,HUANG Chong-pin,et al.Synthesis of novel lignin-based ion-exchange resin and its utilization in heavy metals removal[J].Industrial & Engineering Chemistry Research,2013,52(3):1267-1274.
[9] THAKUR V K,THAKUR M K.Recent advances in green hydrogels from lignin:A review[J].International Journal of Biological Macromolecules,2015,72:834-847.
[10] XU Xue-zhu,ZHOU Jian,JIANG Long,et al.Porous core-shell carbon fibers derived from lignin and cellulose nanofibrils[J].Materials Letters,2013,109:175-178.
[11] AGO M,JAKES J E,ROJAS O J.Thermomechanical properties of lignin-based electrospun nanofibers and films reinforced with cellulose nanocrystals:A dynamic mechanical and nanoindentation study[J].ACS Applied Materials & Interfaces,2013,5(22):11768-11776.
[12] FRANGVILLE C,RUTKEVIIUS M,RICHTER A P,et al.Fabrication of environmentally biodegradable lignin nanoparticles[J].ChemPhysChem,2012,13(18):4235-4243.
[13] LAI Chun-lin,ZHOU Zheng-ping,ZHANG Li-feng,et al.Free-standing and mechanically flexible mats consisting of electrospun carbon nanofibers made from a natural product of alkali lignin as binder-free electrodes for high-performance supercapacitors[J].Journal of Power Sources,2014,247:134-141.
[14] SHIKINAKA K,FUJII N,EGASHIRA S,et al.Polyfunctional nanometric particles obtained from lignin,a woody biomass resource[J].Green Chemistry,2010,12(11):1914-1916.
[15] SPENDER J,DEMERS A L,XIE X,et al.Method for production of polymer and carbon nanofibers from water-soluble polymers[J].Nano Letters,2012,12(7):3857-3860.
[16] WANG Su-xi,YANG Li-ping,STUBBS L P,et al.Lignin-derived fused electrospun carbon fibrous mats as high performance anode materials for lithium ion batteries[J].ACS Applied Materials & Interfaces,2013,5(23):12275-12282.
[17] YIAMSAWSA D,BAIER G,THINES E,et al.Biodegradable lignin nanocontainers[J].RSC Advances,2014,4(23):11661-11663.
[18] KIM S K,KIM Y K,LEE H,et al.Superior pseudocapacitive behavior of confined lignin nanocrystals for renewable energy-storage materials[J].ChemSusChem,2014,7(4):1094-1101.
[19] SAHA D,LI Yun-chao,BI Zhong-he,et al.Studies on supercapacitor electrode material from activated lignin-derived mesoporous carbon[J].Langmuir,2014,30(3):900-910.
[20] CHOWDHURY M A.The controlled release of bioactive compounds from lignin and lignin-based biopolymer matrices[J].International Journal of Biological Macromolecules,2014,65:136-147.
[21] NAIR S S,SHARMA S,PU Yun-qiao,et al.High shear homogenization of lignin to nanolignin and thermal stability of nanolignin-polyvinyl alcohol blends[J].ChemSusChem,2014,7(12):3513-3520.
[22] MA Xiao-fei,JIAN Rui-juan,CHANG P R,et al.Fabrication and characterization of citric acid-modified starch nanoparticles/plasticized-starch composites[J].Biomacromolecules,2008,9(11):3314-3320.
[23] CHIN S F,PANG S C,TAY S H.Size controlled synthesis of starch nanoparticles by a simple nanoprecipitation method[J].Carbohydrate Polymers,2011,86(4):1817-1819.
[24] QIAN Yong,DENG Yong-hong,QIU Xue-qing,et al.Formation of uniform colloidal spheres from lignin,a renewable resource recovered from pulping spent liquor[J].Green Chemistry,2014,16(4):2156-2163.
[25] GOUDARZI A,LIN L T,KO F K.X-ray diffraction analysis of kraft lignins and lignin-derived carbon nanofibers[J].Journal of Nanotechnology in Engineering and Medicine,2014,5(2):21006-21011.

液相沉积法制备尺寸可控木质素纳米粒子及其表征

Preparation and characterization of lignin nanoparticles with controllable size by nanoprecipitation method

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们

[1]	张清桐, 运晓静, 颜德鹏, 李明富, 王双飞, 闵斗勇. 太阳光催化木质素制备银纳米颗粒[J]. 林产化学与工业, 2019, 39(4): 35-41.
[2]	孙永昌, 张冰清, 刘力鸣, 刘肖南, 史正军. 木质素基炭材料的制备及其对Cr(VI)的吸附机制研究[J]. 林产化学与工业, 2019, 39(4): 120-128.
[3]	陈超, 王傲, 孙康, 卢辛成, 许伟, 蒋剑春. 生物质原料的Ni催化石墨化研究[J]. 林产化学与工业, 2019, 39(3): 94-100.
[4]	赵存异, 应文俊, 史正军, 杨海艳, 郑志锋, 杨静. 羟丙基化碱木质素的制备及其对纤维素酶水解的影响[J]. 林产化学与工业, 2019, 39(2): 109-114.
[5]	许利娜, 杨小华, 丁海阳, 李梅, 夏建陵. 氧化改性木质素磺酸钠-石墨烯复合量子点的制备及性能[J]. 林产化学与工业, 2019, 39(1): 29-34.
[6]	李继辉, 孙康, 宋曜光, 王傲, 蒋剑春. 木质素基炭纳米片的制备及其电化学性能[J]. 林产化学与工业, 2019, 39(1): 67-74.
[7]	王广彬, 陈家宝, 谷利敏, 王春鹏, 许玉芝. 木质素基RAFT链转移剂的合成及其聚合特性研究[J]. 林产化学与工业, 2018, 38(6): 75-80.
[8]	周方浪, 郑志锋, 杨静, 杨海艳, 邓佳, 史正军. 木质素基酚醛树脂泡沫的制备及性能研究[J]. 林产化学与工业, 2018, 38(6): 103-109.
[9]	贾转, 万广聪, 李明富, 罗斌, 王双飞, 闵斗勇. 蔗渣硫酸盐木质素的分级分离与表征[J]. 林产化学与工业, 2018, 38(5): 107-114.
[10]	杨晓慧, 尚倩倩, 贾普友, 周永红. 酸性熔盐水合物解聚木质素及其改性酚醛泡沫的性能研究[J]. 林产化学与工业, 2018, 38(5): 115-121.
[11]	冯年捷, 汪继明, 谢益民, 杨鑫, 刘达岸. 杨木预水解液中木质素质量浓度的P因子调控作用[J]. 林产化学与工业, 2018, 38(4): 35-40.
[12]	叶结旺, 蒋剑春, 金贞福, 章卫钢, 张晓春. 超临界甲醇中复合金属氧化物催化木质素的解聚[J]. 林产化学与工业, 2018, 38(4): 52-60.
[13]	杨昇, 王钧, 李改云, 范东斌. 镁离子催化合成木质素-酚醛树脂的结构与固化特性[J]. 林产化学与工业, 2018, 38(4): 74-78.
[14]	张文, 许升, 吕宗泽, 李志国. 氮氧掺杂木质素基炭材料的制备及其电化学性能[J]. 林产化学与工业, 2018, 38(3): 55-62.
[15]	钱爽, 任浩. 木质素-聚丙烯酸钠高吸水树脂的制备及性能[J]. 林产化学与工业, 2018, 38(2): 21-28.