林产化学与工业 ›› 2016, Vol. 36 ›› Issue (5): 23-29.doi: 10.3969/j.issn.0253-2417.2016.05.004
武海棠, 郑冀鲁, 张军华, 黄晓华
收稿日期:
2015-12-15
出版日期:
2016-10-25
发布日期:
2016-11-05
作者简介:
武海棠(1982-),男,安徽宿州人,副教授,博士,主要从事生物质材料研究工作;E-mail:haitang345@gmail.com。
基金资助:
WU Hai-tang, ZHENG Ji-lu, ZHANG Jun-hua, HUANG Xiao-hua
Received:
2015-12-15
Online:
2016-10-25
Published:
2016-11-05
摘要: 以松木为原料,经炭化制得松木炭,以有机锆聚合物(PZC)为先驱体浸渍松木炭后进一步高温热处理制备得到ZrC木质陶瓷。采用XRD、SEM、FT-IR、TG-DSC分别对样品的物相变化、组成和微观结构进行了表征,研究了热处理温度和杂化材料质量增加率对木质陶瓷显气孔率与力学性能的影响。结果表明:有机锆先驱体裂解过程中生成ZrO2,进一步可以在1 400℃通过碳热还原反应转化为ZrC相。ZrC木质陶瓷由立方相ZrC和无定形碳组成,生成的木质陶瓷较好地保留了松木模板的管状孔洞结构,部分ZrC相沉积在孔洞内部。木质陶瓷材料显气孔率随着热处理温度的升高而升高,随质量增加率的增加而降低;力学性能随热处理温度和质量增加率的增加而提高,质量增加率为278%的杂化材料在热处理温度为1 400℃时制备的ZrC木质陶瓷具有良好的力学性能,弯曲强度和断裂韧性分别为158 MPa和1.8 MPa·m1/2。
中图分类号:
武海棠, 郑冀鲁, 张军华, 黄晓华. 先驱体转化法制备ZrC木质陶瓷及其性能分析[J]. 林产化学与工业, 2016, 36(5): 23-29.
WU Hai-tang, ZHENG Ji-lu, ZHANG Jun-hua, HUANG Xiao-hua. Preparation and Performance of ZrC Woodceramics Obtained by Polymer Precursor Conversion[J]. Chemistry and Industry of Forest Products, 2016, 36(5): 23-29.
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