糯米灰浆粘结型富钙成型活性炭的制备及其性能

doi:10.3969/j.issn.0253-2417.2016.06.003

林产化学与工业 ›› 2016, Vol. 36 ›› Issue (6): 16-22.doi: 10.3969/j.issn.0253-2417.2016.06.003

糯米灰浆粘结型富钙成型活性炭的制备及其性能

黄明堦¹, 黄碧珠², 林珊², 黄彪², 陈燕丹²

1. 福建农林大学生命科学学院, 福建福州 350002;
2. 福建农林大学材料工程学院, 福建福州 350002

收稿日期:2016-03-02 出版日期:2016-12-25 发布日期:2016-12-23
通讯作者: 陈燕丹(1977-),女,教授,硕士生导师,主要从事生物质材料与化学品的研究;E-mail:fjaucyd@163.com E-mail:fjaucyd@163.com
作者简介:黄明堦(1976-),男,福建晋江人,高级实验师,硕士,研究方向为生物质资源利用与转化
基金资助:
国家自然科学基金资助项目（31170520）；福建省自然科学基金资助项目（2015J01073）；福建农林大学杰出青年人才基金（xjq201208）

Preparation and Performance of Calcium-rich Activated Carbon Monolith Cemented by Sticky Rice-lime Mortar

HUANG Ming-jie¹, HUANG Bi-zhu², LIN Shan², HUANG Biao², CHEN Yan-dan²

1. College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou 350002, China;
2. College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China

Received:2016-03-02 Online:2016-12-25 Published:2016-12-23

摘要/Abstract

摘要： 利用造纸白泥原位物理活化杉木屑制备富钙活性炭粉，考察了制备工艺条件对活性炭粉得率和吸附性能的影响。在富钙活性炭粉中加入糯米浆进行捏合并压制成型，制得糯米灰浆粘结型柱状成型活性炭。在白泥与杉木屑质量比3∶2，950℃活化1.5 h的优化条件下，可制备出比表面积为975 m²/g、得率约24%的活性炭样品。经300℃热处理1 h后制得的糯米灰浆粘结型富钙成型活性炭，其抗压强度高达18 MPa，碘吸附值为410 mg/g，耐水浸泡性长达60 d以上。SEM和XRD分析结果显示：糯米灰浆粘结成型活性炭中各组分间胶结紧密，且糯米浆对成型活性炭试样中石灰组分的炭化结晶进程具有调控作用。

关键词: 造纸白泥, 糯米灰浆, 富钙成型活性炭, 吸附, 抗压强度

Abstract: Chinese fir sawdust was physically activated by papermaking white mud to prepare calcium-rich powdery activated carbons. The effects of preparation conditions on the yield and adsorption capacity of activated carbons were investigated. Compression molding of a mixture of calcium-rich activated carbons blended with cooked sticky rice soup was performed to fabricate sticky rice-lime mortar cemented column-shaped activated carbon monolith. Under the optimized conditions, the specific surface area of the prepared activated carbon was 975 m²/g and the yield was about 24%. After heat treatment at 300℃ for 1 h, the iodine adsorption value of the prepared activated carbon monolith was 410 mg/g, the compressive strength was 18 MPa, and its resistance to water immersion was excellent. SEM and XRD analysis results indicated that the components of the sticky rice-lime mortar bonding activated carbon monolith were cemented closely, and the carbonation crystallization process of the lime component which was integrated in activated carbon monolith could be regulated by the glutinous rice paste to form a compact microstructure.

Key words: papermaking white mud, sticky rice-lime mortar, calcium-rich activated carbon monolith, adsorption, compressive strength

中图分类号:

TQ424

黄明堦, 黄碧珠, 林珊, 黄彪, 陈燕丹. 糯米灰浆粘结型富钙成型活性炭的制备及其性能[J]. 林产化学与工业, 2016, 36(6): 16-22.

HUANG Ming-jie, HUANG Bi-zhu, LIN Shan, HUANG Biao, CHEN Yan-dan. Preparation and Performance of Calcium-rich Activated Carbon Monolith Cemented by Sticky Rice-lime Mortar[J]. Chemistry and Industry of Forest Products, 2016, 36(6): 16-22.

参考文献

[1] 闫新龙,刘欣梅,乔柯,等.成型活性炭制备技术研究进展[J].化工进展,2008,27(12):1868-1872. YAN Xin-long,LIU Xin-mei,QIAO Ke,et al.Research progress of preparation technique of activated carbon monolith[J].Chemical Industry and Engineering Progress,2008,27(12):1868-1872.
[2] 王锐,陈华,刘守新.CMC粘接法制备柱状成型活性炭[J].林产化学与工业,2011,31(5):6-10. WANG Rui,CHEN Hua,LIU Shou-xin.Preparation of column-shaped activated carbon using carboxymethyl cellulose as adhesives[J].Chemistry and Industry of Forest Products,2011,31(5):6-10.
[3] 程婷,陈杰,黄祥,等.核桃壳脱硫活性炭成型工艺研究[J].林产化学与工业,2013,33(4):48-52. CHENG Ting,CHEN Jie,HUANG Xiang,et al.Molding process of the columnar activated carbon from walnut shell for flue gas desulfurization[J].Chemistry and Industry of Forest Products,2013,33(4):48-52.
[4] 肇巍,汪印,李强,等.高硅灰酒糟基粉状活性炭成型及性能[J].过程工程学报,2011,11(6):1068-1074. ZHAO Wei,WANG Yin,LI Qiang,et al.Molding and characterization of powder activated carbon with high-Si ash made from distilled spirits lees[J]. The Chinese Journal of Process Engineering,2011,11(6):1068-1074.
[5] WEI Guo-feng,ZHANG Hui,WANG Hong-min,et al.An experimental study on application of sticky rice-lime mortar in conservation of the stone tower in the Xiangji Temple[J].Construction and Building Materials,2012,28(1):624-632.
[6] YANG Fu-wei,ZHANG Bing-jian,MA Qing-lin.Study of sticky rice-lime mortar technology for the restoration of historical masonry construction[J].Accounts of Chemical Research,2010,43(6):936-944.
[7] 魏国锋,方世强,张秉坚,等.传统糯米灰浆碳化过程中Liesegang环的形成机理研究[J].光谱学与光谱分析,2012,32(8):2181-2184. WEI Guo-feng,FANG Shi-qiang,ZHANG Bing-jian,et al.Study on the mechanism of Liesegang pattern development during carbonating of traditional sticky rice-Lime mortar[J].Spectroscopy and Spectral Analysis,2012,32(8):2181-2184.
[8] LI Ying-jie,SUN Rong-yue,ZHAO Jian-li,et al.Sulfation behavior of white mud from paper manufacture as SO₂ sorbent at fluidized bed combustion temperatures[J].Journal of Thermal Analysis and Calorimetry,2012,107(1):241-248.
[9] SUN Rong-yue,LI Ying-jie,LIU Chang-tian,et al.Utilization of lime mud from paper mill as CO₂ sorbent in calcium looping process[J].Chemical Engineering Journal,2013,221:124-132.
[10] 何兰兰,于敦喜,曾宪鹏,等.造纸白泥的分解和碳酸盐化特性[J].化工进展,2014,33(11):3095-3100. HE Lan-lan,YU Dun-xi,ZENG Xian-peng,et al.Investigation on calcination and carbonation performance of papermaking lime mud[J].Chemical Industry and Engineering Progress,2014,33(11):3095-3100.
[11] ZHANG Ji-shi,WANG Qing-qing,ZHENG Peng-wei,et al.Anaerobic digestion of food waste stabilized by lime mud from papermaking process[J].Bioresource Technology,2014,170:270-277.
[12] 赵广锡,徐淦臣,吕心刚.造纸白泥在烟气脱硫中的应用[J].中华纸业,2009,8:82-84. ZHAO Guang-xi,XU Gan-chen,LÜ Xin-gang.The application of paper mill lime mud in flue gas desulfurization[J].China Pulp & Paper Industry,2009,8:82-84.
[13] 陈婉君,吴任平,潘金凤,等.无机胶凝成型活性炭的制备及性能研究[J].功能材料,2013,44(21):3195-3198. CHEN Wan-jun,WU Ren-ping,PAN Jin-feng,et al.Research on preparation and performance of activated carbon monoliths with inorganic cement binder[J].Journal of Functional Materials,2013,44(21):3195-3198.
[14] 李建刚,李开喜,凌立成,等.成型活性炭的制备及其甲烷吸附性能的研究[J].新型炭材料,2004,19(2):114-118. LI Jian-gang,LI Kai-xi,LING Li-cheng,et al.The preparation and methane adsorption of formed activated carbon[J].New Carbon Materials,2004,19(2):114-118.
[15] 龙先兵,吴任平.可再生无机胶凝成型活性炭材料的苯吸附特性[J].硅酸盐通报,2012,31(4):785-788. LONG Xian-bing,WU Ren-ping.Renewable inorganic cementitious forming activated carbon and its benzene adsorption capacity[J].Bulletin of the Chinese Ceramic Society,2012,31(4):785-788.
[16] 杨富巍,张秉坚,曾余瑶,等.传统糯米灰浆科学原理及其现代应用的探索性研究[J].故宫博物院院刊,2008,5:105-114. YANG Fu-wei,ZHANG Bing-jian,ZENG Yu-yao,et al.Exploratory research on the scientific nature and application of traditional sticky rice mortar[J].Palace Museum Journal,2008,5:105-114.
[17] LUO Yan-bing,ZHANG Yu-jie.Investigation of sticky-rice lime mortar of the Horse Stopped Wall in Jiange[J].Heritage Science,2013,1:26-30.
[18] 李祖光,方世强,魏国锋,等.无机添加剂对糯米灰浆性能影响及机理研究[J].建筑材料学报,2013,16(3):462-468. LI Zu-guang,FANG Shi-qiang,WEI Guo-feng,et al.Influence of inorganic admixture on performance of sticky rice-lime mortar and its mechanism[J].Journal of Building Materials,2013,16(3):462-468.
[19] 杨富巍,张秉坚,潘昌初,等.以糯米灰浆为代表的传统灰浆:中国古代的重大发明之一[J].中国科学,2009,39(1):1-7. YANG Fu-wei,ZHANG Bing-jian,PAN Chang-chu,et al.The representative traditional mortar of the sticky rice lime mortar:One of the great inventions of ancient China[J].Science in China,2009,39(1):1-7.

糯米灰浆粘结型富钙成型活性炭的制备及其性能

Preparation and Performance of Calcium-rich Activated Carbon Monolith Cemented by Sticky Rice-lime Mortar

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们

[1]	陈金伟, 王丹, 商士斌, 刘鹤, 蔡照胜. 端氨基超支化聚合物接枝双醛基纳米纤维素的制备及其对Ni²⁺的吸附[J]. 林产化学与工业, 2019, 39(4): 18-26.
[2]	吴少基, 江坤, 叶跃元, 刘运权, 王夺, 李水荣. 污泥与杨木屑共热解焦制活性炭及其废水处理应用[J]. 林产化学与工业, 2019, 39(4): 56-64.
[3]	孙永昌, 张冰清, 刘力鸣, 刘肖南, 史正军. 木质素基炭材料的制备及其对Cr(VI)的吸附机制研究[J]. 林产化学与工业, 2019, 39(4): 120-128.
[4]	李延庆, 刘志明, 程小凯, 曹梦楠, 王佳楠. 海藻酸钠/纤维素复合微球的制备及性能表征[J]. 林产化学与工业, 2019, 39(2): 67-72.
[5]	陈金伟, 商士斌, 沈明贵, 王丹, 付飞, 蔡照胜. 端氨基纳米纤维素的制备及对Pb(Ⅱ)的吸附性能研究[J]. 林产化学与工业, 2018, 38(6): 11-19.
[6]	许鹏博, 何晶, 俞娟, 范一民. 高锰酸钾改性汉麻秆芯对亚甲基蓝吸附性能的研究[J]. 林产化学与工业, 2018, 38(6): 81-87.
[7]	刘云龙, 宋科, 肖卓炳, 郭婕. ZSM-5分子筛对杜仲绿原酸的吸附行为研究[J]. 林产化学与工业, 2018, 38(6): 95-102.
[8]	孙佳明, 鄂雷, 马春慧, 李伟, 刘守新. N掺杂炭气凝胶的水热制备及其金属离子吸附性能[J]. 林产化学与工业, 2018, 38(4): 20-28.
[9]	夏远涛, 杨美红, 孙会杰, 高雅廷, 周桂. 复合型吸附剂黑曲霉菌丝体-壳聚糖的制备及对Cu²⁺吸附的作用机制[J]. 林产化学与工业, 2018, 38(4): 117-123.
[10]	佟国宾, 徐州, 李伟, 刘守新. 载钼活性炭的制备、表征及其苯吸附性能[J]. 林产化学与工业, 2018, 38(3): 33-40.
[11]	刘云龙, 宋科, 肖卓炳, 郭婕. ZSM-5分子筛吸附石蒜碱及加兰他敏的动力学研究[J]. 林产化学与工业, 2018, 38(3): 122-128.
[12]	董益帆, 刘志佳, 兰天晴. 预处理对蔗渣吸附纤维素酶特性的影响[J]. 林产化学与工业, 2018, 38(2): 75-79.
[13]	刘志明, 吴鹏. 疏水性纤维素气凝胶球的制备及其吸附性能研究[J]. 林产化学与工业, 2018, 38(1): 9-17.
[14]	周帅, 苗庆显, 黄六莲, 陈礼辉. 半纤维素基功能材料的研究进展[J]. 林产化学与工业, 2017, 37(6): 10-18.
[15]	黄丽, 孙康, 朱光真, 刘石彩. 活性炭微结构及其对丁酮吸附-脱附性能的影响[J]. 林产化学与工业, 2017, 37(5): 146-152.