木醋液的制备、精制与应用研究进展

doi:10.3969/j.issn.0253-2417.2017.03.003

摘要/Abstract

摘要： 从原料、热解工艺、催化剂几方面阐述了对木醋液理化性质及组成成分的影响，概述了静置法、蒸馏法、萃取法、活性炭吸附法、膜过滤法等常用精制工艺及其应用特性，着重介绍了木醋液在农业、林业、畜牧业、医药和食品领域的应用研究进展。

Abstract: The influences of raw materials, preparation conditions and catalyst on the physical and chemical properties of wood vinegar are summarized. The refining processes, including setting method, distillation, extraction, activated carbon adsorption and membrane filtration method, are summarized, too. The applications of wood vinegar in agriculture, forest, animal husbandry, medicine and foodstuff, and so on, are introduced.

Key words: wood vinegar, preparation, purification, application

中图分类号:

TQ35

卢辛成, 蒋剑春, 孙康, 孙云娟. 木醋液的制备、精制与应用研究进展[J]. 林产化学与工业, 2017, 37(3): 21-30.

LU Xincheng, JIANG Jianchun, SUN Kang, SUN Yunjuan. Review on Preparation and Application of Wood Vinegar[J]. Chemistry and Industry of Forest Products, 2017, 37(3): 21-30.

参考文献

[1] 袁振宏, 吴创之, 马隆龙, 等. 生物质能利用原理与技术[M]. 北京:化学工业出版社, 2005. YUAN Z H, WU C Z, MA L L, et al. Application principle and technology of biomass energy[M]. Beijing:Chemical Industry Press, 2005.
[2] SUMRIT M, VIJITR U. Wood charcoal and wood vinegar production from mango tree wood by using 3 m³ carbonizaiong dome kiln[J]. International Journal of Applied Environment Sciences, 2015, 10(5):1911-1922.
[3] WU S Y, WU Y Q, GAO J S. The effect of wood vinegar on hydrothermal liquefaction of cotton stalk under CO atmosphere[J]. Energy Sources A, Energy Sources, Part A:Recovery, Utilization, and Environmental Effects,2013, 36(4):411-417.
[4] SHINY K S, REMADEVI O K. Evaluation of termiticidal activity of coconut shell oil and its comparison to commercial wood preservatives[J]. European Journal of Wood and Wood Products, 2013, 72(1):139-141.
[5] MA X H, WEI Q, ZHANG S S, et al. Isolation and bioactivities of organic acids and phenols from walnut shell pyroligneous acid[J]. Journal of Analytical and Applied Pyrolysis, 2011, 91(2):338-343.
[6] MUN S P, KU C S. Pyrolysis GC-MS analysis of tars formed during the aging of wood and bamboo erode vinegars[J]. Journal of Wood Science, 2019, 56(1):47-52.
[7] 侯宝鑫, 张守玉, 吴巧美, 等. 生物质热解制备木醋液及其性质研究[J]. 燃料化学学报, 2015, 43(12):1439-1445. HOU B X, ZHANG S Y, WU Q M, et al. wood vinegar and its properties from pyrolysis of biomass[J]. Journal of Fuel Chemistry and Technology, 2015, 43(12):1439-1445.
[8] 雷军锋. 木醋液有机成分分析及应用研究[D]. 新乡:河南师范大学硕士学位论文, 2008. LEI J F. Study on analysis and application of wood vinegar[D].Xinxiang:Master Degree Thesis of Henan Normal University, 2008.
[9] 蒋恩臣, 赵晨希, 秦丽元, 等. 松子壳连续热解制备木醋液实验[J]. 农业工程学报, 2014, 30(5):262-269. JIANG E C, ZHAO C X, QIN L Y, et al. Experiment of wood vinegar produced from pine nut shell continuous pyrolysis[J]. Transactions of the Chinese Society of Agricultural Engineering, 2014, 30(5):262-269.
[10] 尉芹, 马希汉, 郑滔. 核桃壳木醋液的制取、成分分析及抑菌实验[J]. 农业工程学报, 2008, 24(7):276-279. WEI Q, MA X H, ZHENG T. Preparation, chemical constituent analysis and antimicrobial activities of pyroligneous acid of walnut shell[J]. Transactions of the CSAE, 2008, 24(7):276-279.
[11] 毛巧芝, 赵忠, 马希汉, 等. 苦杏壳木醋液抑菌活性和化学成分分析[J]. 农业机械学报, 2010, 41(2):164-170. MAO Q Z, ZHAO Z, MA X H, et al. Preparation, toxicity and components for bitter almond shell wood vinegar[J]. Transactions of the Chinese Society for Agricultural Machinery, 2010, 41(2):164-170.
[12] 韩亮. 竹醋液的分析、精制、抗菌性能和应用研究[D]. 镇江:江苏大学硕士学位论文, 2011. HAN L. Study on analysis, refining, antimicrobial activity and application of bamboo vinegar[D].Zhenjiang:Master Degree Thesis of Jiangsu University, 2011.
[13] 魏娟. 秸秆醋液抑菌和杀菌性能的研究[D]. 南京:南京林业大学硕士学位论文, 2009. WEI J. Study on the anti-microbial and bactericidal properties of straw vinegar[J].Nanjing:Master Degree Thesis of Nanjing Forestry University, 2009.
[14] XIONG S W, ZHANG S Y, WU Q M, et al. Investigation on cotton stalk and bamboo sawdust carbonization for barbecue charcoal preparation[J]. Bioresource Technology, 2014, 152:86-92.
[15] DONG Q, XIONG Y. Kinetics study on conventional and microwave pyrolysis of moso bamboo[J].Bioresour Technol, 2014, 171:127-131.
[16] WU Q, ZHANG S, HOU B, et al. Study on the preparation of wood vinegar from biomass residues by carbonization process[J]. Bioresour Technol, 2015, 179:98-103.
[17] 朴哲, 闫吉昌, 崔香兰, 等. 木醋液的精制及有机成分研究[J]. 林产化学与工业, 2003, 23(2):18-21. PIAO Z, YAN J C, CUI X L, et al. Refining process and organic component of wood vinegar[J]. Chemistry and Industry of Forest Products, 2003, 23(2):18-21.
[18] 王海英, 李玉生, 杨国亭, 等. 柞木木醋液有机成分分析[J]. 东北林业大学学报, 2005, 33(3):110-112. WANG H Y, LI Y S, YANG G T, et al. Analysis on the organic components of wood vinegar for mongolian oak[J]. Journal of Northeast Forestry University, 2005, 33(3):110-112.
[19] 王元, 翟梅枝, 晏婷, 等. 不同温度段核桃壳木醋液的组分分析及生物活性研究[J]. 西北植物学报, 2011, 31(11):2321-2327. WANG Y, ZHAI M Z, YAN T, et al. Chemical compositions and biological activity of pyroligneous acids of walnut shell[J]. Acta Botanica Boreal-Occidentalia Sinica, 2011, 31(11):2321-2327.
[20] DOBELE G, MEIER D, FAIX O,et al. Volatile products of catalytic flash pyrolysis of celluloses[J]. Journal of Analytical and Applied Pyrolysis, 2001, 58:453-463.
[21] 杨昌炎,姚建中,吕雪松,等. 生物质中K⁺、Ca²⁺对热解的影响及机理研究[J]. 太阳能学报, 2006,27(5):496-502. YANG C Y, YAO J Z,Lü X S, et al. Influence of K⁺ and Ca²⁺ on the mechanism of biomass pyrolysis[J]. Acta Energiae Solaris Sinica, 2006,27(5):496-502.
[22] MUN S P, JANG J P. Liquefaction of cellulose in the presence of phenol using p-toluene sulfonic acids a catalyst[J]. Journal of Industrial and Engineering Chemistry, 2009, 15(5):743-747.
[23] KARAGÖZ S, BHASKAR T, MUTO A, et al. Effect of Rb and Cs carbonates for production of phenolsfrom liquefaction of wood biomass[J]. Fuel, 2004, 83(17):2293-2299.
[24] 廖艳芬, 王树荣, 骆仲泱, 等. 金属离子催化生物质热裂解规律及其对产物的影响[J]. 林产化学与工业, 2005, 25(2):25-30. LIAO Y F, WANG S R, LUO Z Y, et al. The behavior of biomass pyrolysis catalyzed by metallic ions and their effects on the products[J]. Chemistry and Industty of Forest Products, 2005, 25(2):25-30.
[25] FAGEMAS L, KUOPPALA EK, OASMAA A. Chemical composition of birch wood slow pyrolsis products[J]. Energy & Fuels, 2012, 26(2):1275-1283.
[26] WITITSIRI S. Production of wood vinegars from coconut shells and additional materials for control of termite workers, Odontotermes sp. and striped mealy bugs, Ferrisia virgata[J]. Songklanakarin Journal of Science & Technology, 2011, 33(3):349-354.
[27] WANG M F, JIANG E C, XIONG L M, et al. Components characteristics of wood vinegar from rice husk continuous pyrolysis and catalytic cracking[J]. Applied Mechanics and Materials, 2013, 291:368-374.
[28] 张文标, 华毓绅, 王伟龙, 等. 高纯度竹醋液生产和加工工艺的研究[J]. 林产化学与工业, 2003, 23(3):46-50. ZHANG W B, HUA Y K, WANG W L, et al. Study on technology of high purity bamboo vinegar production[J]. Chemistry and Industry of Forest Products, 2003, 23(1):46-50.
[29] 许英梅, 高连连, 朴永哲, 等. 不同精制法松树木醋液中的生物活性组分的富集[J]. 大连民族学院学报, 2015, 17(3):207-210. XU Y M, GAO L L, PIAO Y Z, et al. Enrichment of bioactive components in pine wood vinegar based on different refining methods[J]. Journal of Dalian Nationalities University, 2015, 17(3):207-210.
[30] WEI Q, MA X H, DONG J. Preparation, chemical constituents and antimicrobial activity of pyroligneous acids from walnut tree branches[J]. Journal of Analytical and Applied Pyrolysis, 2010, 87:24-28.
[31] 邹勇, 蔚芹, 赵忠, 等.木屑快速热解生物油中酚类提取物的抗氧化及抑真菌活性研究[J]. 西北林学院学报, 2014, 29(1):116-121. ZOU Y, WEI Q, ZHAO Z, et al. Antioxidant and antimicrobial activities of phenolic extract from bio-oil by fast pyrolysis of sawdust[J]. Journal of Northwest Forestry University, 2014, 29(1):116-121.
[32] 杨頔, 刘学贵,年中峰, 等. 木醋液中酚类物质的富集及其提取工艺的研究[J]. 宁夏农林科技, 2015, 56(4):55-58. YANG D, LIU X G, NIAN Z F, et al. A study of extraction process of enriched phenols from wood vinegar[J]. Ningxia Journal of Agriculture and Forestry Science and technology, 2015, 56(4):55-58.
[33] 柏明娥, 陈顺伟, 庄晓伟. 不同精制工艺对竹醋液理化性质的影响[J]. 林产化工通讯, 2005, 39(2):25-27. BAI M E, CHEN S W, ZHUANG X W. The impact of the different preparation technics on properties of bamboo vinegar[J]. Journal of Chemical Industry of Forest Products, 2005, 39(2):25-27.
[34] 张晶晶, 周楚仪, 吴春香, 等. 不同活性炭对竹醋液的脱色脱臭应用研究[J]. 宝鸡文理学院学报:自然科学版, 2012, 32(2):34-41. ZHANG J J, ZHOU C Y, WU C X, et al. Applications researches on the decolorization and deodorization of bamboo vinegar with different activated carbons[J]. Journal of Baoji University of Arts and Sciences:Natural Science Edition, 2012, 32(2):34-41.
[35] 黄海林. 微滤/超滤深度处理生活污水研究[D]. 天津:天津大学硕士学位论文, 2005. HUANG H L.Study on the advanced treatment of municipal sewage by MF/UF[D]. Tianjin:Master Degree Thesis of Tianjin University, 2005.
[36] 田国军. 纳滤膜性能及其在染料分离中的应用[D]. 天津:天津工业大学硕士学位论文, 2007. TIAN G J.Study on the performance and application of nanofiltration membrane in dye separation[D]. Tianjin:Master Degree Thesis of Tianjin Polytechnic University, 2007.
[37] 冯凌蕾. 反渗透法应用于酒类脱醇的研究[D]. 无锡:江南大学硕士学位论文, 2005. FENG L L.Study on the application of reverse osmosis used in alcohol elimination from alcohol[D]. Wuxi:Master Degree Thesis of Jiangnan University, 2005.
[38] 王宗海. 络合-超滤技术处理镍离子废水[D]. 大连:大连理工大学硕士学位论文, 2008. WANG Z H. Treatment of nickel ions in waste water by complexation-ultrafiltration technology[D]. Dalian:Master Degree Thesis of Dalian University of Technology, 2008.
[39] 乔玉彦. 膜技术在木醋液纯化工艺中的应用[D]. 郑州:郑州大学硕士学位论文, 2010. QIAO Y Y.Application of membrane technology in purification of wood vinegar[D]. Zhengzhou:Master Degree Thesis of Zhengzhou University, 2010.
[40] 陆淇, 肖志良, 何应会, 等. 叶面喷施生物醋液对桉树苗期营养及生长的影响[J]. 安徽农业科学, 2013, 41(2):645-647,681. LU Q, XIAO Z L, HE Y H, et al. Application of pyroligneous solution as foliar fertilizer in eucalyptus fertilization[J]. Journal of Anhui Agricultural Sciences, 2013, 41(2):645-647,681.
[41] 孫太權, 李知彦, 金相国ら. 異なる肥料水凖における木酢液と木炭の混合物が土壤理が水稻生育に及ほす影響[J].日作紀,2003, 72(3):345-349.
[42] 李忠徽, 王旭东. 灌施木醋液对土壤性质和植物生长的影响[J]. 植物营养与肥料学报, 2014, 20(2):510-516. LI Z H, WANG X D. Effect of wood vinegar on soil properties and plant growth[J]. Plant Nutrition and Fertilizer Science, 2014, 20(2):510-516.
[43] 王海英. 木醋液对植物生长调节机理研究[D]. 哈尔滨:东北林业大学博士学位论文, 2005. HANG H Y. Research on regulation mechanism of wood vinegar on plant growth[D]. Haerbin:Doctoral dissertation of Northeast Forestry University,2005.
[44] 続栄治, 脇山恭行, 江藤博六,等.木酢液ならびに木酢液と木炭の混合物がイネの生育および収量に及ぼす影響[J]. 日本作物學會紀事, 1989, 58:592-597.
[45] 杠冠華, 続栄治, 寺尾寛行. 木酢液と木炭の混合物がイネの生育ならびに収量に及ぼす影響[J]. 日本作物学会九州支部会報, 1998, 64:21-22.
[46] 张琳, 董琳, 王甲辰, 等. 木醋液作为叶面施用对西红柿长势及品质的影响[J]. 北京农业, 2010(30):58-62. ZHANG L, DONG L, WANG J C, et al. Influence of wood vinegar as leaves fertilizeron growth and quality of tomato[J]. Beijing Agriculture, 2010(30):58-62.
[47] 黄文, 应芳卿, 黄晓燕, 等. 木醋液作灌根对番茄生长发育和产量的影响[J]. 北方园艺, 2010(24):37-38. HUANG W, YING F Q, HUANG X Y, et al. Effects of wood vinegar for irrigating roots on growth and yield[J]. Northern Horticulture, 2010(24):37-38.
[48] 童晓利, 陈月红, 郭成宝, 等. 草醋液对草莓生物学特性及果实品质的影响[J]. 江苏农业科学, 2012, 40(10):165-167. TONG X L, CHEN Y H, GUO C B, et al.The influence of grass vinegar on biological characteristics and fruit quality of strawberries[J].Jiangsu Agricultural Sciences, 2012, 40(10):165-167.
[49] 史咏竹, 杜相革. 木醋液在农业生产上的研究新进展[J]. 中国农学通报, 2003, 19(3):108-109,114. SHI Y Z, DU X G.The study of wood vinegar applied in agricultural production[J]. Chinese Agricultural Science Bulletin, 2003, 19(3):108-109,114.
[50] 黄文, 应芳卿, 黄晓燕, 等. 叶面喷施木醋液对番茄生长发育的影响[J]. 现代农业科技, 2010(20):121,125. HUANG W, YING F Q, HUANG X Y, et al. Effects of wood vinegar by foliage spraying on growth and development of tomato[J]. Modern Agricultural Science and Technology, 2010(20):121,125.
[51] 潘洁, 肖辉, 程文娟, 等. 木醋液土壤灌溉对土壤养分、番茄产量及品质的影响[J]. 中国土壤与肥料, 2016(2):61-64,77. PAN J, XIAO H, CHENG W J, et al. Effect of wood vinegar on soil nutrient, tomato yield and quality[J]. Soils and Fertilizers Sciences in China, 2016(2):61-64,77.
[52] 胡春花, 达布希拉图, 武闻权, 等. 木醋液及炭醋肥对设施土壤微生物数量及相关性的影响[J]. 土壤通报, 2012, 43(4):815-820. HU C H, DABU X L T, WU W Q, et al. The influence of wood vinegar and charcoal on the soil microbial quantity and correlation of the facilities[J]. Chinese Journal of Soil Science, 2012, 43(4):815-820.
[53] 张亚兰, 孙金龙, 李治宇, 等. 木醋液对盐碱土改良效果研究[J]. 中国农机化学报, 2014, 35(6):292-295. ZHANG Y L, SUN J L, LI Z Y, et al. Study on the improvement effects of wood vinegar on saline-alkali soil[J]. Journal of Chinese Agricultural Mechanization, 2014, 35(6):292-295.
[54] 谷田具光克. 木酢液の生物活性とその利活用への最近の動向[J]. New Food Industry, 2004, 46(8):5-16.
[55] SAMANYA M, YAMAUCHI K E. Morphological demonstration of the stimulative:Effects of charcoal powder including wood vinegar compound solution on growth performance and intestinal villus histology in chickens[J]. The Journal of Poultry Science, 2002, 39(1):42-55.
[56] 付海冬, 李瑜, 张亚男. 木醋液作产蛋鸡饲料添加剂研究[J]. 现代农业科技, 2010(9):325-327. FU H D, LI Y, ZHANG Y N. Study on wood vinegar as feed additive of laying hens[J]. Modern Agricultural Science and Technology, 2010(9):322-327.
[57] 岸本定吉. 炭博士にきく木醋液の神秘[M]. 東京:株式会社DHC, 1998:32,106,136,145,158-159.
[58] 坂井田節. 炭と木酢液の有効活用(14):鶏卵肉を中心として木酢酸粉末を給与することにより高品質の成鶏肉を生産[J]. 鶏の研究,2006, 81(4):46-50.
[59] 坂井田節. 炭と木酢液の有効活用(25):鶏卵肉を中心として鶏にとどまらない炭と木酢液の有効性、普遍性に大きな特徴[J]. 鶏の研究, 2007, 82(2):10-15.
[60] WANG H F, WANG J L, WANG C, et al. Effect of bamboo vinegar as an antibiotic alternative on growth performance and fecal bacterial communities of weaned piglets[J]. Livestock Science, 2012, 144(1):173-180.
[61] 张君正, 王巍, 张敏. 木醋液对育肥猪肉质性状的影响[J]. 黑龙江畜牧兽医, 2010(7):95-97. ZHANG J Z, WANG W, ZHANG M. The effect of wood vinegar on the quality pig meat[J]. Journal of Heilongjiang Animal Husbandry and Veterinary, 2010(7):95-97.
[62] MEKBUNGWAN A, YAMAUCHI K, SAKAIDA T. Intestinal villus histological alterations in piglets fed dietary charcoal powder including wood vinegar compound liquid[J]. Anat Histol Embryol, 2004, 33(1):11-16.
[63] ORAMAHI H A, YOSHIMURA T. Antifungal and antitermitic activities of wood vinegar from Vitex pubescens Vahl[J]. Journal of Journal of Wood Science, 2013, 59(4):344-350.
[64] 王海英, 曹宏颖. 农林废弃物木醋液抑菌机理进展[J]. 安徽农业科学, 2014, 42(3):741-742,839. WANG H Y, CAO H Y. Progress of antimicrobial mechanism of wood vinegar from agricultural and forestry wastes[J]. Journal of Anhui Agricultural Sciences, 2014, 42(3):741-742,839.
[65] WEI Q, MA X H, DONG J. Preparation, chemical constituents and antimicrobial activity of pyroligneous acids from walnut tree branches[J]. Journal of Analytical and Applied Pyrolysis, 2010, 87:24-28.
[66] 彭美芳, 陈文学, 李宇真, 等. 草果提取物对金黄色葡萄球菌抑菌机制的初探[J]. 食品工业科技, 2013, 34(24):79-82. PENG M F, CHEN W X, LI Y Z, et al. Antibacterial mechanism of extract from amomum tsao-ko on staphylococcus aureus[J]. Science and Technology of Food Industry, 2013, 34(24):79-82.
[67] 张立华, 王丹, 宫文哲, 等. 枣核木醋液化学成分分析及其抑菌活性[J]. 食品科学, 2016, 37(14):123-127. ZHANG L H, WANG D, GONG W Z, et al. Chemical constituents and antimicrobial activities of pyroligneous acid from jujubepit[J]. Food Science, 2016, 37(14):123-127.
[68] 刘勇, 何华平, 龚林忠, 等. 桃炭疽病病原鉴定及木醋液防治研究[J]. 湖北农业科学, 2014, 53(24):6002-6006. LIU Y, HE H P, GONG L Z, et al. Identifying pathogen of peach anthracnose and controling it with wood vinegar[J]. Hubei Agricultural Sciences, 2014, 53(24):6002-6006.
[69] LEE C S, YI E H, KIM H R, et al. Anti-dermatitis effects of oak wood vinegar on the DNCB-inducedcontact hypersensitivity via STAT3 suppression[J]. Journal of Ethnopharmacology, 2011, 135(3):747-753.
[70] 王文桥, 许晓梅, 刘金朵, 等. 竹醋液对几种植物病原真菌的抑制活性[J]. 植物病理学报, 2005, 35(6):99-104. WANG W Q, XU X M, LIU J D, et al. Fungicidal activity of bamboo vinegar against several phytopathogenic fungi[J]. Acta Phytopathologica Sinica, 2005, 35(6):99-104.
[71] 黄健屏, 林亲雄, 宋贤聚. 竹醋4种分馏物的抑菌试验[J]. 中南林学院学报, 1999, 19(3):82-84. HUANG J P, LIN Q X, SONG X J. Bacteriostatic experiment of the distillates of bamboo acid[J]. Journal of Central South Forestry University, 1999, 19(3):82-84.