基于离子液体的椰壳纤维纳米纤维素的制备与表征

doi:10.3969/j.issn.0253-2417.2017.05.019

林产化学与工业 ›› 2017, Vol. 37 ›› Issue (5): 139-145.doi: 10.3969/j.issn.0253-2417.2017.05.019

基于离子液体的椰壳纤维纳米纤维素的制备与表征

曹菲, 赵鑫, 胡英成, 陈培培, 李慧芳

东北林业大学材料科学与工程学院;生物质材料科学与技术教育部重点实验室, 黑龙江哈尔滨 150040

收稿日期:2017-03-14 出版日期:2017-10-25 发布日期:2017-10-30
通讯作者: 胡英成,教授,博士生导师,研究领域为生物质材料性能;E-mail:yingchenghu@163.com。 E-mail:yingchenghu@163.com
作者简介:曹菲(1995-),女,河南新乡人,本科生,主要从事椰壳纤维组分分离及利用研究工作
基金资助:
国家级大学生创新训练项目资助（201510225009）

Preparationand Characterization of Nanocellulose from Coconut Husk Fibers Based on Ionic Liquids

CAO Fei, ZHAO Xin, HU Yingcheng, CHEN Peipei, LI Huifang

Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Material Science and Engineering, Northeast Forestry University, Harbin 150040, China

Received:2017-03-14 Online:2017-10-25 Published:2017-10-30

摘要/Abstract

摘要： 采用酸性离子液体1-丁基-3-甲基咪唑硫酸氢盐（[Bmim][HSO₄]）/1，4-丁二醇/水体系对椰壳纤维进行组分分离，采用亚氯酸钠对综纤维素进行漂白处理得到纯纤维素，利用酸水解-超声波辅助法制备纳米纤维素。采用扫描电子显微镜（SEM）、透射电子显微镜（TEM）、傅里叶红外光谱（FT-IR）仪、X射线衍射（XRD）仪、热重分析（TG）对纳米纤维素的形貌、化学成分、结晶度、热性能进行表征，并探讨了[Bmim][HSO₄]对纳米纤维素得率及性能的影响。结果表明：[Bmim][HSO₄]提高了木质素脱除率，提高了纤维素的易处理性，有利于纯纤维素的制备；椰壳纤维纳米纤维素仍具有纤维素的基本化学结构和结晶结构，属于纤维素I型；离子液体使得综纤维素质量损失率提高，进而导致纳米纤维素得率降低；椰壳纤维纳米纤维素纤丝平均长度（271±81） nm，平均直径（6.3±1.8） nm，[Bmim][HSO₄]对纳米纤维素粒径尺寸分布（3~9 nm）无明显影响。

关键词: 纳米纤维素, 1, 4-丁二醇, 离子液体

Abstract: The main components of coconut husk fibers was separated by the 1,4-butylene glycol/water system combined with 1-butyl-3-methylimidazolium hydrogen sulfate([Bmim] [HSO₄]) as a catalyst, and the cellulose-rich material was subjected to bleaching treatment of sodium chlorite to obtain pure cellulose. Then, the nanocellulose was prepared by acid hydrolysis followed by ultrasonication. The morphological behavior, chemical characterization, crystallinity index, thermostability of nanocellulose were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), Fourier transform infrared spectroscopy(FT-IR), X-ray diffraction(XRD) and thermogravimetric analysis(TG). The effects of[Bmim] [HSO₄] on the yield and properties of nanocellulose were investigated. The results showed that[Bmim] [HSO₄] the extraction rate of lignin and the disposability of the cellulose, which was beneficial to the preparation of pure cellulose. Nanocellulose from coconut husk fibers still maintain the basic chemical structure and the cellulose I crystalline structure. The[Bmim] [HSO₄] increased the mass loss rate of the cellulose, which led to the decrease of the nanocellulose yield. The nanocellulose from Coconut husk fiber based on ionic liquid exhibited an average length of(271±81)nm and a diameter of(6.3±1.8)nm.[Bmim] [HSO₄] had no significant effect on the size of diameter(3-9 nm).

Key words: nanocellulose, 1,4-butylene glycol, ionic liquid

中图分类号:

TQ35

曹菲, 赵鑫, 胡英成, 陈培培, 李慧芳. 基于离子液体的椰壳纤维纳米纤维素的制备与表征[J]. 林产化学与工业, 2017, 37(5): 139-145.

CAO Fei, ZHAO Xin, HU Yingcheng, CHEN Peipei, LI Huifang. Preparationand Characterization of Nanocellulose from Coconut Husk Fibers Based on Ionic Liquids[J]. Chemistry and Industry of Forest Products, 2017, 37(5): 139-145.

参考文献

[1] NASCIMENTO D M,ALMEIDA J S,DIAS A F,et al. A novel green approach for the preparation of cellulose nanowhiskers from white coir[J]. Carbohydrate Polymers,2014,110:456-463.
[2] 陈文帅,于海鹏,李勍,等.纳米纤维素机械法制备与应用基础[M].北京:科学出版社,2014. CHEN W S,YU H P,LI Q,et al. Preparation and Application of Nanocellulose by Mechincal method[M]. Beijing:Science Press,2014.
[3] HUANG H J,YUAN X Z,ZHU H N,et al. Comparative studies of thermochemical liquefaction characteristics of microalgae,lignocellulosic biomass and sewage sludge[J]. Energy,2013,56:52-60.
[4] RAMLI N A S,AMIN N A S. Catalytic hydrolysis of cellulose and oil palm biomass in ionic liquid to reducing sugar for levulinic acid production[J]. Fuel Processing Technology,2014,128:490-498.
[5] 孙茉莉,刘钧,付严,等. 离子液体-乙醇-水体系水热法分离毛竹组分[J]. 过程工程学报,2016,16(1):86-92. SUN M L,LIU J,FU Y,et al. Fractionation of bamboo in ionic liquid-ethanol-H₂O system by hydrothermal method[J].The Chinese Journal of Process Engineering,2016,16(1):86-92.
[6] 卢芸,孙庆丰,于海鹏,等. 离子液体中的纤维素溶解、再生及材料制备研究进展[J]. 有机化学,2010,30(10):1593-1602. LU Y,SUN Q F,YU H P,et al. Dissolution and regeneration of cellulose and development in processing cellulose-based materials with ionic liquids[J].Chinese Journal of Organic Chemistry,2010,30(10):1593-1602.
[7] 程芳超. 基于离子液体的农林生物质组分分离及催化转化研究[D]. 哈尔滨:东北林业大学博士学位论文,2015. CHENG F C. Fractionation and catalytic conversion of agricultural and forestry biomass based on ionic liquids[D]. Harbin:Doctoral Dissertation of Northeast Forestry University,2015.
[8] 李艳娜. 乙醇溶剂热法预处理木质纤维及制备纳米纤维素的研究[D]. 哈尔滨:东北林业大学硕士学位论文,2016. LI Y N. Pretreatment of lignocelluloses by ethanol solvothermal method and fabrication of nanocellulose[D].Harbin:Master Degree Thesis of Northeast Forestry University,2016.
[9] YOKOYAMA T,KADLA J F,CHANG H M. Microanalytical method for the characterization of fiber components and morphology of woody plants[J]. Journal of Agricultural and Food Chemistry,2002,50(5):1040-1044.
[10] SEGAL L,CREELY J J,MARTIN J A E,et al. An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer[J]. Textile Research Journal,1959,29(10):786-794.
[11] ZHANG Y,DU H,QIAN X,et al. Ionic liquid-water mixtures:Enhanced K_W for efficient cellulosic biomass conversion[J]. Energy & Fuels,2010,24(4):2410-2417.
[12] ROSA M F,MEDEIROS E S,MALMONGE J A,et al. Cellulose nanowhiskers from coconut husk fibers:Effect of preparation conditions on their thermal and morphological behavior[J]. Carbohydrate Polymers,2010,81(1):83-92.
[13] KARGARZADEH H,AHMAD I,ABDULLAH I,et al. Effects of hydrolysis conditions on the morphology,crystallinity,and thermal stability of cellulose nanocrystals extracted from kenaf bast fibers[J]. Cellulose,2012,19(3):855-866.
[14] 陈为健,程贤甦. 竹子高沸醇溶剂法制备纸浆纤维与木质素的研究[J]. 林产化学与工业,2004,24(1):34-38. CHEN W J,CHENG X S. Research on preparation of fiber and lignin from bamboo with high-boiling alcohol solvent[J]. Chemistry and Industry of Forest Products,2004,24(1):34-38.
[15] 朱宛萤,李利芬,胡英成. 乙二醇/碳酸乙烯酯预处理对椰壳纤维成分及结构的影响[J]. 林产化学与工业,2017,37(1):123-128. ZHU W Y,LI L F,HU Y C. Effect of ethylene glycol/ethylene carbohydrate pretreatment on components and structure of coconut fiber[J]. Chemistry and Industry of Forest Products,2017,37(1):123-128.

基于离子液体的椰壳纤维纳米纤维素的制备与表征

Preparationand Characterization of Nanocellulose from Coconut Husk Fibers Based on Ionic Liquids

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