半纤维素基功能材料的研究进展

doi:10.3969/j.issn.0253-2417.2017.06.002

摘要/Abstract

摘要： 综述了近年来半纤维素基功能材料包括半纤维素膜、水凝胶、吸附材料、医用材料和催化剂载体的研究进展，并对其未来应用前景进行了展望。半纤维素膜可以作为包装材料和食品包覆膜，但要解决其强度和韧性低的问题；半纤维素水凝胶可以采用物理和化学交联的方法制备，在医药和环境等领域具有较好的应用前景，但要解决化学交联水凝胶生物相容性较差及物理交联水凝胶强度不够等问题；此外，半纤维素还可以作为吸附材料用于废水和空气净化，作为医用材料用于药物缓释和抗菌，作为催化剂载体用于化学合成，将来还有望在光电材料、组织工程材料等领域得到应用。

关键词: 半纤维素, 膜, 水凝胶, 催化剂载体, 吸附材料, 医用材料

Abstract: The research progresses in recent years in the functional materials of hemicelluloses including membrane, hydrogel, absorbent, medical material and catalyst support were reviewed. In addition, the application prospect of hemicelluloses-based functional materials was addressed. Hemicelluloses-based membrane can be used as packing material and food wrapping material, but the problem of lower strength and flexibility should be solved. Hemicelluloses-based hydrogel can be prepared by chemical and physical cross-linking and utilized in medical and environmental fields, but the biocompatibility of chemical cross-linking hydrogel and strength of physical cross-linking hydrogel should be further improved. Furthermore, the hemicelluloses can be applied as absorbent for cleaning waster water and air, as medical material for drug sustained release and antibiosis, and as catalyst support for chemical synthesis. In the future, the hemicelluloses would be expected to be used in the fields of photoelectrical material, tissue engineering material, et al.

Key words: hemicelluloses, membrane, hydrogel, catalyst support, absorbent, medical material

中图分类号:

TQ35

周帅, 苗庆显, 黄六莲, 陈礼辉. 半纤维素基功能材料的研究进展[J]. 林产化学与工业, 2017, 37(6): 10-18.

ZHOU Shuai, MIAO Qingxian, HUANG Liulian, CHEN Lihui. Research Progress in Hemicellulose-based Functional Materials[J]. Chemistry and Industry of Forest Products, 2017, 37(6): 10-18.

参考文献

[1] 吴述平. 半纤维素-壳聚糖基生物功能材料及其应用[D]. 武汉:武汉大学博士学位论文,2014. WU S P. Studies and application of functional biomaterials based on hemicellulose-chitosan[D]. Wuhan:Doctoral Dissertation of Wuhan University,2014.
[2] 裴继诚. 植物纤维化学[M]. 北京:中国轻工业出版社,2014. PEI J C. Plant Fiber Chemistry[M]. Beijing:China Light Industry Press,2014.
[3] 林妲,彭红,余紫苹,等. 半纤维素分离纯化研究进展[J]. 中国造纸,2011,30(1):60-64. LIN D,PENG H,YU Z P,et al. Research progress in separation and purification of hemicelluloses[J]. China Pulp & Paper,2011,30(1):60-64.
[4] 余紫苹,彭红,林妲,等. 植物半纤维素结构研究进展[J]. 高分子通报,2011,23(6):48-54. YU Z P,PENG H,LIN D,et al. The structure characteristic of hemicellulose:A review[J]. Polymer Bulletin,2011,23(6):48-54.
[5] 孙辉,胡宇,杨彪,等. 农林生物质残余物的高值化利用:半纤维素的提取、改性及应用研究进展[J]. 中国塑料,2016,30(4):12-22. SUN H,HU Y,YANG B,et al. Valorization of agricultural and forestry biomass byproducts:Progress in isolation,modification and application of hemicelluloses[J]. China Plastics,2016,30(4):12-22.
[6] 张伯坤,张美云,李金宝.半纤维素提取技术及综合利用研究进展[J]. 黑龙江造纸,2009,37(3):12-14. ZHANG B K,ZHANG M Y,LI J B. Research progress in extraction technology and comprehensive uilization of hemicelluloses[J]. Heilongjiang Pulp & Paper,2009,37(3):12-14.
[7] SUN R C,SUN X F,TOMKINSON J. Hemicellulose:Science and Technology[M]. Washington DC:American Chemical Society,2004.
[8] 于庆雪,王海松,褚夫强,等. 新型半纤维素膜材料的制备与性能研究[J]. 造纸科学与技术,2014,33(2):30-34. YU Q X,WANG H S,CHU F Q,et al. Preparation and characterization of hemicellulose-based films[J]. Paper Science & Technology,2014,33(2):30-34.
[9] 王忠良. 蔗渣半纤维素基可食膜材料的制备及其保鲜性能研究[D]. 昆明:昆明理工大学硕士学位论文,2013. WANG Z L. Preparation and preservation of bagasse hemicellulose-based edible membrane matevials[D]. Kunming:Master Degree Thesis if Kunming University of Science and Technology,2013.
[10] 梁玉芝.半纤维素/壳聚糖复合膜的制备及性能研究[D]. 济南:齐鲁工业大学硕士学位论文,2015. LIANG Y Z. Preparation and properties of hemicellulose/chitosan composite membranes[D]. Jinan:Master Degree Thesis of Qilu University of Technology,2015.
[11] HANSEN N M L,PLACKETT D. Sustainable films and coatings form hemicelluloses:A review[J]. Biomacromolecules,2008,9(6):1493-1505.
[12] GRÖNDAHL M,ERIKSSON L,GATENHOLM P. Material properties of plasticized hardwood xylans for potential application as oxygen barrier films[J]. Biomacromelecules,2004,5(4):1528-1535.
[13] WANG S Y,REN J L,LI W Y,et al. Properties of polyvinyl alcohol/xylan composite films with citric acid[J]. Carbohydrate Polymers,2014,103(1):94-99.
[14] HARTMAN J,ALBERTSSON A C,LINDBLAD M S,et al. Oxygen barrier materials from renewable sources:Material properties of softwood hemicellulose-based films[J]. Journal of Applied Polymer Science,2006,100(4):2985-2991.
[15] ZHANG P Y,WHISTLER R L. Mechanical properties and water vapor permeability of thin film from corn hull arabinoxylan[J]. Journal of Applied Polymer Science,2004,93(6):2896-2902.
[16] GRÖNDAHL M,GUSTAFSSON A,GATENHOLM P. Gas-phase surface fluorination of arabinoxylan films[J]. Macromolecules,2006,39(7):2718-2721.
[17] PEROVAL C,DEBEAUFORT F,SEUVER A M,et al. Modified arabinoxylan-based films:Grafting of functional acrylates by oxygen plasma and electron beam irradiation[J]. Journal of Membrane Science,2004,233(1):129-139.
[18] HARTMAN J,ALBERTSSON A C,SJOBERG J. Surface-and bulk-modified galactoglucomannan hemicellulose films and film laminates for versatile oxygen barriers[J]. Biomacromolecules,2006,7(6):1983-1989.
[19] SAXENA A,ELDER T J,PAN S,et al. Novel nanocellulosic xylan composite film[J]. Composites Part B:Engineering,2009,40(8):727-730.
[20] PENG X W,REN J L,SUN R C,et al. Nanocomposite films based on xylan-rich hemicelluloses and cellulose nanofibers with enhanced mechanical properties[J]. Biomacromolecules,2011,12(9):3321-3329.
[21] 关莹. 竹材半纤维素基软材料的制备及性能研究[D]. 广州:华南理工大学博士学位论文,2015. GUAN Y. Preparation and properties of bamboo hemicellulose-based soft materials[D]. Guangzhou:Doctoral Dissertation of South China University of Technology,2015.
[22] 程合丽,冯清华,陈洪雷,等. 半纤维素基水凝胶制备方法研究进展[J]. 造纸科学与技术,2015,34(6):40-45. CHENG H L,FENG Q H,CHEN H L,et al. Progress in preparation methods of hemicellulose-based hydrogels[J]. Paper Science & Technology,2015,34(6):40-45.
[23] PENG X W,REN J L,SUN R C,et al. Xylan-rich hemicelluloses-graft-acrylic acid ionic hydrogels with rapid responses to pH,salt,and organic solvents[J]. Journal of Agricultural and Food Chemistry,2012,59(15):8208-8215.
[24] YANG J Y,ZHOU X S,FANG J. Synthesis and characterization of temperature sensitive hemicellulose-based hydrogels[J]. Carbohydrates Research,2011,86(3):1113-1117.
[25] KUZMENKO V,HÄGG D,TORIZ G,et al. In situ forming spruce xylan-based hydrogen for cell immobilization[J]. Carbohydrates Polymers,2014,102(5):862-868.
[26] MEENA R,LEHNEN R,SAAKE B. Microwave-assisted synthesis of kC/xylan/PVP-based blend hydrogel materials:Physicochemical and rheological studies[J]. Cellulose,2014,21(1):553-568.
[27] ZHAO W,GLAVAS L,ODELIUS K,et al. Facile and green approach towards electrically conductive hemicellulose hydrogels with tunable conductivity and swelling behavior[J]. Chemistry of Materials,2014,26(14):4265-4273.
[28] GABRIELⅡ I,GATENHOLM P,GLASSER W G,et al. Separation,characterization and hydrogel-formation of hemicelluloses from aspen wood[J]. Carbohydrate Polymers,2000,43(4):367-374.
[29] GUAN Y,BIAN J,PENG F,et al. High strength of hemicelluloses based hydrogels by freeze/thaw technique[J]. Carbohydrate Polymers,2014,101(3),272-280.
[30] GUAN Y,ZHANG B,TAN X,et al. Organic-inorganic composite films based on modified hemicelluloses with clay nanoplatelets[J]. ACS Sustainable Chemistry & Engineering,2014,2(7):1811-1818.
[31] REN J L,WANG S Y,GAO C D,et al. TiO₂-containing PVA/xylan composite films with enhanced mechanical properties,high hydrophobicity and UV shielding performance[J]. Cellulose,2015,22(1):593-602.
[32] TANODEKAEW S,CHANNASANON S,UPPANAN P. Xylan/polyvinyl alcohol blend and its performance as hydrogel[J]. Journal of Applied Polymer Science,2006,100(3):1914.
[33] LUKANOFF B. Charaterization of hemicellulose from spent liquors and derivatives based on them[J]. Khlim Drev,1991,4(1):45-47.
[34] 王利军. 蔗渣半纤维素化学改性及其吸附重金属的研究[D]. 南宁:广西大学博士学位论文,2013. WANG L J. A study on preparation and heavy metals adsorption characteristics of chemically modified sugarcane bagasse hemicelluloses[D]. Nanning:Doctoral Dissertation of Guangxi University,2013.
[35] WU S P,HU J,WEI L T,et al. Construction of porous chitosan-xylan-TiO₂ hybrid with highly efficient sorption capability on heavy metals[J].Journal of Environmental Chemical Engineering,2014,2(3):1568-1577.
[36] 李冬雪,朱红祥,王利军,等. 改性半纤维素吸附剂的制备及其对Pb²⁺的吸附[J]. 造纸科学与技术,2016,35(4):8-12. LI D X,ZHU H X,WANG L J,et al. Preparation and characterization of modified hemicellulose and its application for adsorption of Pb²⁺[J]. Paper Science & Technology,2016,35(4):8-12.
[37] 孔维庆. 基于蔗渣和半纤维素吸附材料的制备及其吸附性能的研究[D]. 广州:华南理工大学硕士学位论文,2015. KONG W Q. Preparation of adsorption materials based on sugarcane bagasse and hemicelluloses and their adsorption properties[D]. Guangzhou:Master Degree Thesis of South China University of Technology,2015.
[38] 林冠烽,蒋剑春,吴开金. 磷酸活化法制备半纤维素基颗粒活性炭[J]. 生物质化学工程,2013,47(3):6-10. LIN G F,JIANG J C,WU K J. Preparation of hemi-cellulose-based granular activated carbon by phosphoric acid activation[J]. Biomass Chemical Engineering,2013,47(3):6-10.
[39] PENG X W,REN J L,SUN R C,et al. Highly effective adsorption of heavy metal ions from aqueous solutions by macroporous xylan-rich hemicelluloses-based hydrogel[J]. Journal of Agricultural and Food Chemistry,2012,60(15):3909-3916.
[40] WU S P,HU J,WEI L T,et al. Antioxidant and antimicrobial activity of Maillard reaction products from xylan with chitisan/chitioligomer/glucosamine hydrochloride/taurine model systems[J]. Food Chemistry,2014,148(3):196-203.
[41] 彭新文. 功能化半纤维素高效合成及其材料应用研究[D]. 广州:华南理工大学博士学位论文,2012. PENG X W. Efficient synthesis and applications of functional gemicelluloses[D]. Guangzhou:Doctoral Dissertation of South China University of Technology,2012.
[42] DAUS S,HEINZE T. Xylan-based nanoparticles:Prodrugs for ibuprofen release[J]. Macromolecular Bioscience,2010,10(2):211-220.
[43] 全金英,王佩卿. 羧甲基变性半纤维素的制备及应用前景[J]. 林产化学与工业,1997,17(4):25-31. QUAN J Y,WANG P Q. Preparation of carboxymethyl modified hemicellulose and its application potential[J]. Chemistry and Industry of Forest Products,1997,17(4):25-31.
[44] EBRINGEROVÁ A,BELICOVÁ A,EBRINGER L. Antimicrobial activity of quatermized heteroxylans[J]. World Journal of Microbiology & Biotechnology,1994,10(6):640-644.
[45] 陈巍. 生物质基催化剂的制备及其催化性能研究[D].广州:华南理工大学博士学位论文,2015. CUI W. Preparation and catalytic properties of biomass-based catalysts[D]. Guangzhou:Doctoral Dissertation of South China University of Technology,2015.
[46] LUO Y Q,SHEN S Q,LUO J W,et al. Green synthesis of silver nanoparticles in xylan solution via tollens reaction and their detection for Hg²⁺[J]. Nanoscale,2015,7(2):690-700.
[47] HABIBI Y,DUFRESNE A. Highly filled bionanocomposites from functionalized polysaccharide nanocrystals[J]. Biomacromolecules,2008,9(7):1974-1980.
[48] 吴昌艳. 半纤维素基过渡金属催化剂的制备及其催化性能的研究[D]. 广州:华南理工大学硕士学位论文,2016. WU C Y. Preparation and catalytic performance of hemicelluloses supported noble metal compounds[D]. Guangzhou:Master Degree Thesis of South China University of Technology,2016.
[49] 彭新文,谭杰文,吴昌艳,等. 半纤维素-g-壳聚糖负载钯(O)催化剂的制备与催化性能[J].华南理工大学学报:自然科学版,2016,44(6):27-35. PENG X W,TAN J W,WU C Y,et al. Preparation and catalysis performance of hemicelluloses-g-chitosan-Pd(O) catalyst[J]. Journal of South China University of Technology:Natural Science Edition,2016,44(6):27-35.
[50] WU C Y,PENG X W,ZHONG L X,et al. Green synthesis of palladium nanoparticles via branched polymers:A bio-based nanocompositefor C-C coupling reactions[J]. RSC Advances,2016,6(38):32202-32211.
[51] CHEN W,ZHONG L X,PENG X W,et al. Xylan-type hemicelluloses supported terpyridine-palladium(Ⅱ) complex as an efficient and recyclable catalyst for Suzuki-Miyaura reation[J]. Cellulose,2013,21(1):125-137.
[52] 孙晓锋,李驰,夏修阳,等. 半纤维素/TiO₂复合凝胶的光催化降解性能[J]. 化工学报,2016,5(5):2070-2077. SUN X F,LI C,XIA X Y,et al. Photocatalytic degradation property of hemicellulose/TiO₂ composite gel[J]. Journal of Chemical Industry and Engineering,2016,5(5):2070-2077.