两性高分子表面活性剂CHPDMDHA-g-N,O-CMC的合成、表征及性能

doi:10.3969/j.issn.0253-2417.2018.01.017

林产化学与工业 ›› 2018, Vol. 38 ›› Issue (1): 115-120.doi: 10.3969/j.issn.0253-2417.2018.01.017

两性高分子表面活性剂CHPDMDHA-g-N,O-CMC的合成、表征及性能

李漫^1,2, 裴立军^1,2, 蔡照胜¹, 房桂干²

1. 盐城工学院化学化工学院, 江苏盐城 224051;
2. 中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2017-06-07 出版日期:2018-02-25 发布日期:2018-02-28
通讯作者: 蔡照胜,教授,硕士生导师,研究领域为生物质化学改性与利用及化工"三废"资源化利用;E-mail:jsyc_czs@163.com。 E-mail:jsyc_czs@163.com
作者简介:李漫(1992-),女,山东枣庄人,硕士生,主要从事制浆造纸和松脂化学利用研究
基金资助:
江苏省生物质能源与材料重点实验室开放基金项目资助（JSBEM201607）；国家自然科学基金面上项目资助（31170543）

Synthesis,Characterization and Properties of Amphoteric Polymeric Surfactant CHPDMDHA-g-N,O-CMC

LI Man^1,2, PEI Lijun^1,2, CAI Zhaosheng¹, FANG Guigan²

1. School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China;
2. Institute of Chemical Industry of Forestry Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2017-06-07 Online:2018-02-25 Published:2018-02-28

摘要/Abstract

摘要： 在25% NaOH溶液催化下，通过3-氯-2-羟丙基二甲基脱氢枞基氯化铵（CHPDMDHA）与N，O-羧甲基壳低聚糖（N，O-CMC）缩合，得到3-氯-2-羟丙基二甲基脱氢枞基氯化铵接枝N，O-羧甲基壳低聚糖（CHPDMDHA-g-N，O-CMC）；采用FT-IR和¹H NMR表征了产物结构，元素分析法确定了产物接枝度（D_Q）；根据CHPDMDHA-g-N，O-CMC水溶液表面张力随浓度的变化，确定了其临界胶束浓度（C_CMC）及对应的表面张力（γ_CMC）；根据振荡乳化法得到的苯/水体系乳状液稳定时间研究了产物的乳化能力。结果表明：对于接枝度分别为18.7%、21.5%和23.1%的CHPDMDHA-g-N，O-CMC，其C_CMC值分别为4.82×10^-4、1.33×10^-4和7.50×10^-5 mol/L，γ_CMC分别为35.1、33.7和32.7 mN/m；接枝度为23.1%的CHPDMDHA-g-N，O-CMC，其1.0 g/L的水溶液与等体积的苯构成的乳液的稳定时间为195 s，大于同等条件下蔗糖酯和单甘酯为乳化剂时形成的乳液。

关键词: 接枝改性, 表面活性, 乳化性能

Abstract: 3-Chloro-2-hydroxypropyl dimethyl dehydroabietyl ammonium chloride grafted N,O-carboxymethyl chitosan oligosaccharide (CHPDMDHA-g-N,O-CMC) was obtained through the grafting reaction between 3-chloro-2-hydroxypropyl dimethyl dehydroabietyl ammonium chloride (CHPDMDHA) and N,O-carboxymethyl chitosan oligosaccharide (N,O-CMC) with 25% NaOH aqueous solution as catalyst.The structure of CHPDMDHA-g-N,O-CMCs was confirmed by FT-IR and ¹H NMR,and the grafting degree (D_Q) of CHPDMDHA-g-N,O-CMCs was determined by elemental analysis.The critical micelle concentration (C_CMC) and surface tension (γ_CMC) were determinated according to the variation of the surface tension of CHPDMDHA-g-N,O-CMCs in aqueous solution with the concentration.The emulsifying power of CHPDMDHA-g-N,O-CMCs was investigated according to the stability time of emulsion which was formed by oscillametric method and composed of water and benzene.The experimental results showed when the grafting degrees of CHPDMDHA-g-N,O-CMCs were 18.7%,21.5% and 23.1%,the critical micelle concentrations were 4.82×10^-4,1.33×10^-4 and 7.50×10^-5 mol/L,the surface tensions at cmc ware 35.1,33.7 and 32.7 mN/m,respectively.The stability time of emulsion composed of 1.0 g/L CHPDMDHA-g-N,O-CMC,whose D_Q was 23.1%,aqueous solution and benzene at the same volume was up to 195s,which was the longest one among CHPDMDHA-g-N,O-CMC3,sucrose stearate and monoglyceride.

Key words: grafting modification, surface activity, emulsion power

中图分类号:

TQ35

李漫, 裴立军, 蔡照胜, 房桂干. 两性高分子表面活性剂CHPDMDHA-g-N,O-CMC的合成、表征及性能[J]. 林产化学与工业, 2018, 38(1): 115-120.

LI Man, PEI Lijun, CAI Zhaosheng, FANG Guigan. Synthesis,Characterization and Properties of Amphoteric Polymeric Surfactant CHPDMDHA-g-N,O-CMC[J]. Chemistry and Industry of Forest Products, 2018, 38(1): 115-120.

参考文献

[1] GUO X R,QIU F X,DONG K,et al. Preparation,characterization and scale performance of scale inhibitor copolymer modification with chitosan[J]. Journal of Industrial and Engineering Chemistry,2012,18(6):2177-2183.
[2] VAN DER LUBBEN I M,VERHOEF J C,BORCHARD G,et al. Chitosan and its derivatives in mucosal drug and vaccine delivery[J]. European Journal of Pharmaceutical Science,2001,14(3):201-207.
[3] JAYAKUMAR R,PRABAHARAN M,REIS R L,et al. Graft copolymerized chitosan:Present status and applications[J]. Carbohydrate Polymers,2005,62(2):142-158.
[4] RAVI KUMAR M N V. A review of chitin and chitosan applications[J]. Reactive and Functional Polymers,2000,46(1):1-27.
[5] LOGITHKUMAR R,KESHAVNARAYAN A,DHIVYA S,et al. A review of chitosan and its derivatives in bone tissue engineering[J]. Carbohydrate Polymers,2016,151:172-188.
[6] LIU X F,WANG Q,ZHUANG X P,et al. Study on antibacterial activity of O-carboxymethyl chitosan sodium salt and spinnability of O-carboxymethyl chitosan sodium salt/cellulose polyblends in N-methylmorpholine-N-oxide system[J]. Carbohydrate Polymers,2012,89(1):104-110.
[7] NORDTVEIT HJERDE R J,VARUM K M,GRASDALEN H,et al. Chemical composition of O-(carboxymethyl)-chitin in relation to lysozyme degradation rates[J]. Carbohydrate Polymers,1997,34(3):131-139.
[8] PEI L J,CAI Z S,SONG Z Q,et al. 3-Chloro-2-hydroxypropyl dimethyl dehydroabietyl ammonium chloride:Synthesis,characterization,and physicochemical properties[J]. Journal of Surfactants and Detergents,2014,17(3):493-499.
[9] 朱雪梅,蒋士猛,蔡照胜,等. 3-氯-2-羟丙基二甲基脱氢枞基氯化铵的制备及其表面活性研究[J]. 林产化学与工业,2014,34(3):116-120. ZHU X M,JIANG S M,CAI Z S,et al. Preparation of 3-chloro-2-hydroxypropyl dimethyl dehydroabietyl ammonium chloride and its surface activities[J]. Chemistry and Industry of Forest Products,2014,34(3):116-120.
[10] HONG P,FA C,WEI Y P,et al. Surface properties and synthesis of the cellulose-based amphoteric polymeric surfactant[J].Carbohydrate Polymers,2007,69(4):625-630.
[11] CAI Z S,SONG Z Q,SHANG S B,et al. Study on the flocculating properties of quaternized carboxymethyl chitosan[J]. Polymer Bulletin,2007,59(5):655-665.
[12] CAI Z S,YANG C S,ZHU X M. Preparation of quaternized carboxymethyl chitosan and its capacity to flocculate COD from printing wastewater[J]. Journal of Applied Polymer Science,2010,118(1):299-305.
[13] HEBEISH A,HIGAZY A,EL-SHAFEI A,et al. Synthesis of carboxymethyl cellulose(CMC) and starch-based hybrids and their applications in flocculation and sizing[J]. Carbohydrate Polymers,2010,79(1):60-69.
[14] ZAMAN M,XIAO H N,CHIBANTE F,et al. Synthesis and characterization of cationically modified nanocrystalline cellulose[J]. Carbohydrate Polymers,2012,89(1):163-170.
[15] QI F,CAI Z S,ZHU X M,et al. Synthesis,characterization,and performance of a novel polymeric cationic surfactant based on low molecular weight chitosan and 3-chloro-2-hydroxypropyl dimethyl dehydroabietyl ammonium chloride(CHPDMDHA)[J]. Journal of Surfactants and Detergents,2015,18(3):463-470.
[16] HUANG K S,WU W J,CHEN J B,et al. Application of low molecular weight chitosan in durable press finishing[J]. Carbohydrate Polymers,2008,73(2):254-260.

两性高分子表面活性剂CHPDMDHA-g-N,O-CMC的合成、表征及性能

Synthesis,Characterization and Properties of Amphoteric Polymeric Surfactant CHPDMDHA-g-N,O-CMC

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们

[1]	王凤, 龙柱, 陈杰, 王斌, 张凤山. 腰果酚聚氧乙烯醚复配脱墨剂的制备及应用[J]. 林产化学与工业, 2017, 37(6): 95-100.
[2]	闫鑫焱, 饶小平, 宋湛谦, 商士斌. 聚萜烯马来酸酐聚乙二醇酯高分子表面活性剂的制备及性能研究[J]. 林产化学与工业, 2017, 37(2): 129-134.
[3]	宋冰蕾, 余小娜, 陈燕, 裴晓梅, 周萍萍, 翟兆兰. 含酰胺基团松香基双子表面活性剂的合成与性能[J]. 林产化学与工业, 2015, 35(6): 39-46.
[4]	郑建强, 刘莉, 饶小平, 宋湛谦, 商士斌. 松香基胆碱季铵盐表面活性剂的合成及抑菌活性研究[J]. 林产化学与工业, 2015, 35(5): 98-104.
[5]	王奎, 蒋剑春, 卢辛成, 徐俊明, 梁馨予. 超声波辅助下K₂O/C催化制备纤维低聚糖脂肪酸酯表面活性剂[J]. 林产化学与工业, 2015, 35(4): 72-78.
[6]	贝俊杰, 曹云峰. 疏水改性羧甲基纤维素及其在废纸脱墨中的应用[J]. 林产化学与工业, 2015, 35(3): 80-84.
[7]	毛翠平, 武书彬. 有机改性硅藻土对聚乙酸乙烯酯乳液吸附性能及其动力学的研究[J]. 林产化学与工业, 2014, 34(6): 8-12.
[8]	黄秀芝, 饶小平, 薛志革, 崔艳杰. 松香酯羟丙基季铵盐表面活性剂的合成、表征及性能[J]. 林产化学与工业, 2014, 34(6): 75-80.
[9]	王娟, 王丹, 商士斌, 沈明贵, 齐帆. 松香基季铵盐型杂双子表面活性剂的合成及性能研究[J]. 林产化学与工业, 2014, 34(6): 111-116.
[10]	裴立军, 蔡照胜, 商士斌, 宋湛谦. 脱氢枞胺-壳聚糖阳离子表面活性剂的合成及性能研究[J]. 林产化学与工业, 2014, 34(5): 47-52.
[11]	王娟, 王丹, 商士斌, 沈明贵, 齐帆. 松香基聚氧乙烯胺型双子表面活性剂的合成及性能研究[J]. 林产化学与工业, 2014, 34(5): 109-114.
[12]	田金玲, 任世学, 方桂珍, 艾青. 二甲基-正丁基-磺化木质素基氯化铵的合成及性能研究[J]. 林产化学与工业, 2014, 34(4): 42-50.
[13]	朱雪梅, 蒋士猛, 蔡照胜, 陈智栋. 3-氯-2-羟丙基二甲基脱氢枞基氯化铵的制备及其表面活性研究[J]. 林产化学与工业, 2014, 34(3): 116-120.
[14]	庄志良, 祝黎, 吴伟兵, 戴红旗. 纤维素非均相ATRP接枝聚合的研究进展[J]. 林产化学与工业, 2014, 34(3): 121-129.
[15]	林广沅, 吴国民, 孔振武. 表面活性剂对有机硅包覆松香基环氧树脂微胶囊的影响[J]. 林产化学与工业, 2014, 34(1): 25-30.