马来松香季戊四醇酯对椪柑保鲜效果的研究

doi:10.3969/j.issn.0253-2417.2020.06.003

林产化学与工业 ›› 2020, Vol. 40 ›› Issue (6): 15-22.doi: 10.3969/j.issn.0253-2417.2020.06.003

马来松香季戊四醇酯对椪柑保鲜效果的研究

张海波¹(), 许嘉琍¹, 姚姝凤¹, 高宏¹^,², 商士斌¹^,*()

1. 中国林业科学研究院林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业和草原局林产化学工程重点开放性实验室; 江苏省生物质能源与材料重点实验室江苏省林业资源高效加工利用协同创新中心, 江苏南京 210042
2. 中国林业科学研究院林业新技术研究所, 北京 100091

收稿日期:2020-06-23 出版日期:2020-12-28 发布日期:2020-12-29
通讯作者: 商士斌 E-mail:shdzhanghaibo@163.com;shangsb@163.com
作者简介:商士斌, 研究员, 博士生导师, 研究领域为天然资源化学与利用; E-mail:shangsb@163.com
张海波(1990-), 男, 山东菏泽人, 助理研究员, 从事松脂化学与利用的研究; E-mail:shdzhanghaibo@163.com
基金资助:
国家重点研发计划资助项目(2016YFD0600804)

Study on Preservation Effect of Maleric Rosin Pentaerythritol on Ponkan

Haibo ZHANG¹(), Jiali XU¹, Shufeng YAO¹, Hong GAO¹^,², Shibin SHANG¹^,*()

1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; Key Lab. of Biomass Energy and Material, Jiangsu Province; Jiangsu Co-Innovation Center for Efficient Processing and Utilization of Forest Resources, Nanjing 210042, China
2. Research Institute of Forestry New Technology, CAF, Beijing 100091, China

Received:2020-06-23 Online:2020-12-28 Published:2020-12-29
Contact: Shibin SHANG E-mail:shdzhanghaibo@163.com;shangsb@163.com

摘要/Abstract

摘要：

为探讨松香基保鲜剂对柑橘果实采后的保鲜效果，以马来松香季戊四醇酯（MRPE）为主要成分制备保鲜剂，在室温下对椪柑进行采后涂膜保鲜处理，每隔6 d测定相关指标并与市售保鲜剂吗啉脂肪酸盐（MFAS）的保鲜效果进行对比，且以清水处理样品为空白对照。研究结果表明：当贮藏至42 d时，MRPE涂膜处理的椪柑的失重率仅为11.39%，比空白对照组低31.39%；硬度为1.61 N，硬度变化明显小于MFAS涂膜处理组和空白对照组。MRPE和MFAS涂膜处理均能抑制椪柑中可溶性固形物和可滴定酸的变化，以及丙二醛（MDA）含量的上升。椪柑中超氧化物歧化酶（SOD）、过氧化物酶（POD）和过氧化氢酶（CAT）的活性提高，贮藏42 d时，SOD、POD和CAT的活性分别为9.90、1.26和1.02 U/g。综合各指标发现，MRPE涂膜处理对椪柑的保鲜效果优于市售保鲜剂MFAS涂膜处理，表明马来松香季戊四醇酯在椪柑贮藏保鲜方面有很好的应用前景。

关键词: 马来松香季戊四醇酯, 椪柑, 涂膜, 保鲜

Abstract:

In order to explore the preservation effect of rosin-based antistaling agent on postharvest citrus fruits, maleic rosin pentaerythritol ester(MRPE) was used as main component to prepare preservative, which was coated on ponkan for preservation and compared with uncoated ponkan and ponkan coated by morpholine fatty acid salt(MFAS) at room temperature storage conditions.Relevant indexes were measured every 6 days, and the results showed that after storing for 42 days, the weight loss rate of ponkan coated by MRPE coatings was 11.39%, which was 31.39% lower than that of the blank control group; firmness of ponkan coated by MRPE coatings was 1.61 N and the changes of firmness were lower than those coated by MFAS and the blank control; meanwhile, MRPE and MFAS coatings all could effectively inhibited the changes of soluble solids content and titratable acid content and the increase of malondialdehyde content(MDA). At the same time, the activities of superoxide dismutase(SOD), peroxidase(POD) and catalase(CAT) of ponkan coated by MRPE were increased which were 9.90, 1.26 and 1.02 U/g after storing for 42 days. These results showed that the preservation effect of MRPE coating treatment was better than that of MFAS treatment, which indicated that rosin resin had a good application prospect in postharvest preservation of ponkan.

Key words: maleric rosin pentaerythritol ester, ponkan, coating, preservation

中图分类号:

TQ35
S666.1

张海波, 许嘉琍, 姚姝凤, 高宏, 商士斌. 马来松香季戊四醇酯对椪柑保鲜效果的研究[J]. 林产化学与工业, 2020, 40(6): 15-22.

Haibo ZHANG, Jiali XU, Shufeng YAO, Hong GAO, Shibin SHANG. Study on Preservation Effect of Maleric Rosin Pentaerythritol on Ponkan[J]. Chemistry and Industry of Forest Products, 2020, 40(6): 15-22.

图/表 6

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涂膜类型 type of coating	不同贮藏时间下的硬度firmness under different storage time/N
涂膜类型 type of coating	0 d	7 d	14 d	21 d	28 d	35 d	42 d
空白对照blank control	2	1.53±0.23	1.49±0.26	1.47±0.07	1.45±0.17	1.70±0.17	1.99±0.20
MRPE	2	1.71±0.21	1.69±0.27	1.66±0.28	1.64±0.31	1.64±0.21	1.61±0.38
MFAS	2	1.57±0.16	1.56±0.30	1.55±0.31	1.54±0.22	1.54±0.20	1.47±0.35

涂膜类型 type of coating	超氧化物歧化酶酶活superoxide dismutase/(U·g^-1)
涂膜类型 type of coating	0 d	7 d	14 d	21 d	28 d	35 d	42 d
空白对照 blank control	7.29±0.45	7.49	7.58±0.46	7.85±0.21	8.51±1.50	8.06±0.35	7.46±0.04
MRPE	7.29±0.45	8.61±0.35	9.05±0.26	8.76±0.35	9.29±0.60	8.37±0.34	9.90±0.31
MFAS	7.29±0.45	7.74±0.19	7.42±0.23	7.58±0.31	7.90±0.37	7.79±0.68	8.16±0.64

涂膜类型 type of coating	过氧化物酶酶活peroxidase/(U·g^-1)
涂膜类型 type of coating	0 d	7 d	14 d	21 d	28 d	35 d	42 d
空白对照 blank control	0.79	1.34±0.01	1.08±0.06	1.02±0.02	0.78±0.01	0.73±0.01	0.49±0.01
MRPE	0.79	2.49±0.01	1.58±0.04	2.06±0.05	2.45±0.04	1.43±0.02	1.26±0.04
MFAS	0.79	1.54±0.05	0.78±0.03	2.41±0.01	0.91±0.01	0.82±0.01	1.28±0.01

涂膜类型 type of coating	过氧化氢酶酶活catalase/(U·g^-1)
涂膜类型 type of coating	0 d	7 d	14 d	21 d	28 d	35 d	42 d
空白对照 blank control	1.14±0.01	1.04±0.13	1.17±0.04	1.53±0.02	0.93±0.06	1.18±0.05	0.74±0.04
MRPE	1.14±0.01	1.45±0.01	1.40±0.01	1.47	1.15	1.14±0.05	1.02±0.03
MFAS	1.14±0.01	1.19±0.03	1.09±0.04	1.44±0.06	1.23±0.04	0.80±0.04	0.96±0.03

[1]	许嘉琍,张海波,姚姝凤,高宏,商士斌. 林业生物质基果蔬涂膜保鲜剂的研究进展[J]. 林产化学与工业, 2019, 39(3): 10-16.
[2]	薛兴颖,周昊,张昌伟,陈虹霞,王成章. 漆蜡复配涂膜保鲜剂的制备及抗菌、保鲜作用研究[J]. 林产化学与工业, 2019, 39(3): 123-128.
[3]	陈兵;杜予民. 漆酚镧螯合物的性质及对漆酚改性涂膜性能的影响研究[J]. 林产化学与工业, 2000, 20(3): 70-74.

马来松香季戊四醇酯对椪柑保鲜效果的研究

Study on Preservation Effect of Maleric Rosin Pentaerythritol on Ponkan

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