林产化学与工业 ›› 2021, Vol. 41 ›› Issue (4): 124-134.doi: 10.3969/j.issn.0253-2417.2021.04.016
收稿日期:
2020-08-14
出版日期:
2021-08-28
发布日期:
2021-08-31
通讯作者:
王霆
E-mail:thundersking@nefu.edu.cn
作者简介:
王霆, 教授, 硕士生导师, 研究领域为生物质资源高效利用; E-mail: thundersking@nefu.edu.cn基金资助:
Received:
2020-08-14
Online:
2021-08-28
Published:
2021-08-31
Contact:
Ting WANG
E-mail:thundersking@nefu.edu.cn
摘要:
木质素的降解往往会伴随其解聚中间体的再聚合,从而增加进一步降解的难度,严重影响木质素的降解率。因此,有效抑制中间体的再聚合是提高木质素降解率的关键。抑制再聚合可以通过改变木质素降解体系的反应路径或者反应环境来达到。主要从抑制或减少木质素再聚合的角度出发,综述了对反应体系添加阻聚剂、缩短反应停留时间和提供温和的反应环境3种有效方法来提高木质素的降解率。
中图分类号:
李梦竹, 王霆. 抑制木质素降解中间体再聚合的研究进展[J]. 林产化学与工业, 2021, 41(4): 124-134.
Mengzhu LI, Ting WANG. Research Progress in Inhibiting Repolymerization of Lignin Degradation Intermediates[J]. Chemistry and Industry of Forest Products, 2021, 41(4): 124-134.
表1
几种常用于木质素解聚的超临界有机溶剂"
超临界溶剂 supercritical solvent | 催化剂1) catalyst | 条件 conditions | 底物 substrate | 产品(产量) products(yield) | 参考文献 references |
甲醇methanol | Cu20La20PMO | 310 ℃,6 h | 桐树木质素 candlenut lignin | 生物油bio-oil (98%) | [ |
Ag掺杂的Mn2O3纳米片 Ag-doped Mn2O3 nanosheets | 180 ℃,2 h | 碱性木质素 alkali lignin | 液态乙醇liquid alcohols (42.5%) | [ | |
Fe3+,H2O2 | 250 ℃,3 h 6.5 MPa | 甜高粱渣木质素 sweet sorghum bagasse lignin | 酚醛树脂phenolic oil (75.85%) | [ | |
乙醇ethanol | Ru/C,Ni/ZSM-5,CuNiAl | 290 ℃,3 h | 碱性木质素 alkali lignin | 生物油bio-oil (81.8%) | [ |
WO3/γ-Al2O3 | 320 ℃,8 h | 酶解木质素 enzymatic hydrolysis lignin | 烷基酚alkylphenols (86.9%) | [ | |
Ru/C-MgO-ZrO2 | 320 ℃,4 h, 3 MPa-H2 | 有机溶剂木质素 organosolv lignin | 生物油bio-oil (76.2%), 酚类单体phenolic monomer(31.44%) | [ | |
丙酮acetone | 甲酸 formic acid | 300-370 ℃,10 MPa | 硬木hardwood, 麦秆木质素 wheat straw lignin | 丁香酚syringol (3.6%), 丁香酸syringic acid (2.0%) | [ |
1 |
KAWAMOTO H . Lignin pyrolysis reactions[J]. Journal of Wood Science, 2017, 63 (2): 117- 132.
doi: 10.1007/s10086-016-1606-z |
2 | CASIMIRO F M , COSTA C A E , BOTELHO C M , et al. Kinetics of oxidative degradation of lignin-based phenolic compounds in batch reactor[J]. Industrial & Engineering Chemistry Research, 2019, 58 (36): 16442- 16449. |
3 |
RENDERS T , BOSSCHE G V D , VANGEEL T , et al. Reductive catalytic fractionation: State of the art of the lignin-first biorefinery[J]. Current Opinion in Biotechnology, 2019, 56, 193- 201.
doi: 10.1016/j.copbio.2018.12.005 |
4 |
DEEPA A K , DHEPE P L . Lignin depolymerization into aromatic monomers over solid acid catalysts[J]. ACS Catalysis, 2015, 5 (1): 365- 379.
doi: 10.1021/cs501371q |
5 |
MAHMOOD N , YUAN Z S , SCHMIDT J , et al. Production of polyols via direct hydrolysis of kraft lignin: Effect of process parameters[J]. Bioresource Technology, 2013, 139, 13- 20.
doi: 10.1016/j.biortech.2013.03.199 |
6 |
HA J M , HWANG K R , KIM Y M , et al. Recent progress in the thermal and catalytic conversion of lignin[J]. Renewable and Sustainable Energy Reviews, 2019, 111, 422- 441.
doi: 10.1016/j.rser.2019.05.034 |
7 |
CHIO C L , SAIN M , QIN W S . Lignin utilization: A review of lignin depolymerization from various aspects[J]. Renewable and Sustainable Energy Reviews, 2019, 107, 232- 249.
doi: 10.1016/j.rser.2019.03.008 |
8 |
BARTA K , MATSON T D , FETTIG M L , et al. Catalytic disassembly of an organosolv lignin via hydrogen transfer from supercritical methanol[J]. Green Chemistry, 2010, 12 (9): 1640- 1647.
doi: 10.1039/c0gc00181c |
9 |
OUYANG X P , RUAN T , QIU X Q , et al. Effect of solvent on hydrothermal oxidation depolymerization of lignin for the production of monophenolic compounds[J]. Fuel Processing Technology, 2016, 144, 181- 185.
doi: 10.1016/j.fuproc.2015.12.019 |
10 |
HUANG X M , ATAY C , KORANYI T I , et al. Role of Cu-Mg-Al mixed oxide catalysts in lignin depolymerization in supercritical ethanol[J]. ACS Catalysis, 2015, 5 (12): 7359- 7370.
doi: 10.1021/acscatal.5b02230 |
11 | HUNAG X M , ATAY C , ZHU J D , et al. Catalytic depolymerization of lignin and woody biomass in supercritical ethanol: Influence of reaction temperature and feedstock[J]. ACS Sustainable Chemistry & Engineering, 2017, 5 (11): 10864- 10874. |
12 | ERDOCIA X , PRADO R , FERNANDEZRODRIGUZE J , et al. Depolymerization of different organosolv lignins in supercritical methanol, ethanol, and acetone to produce phenolic monomers[J]. ACS Sustainable Chemistry & Engineering, 2016, 4 (3): 1373- 1380. |
13 |
WARNER G , HANSEN T S , RIISAGER A , et al. Depolymerization of organosolv lignin using doped porous metal oxides in supercritical methanol[J]. Bioresource Technology, 2014, 161, 78- 83.
doi: 10.1016/j.biortech.2014.02.092 |
14 |
BARAKAT N A , YOUSEF A , OBAID M , et al. Ag-doped M2O3 nanoflakes as effective catalyst for lignin liquefaction in supercritical methanol medium[J]. Ceramics International, 2016, 42 (3): 4386- 4392.
doi: 10.1016/j.ceramint.2015.11.120 |
15 | SAGUES W J , BAO H X , NEMENYI J L , et al. Lignin-first approach to biorefining: Utilizing fenton's reagent and supercritical ethanol for the production of phenolics and sugars[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (4): 4958- 4965. |
16 | ZHOU M G , SHARMA B K , LIU P , et al. Catalytic in situ hydrogenolysis of lignin in supercritical ethanol: Effect of phenol, catalysts, and reaction temperature[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (5): 6867- 6875. |
17 | MAI F H , WEN Z , BAI Y F , et al. Selective conversion of enzymatic hydrolysis lignin into alkylphenols in supercritical ethanol over a WO3/γ-Al2O3 Catalyst[J]. Industrial & Engineering Chemistry Research, 2019, 58 (24): 10255- 10263. |
18 | LIMARTA S O, KIM H, HA J M, et al. High-quality and phenolic monomer-rich bio-oil production from lignin in supercritical ethanol over synergistic Ru and Mg-Zr-oxide catalysts[J/OL]. Chemical Engineering Journal, 2020, 396: 1-11[2020-01-25]. https://doi.org/10.1016/j.cej.2020.125175. |
19 |
GOSSELINK R J A , TEUNISSEN W , VAN DAM J , et al. Lignin depolymerisation in supercritical carbon dioxide/acetone/water fluid for the production of aromatic chemicals[J]. Bioresource Technology, 2012, 106, 173- 177.
doi: 10.1016/j.biortech.2011.11.121 |
20 |
LI H Q , XU B N , JIN H H , et al. Molecular dynamics investigation on the lignin gasification in supercritical water[J]. Fuel Processing Technology, 2019, 192, 203- 209.
doi: 10.1016/j.fuproc.2019.04.014 |
21 |
NUMANALMOBIN A M , KOLLA P , DIXON D , et al. Effect of water-carbon dioxide ratio on the selectivity of phenolic compounds produced from alkali lignin in sub- and supercritical fluid mixtures[J]. Fuel, 2016, 185, 26- 33.
doi: 10.1016/j.fuel.2016.07.043 |
22 | NUMANALMOBIN A M , VOELLER K , BILEK H , et al. Selective synthesis of phenolic compounds from alkali lignin in a mixture of sub- and supercritical fluids: Catalysis by CO2[J]. Energy & Fuels, 2016, 30 (3): 2137- 2143. |
23 | DUTTA T , ISERN N G , SUN J , et al. Survey of lignin-structure changes and depolymerization during ionic liquid pretreatment[J]. ACS Sustainable Chemistry & Engineering, 2017, 5 (11): 10116- 10127. |
24 |
陈茹茹, 王雪, 吕兴梅, 等. 离子液体在生物质转化中的应用与研究进展[J]. 轻工学报, 2019, 34 (3): 1- 20.
doi: 10.3969/j.issn.2096-1553.2019.03.001 |
CHEN R R , WANG X , LYU X M , et al. Application and progress of ionic liquid in biomass conversion[J]. Journal of Light Industry, 2019, 34 (3): 1- 20.
doi: 10.3969/j.issn.2096-1553.2019.03.001 |
|
25 | 刘光勇, 王倩, 张雅琴, 等. 离子液体中催化解聚木质素研究现状[J]. 中国科学: 化学, 2020, 50 (2): 259- 270. |
LIU G Y , WANG Q , ZHNAG Y Q , et al. Degradation of lignin in ionic liquids: Review[J]. Scientia Sinica: Chimica, 2020, 50 (2): 259- 270. | |
26 |
ZHANG Z R , SONG J L , HAN B X , et al. Catalytic transformation of lignocellulose into chemicals and fuel products in ionic liquids[J]. Chemical Reviews, 2017, 117 (10): 6834- 6880.
doi: 10.1021/acs.chemrev.6b00457 |
27 | ZUBELTZU J, FORMOSO E, REZABAL E. Lignin solvation by ionic liquids: The role of cation[J/OL]. Journal of Molecular Liquids, 2020, 303: 1-31[2020-04-19]. https://doi.org/10.1016j.molliq.2020.112588. |
28 | DE GREGORIO G F , PRADO R , VRIAMONT C , et al. Oxidative depolymerization of lignin using a novel polyoxometalate-protic ionic liquid system[J]. ACS Sustainable Chemistry & Engineering, 2016, 4 (11): 6031- 6036. |
29 |
SHI N , LIU D , HUANG Q , et al. Product-oriented decomposition of lignocellulose catalyzed by novel polyoxometalates-ionic liquid mixture[J]. Bioresource Technology, 2019, 283, 174- 183.
doi: 10.1016/j.biortech.2019.03.048 |
30 |
ROBERTS V , STEIN V , REINER T , et al. Towards quantitative catalytic lignin depolymerization[J]. Chemistry: A European Journal, 2011, 17 (21): 5939- 5948.
doi: 10.1002/chem.201002438 |
31 | TOLEDANO A , SERRANO L , LABIDI J . Improving base catalyzed lignin depolymerization by avoiding lignin repolymerization[J]. Fuel, 2014, 161, 617- 624. |
32 |
YUAN Z , CHENG S , LEITCH M , et al. Hydrolytic degradation of alkaline lignin in hot-compressed water and ethanol[J]. Bioresource Technology, 2010, 101 (23): 9308- 9313.
doi: 10.1016/j.biortech.2010.06.140 |
33 | YU X, WEI Z, LU Z, et al. Activation of lignin by selective oxidation: An emerging strategy for boosting lignin depolymerization to aromatics[J/OL]. Bioresource Technology, 2019, 291: 1-48[2020-05-16]. https://doi.org/10.1016j.biortech.2019.121885. |
34 |
LI S , MASOUD T A , YDNA M Q , et al. Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization[J]. Science, 2016, 354 (6310): 329- 333.
doi: 10.1126/science.aaf7810 |
35 |
MU X L , HAN Z , LIU C L , et al. Mechanistic Insights into formaldehyde-blocked lignin condensation: A DFT study[J]. Journal of Physical Chemistry C, 2019, 123 (14): 8640- 8648.
doi: 10.1021/acs.jpcc.9b00247 |
36 |
MEIER D , ANTE R , FAIX O . Catalytic hydropyrolysis of lignin: Influence of reaction conditions on the formation and composition of liquid products[J]. Bioresource Technology, 1992, 40 (2): 171- 177.
doi: 10.1016/0960-8524(92)90205-C |
37 |
RATCLIFF M , JOHNSON D K , POSEY F L , et al. Hydrodeoxygenation of lignins and model compounds: Scientific note[J]. Applied Biochemistry and Biotechnology, 1988, 17 (1): 151- 160.
doi: 10.1007/BF02779153 |
38 |
JOFFRES B , LORENTZ C , VIDALIE M , et al. Catalytic hydroconversion of a wheat straw soda lignin: Characterization of the products and the lignin residue[J]. Applied Catalysis B: Environmental, 2014, 145, 167- 176.
doi: 10.1016/j.apcatb.2013.01.039 |
39 |
SHAFAGHAT H , REZAEI P S , DAUD W M A W . Using decalin and tetralin as hydrogen source for transfer hydrogenation of renewable lignin-derived phenolics over activated carbon supported Pd and Pt catalysts[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016, 65, 91- 100.
doi: 10.1016/j.jtice.2016.05.032 |
40 |
HOLMELID B , KLEINERT M , BARTH T . Reactivity and reaction pathways in thermochemical treatment of selected lignin-like model compounds under hydrogen rich conditions[J]. Journal of Analytical and Applied Pyrolysis, 2012, 98, 37- 44.
doi: 10.1016/j.jaap.2012.03.007 |
41 |
ONWUDILI J A , WILLIAMS P T . Catalytic depolymerization of alkali lignin in subcritical water: Influence of formic acid and Pd/C catalyst on the yields of liquid monomeric aromatic products[J]. Green Chemistry, 2014, 16 (11): 4740- 4748.
doi: 10.1039/C4GC00854E |
42 | RAHIMI A , ULBRICH A , COON J J , et al. Formic-acid-induced depolymerization of oxidized lignin to aromatics[J]. Nature: International Weekly Journal of Science, 2014, 515 (7526): 249- 252. |
43 |
HIDAJAT M J , RIAZ A , KIM J . A two-step approach for producing oxygen-free aromatics from lignin using formic acid as a hydrogen source[J]. Chemical Engineering Journal, 2018, 348, 799- 810.
doi: 10.1016/j.cej.2018.05.036 |
44 |
WANG M , ZHANG X C , LI H J , et al. Carbon modification of nickel catalyst for depolymerization of oxidized lignin to aromatics[J]. ACS Catalysis, 2018, 8 (2): 1614- 1620.
doi: 10.1021/acscatal.7b03475 |
45 | WANG D, LI G C, ZHANG C H, et al. Nickel nanoparticles inlaid in lignin-derived carbon as high effective catalyst for lignin depolymerization[J/OL]. Bioresource Technology, 2019, 289: 1-7[2020-05-20]. https://doi.org/10.1016/j.biortech.2019.121629. |
46 |
BURCU G , ERIK H J H E , EVGENY A P , et al. Lewis acid-catalyzed depolymerization of soda lignin in supercritical ethanol/water mixtures[J]. Catalysis Today, 2016, 269, 9- 20.
doi: 10.1016/j.cattod.2015.08.039 |
47 | NANDIWALE K Y , DANBY A M , RAMANATHAN A , et al. Dual function lewis acid catalyzed depolymerization of industrial corn stover lignin into stable monomeric phenols[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (1): 1362- 1371. |
48 | SHEN X J , CHEN T Y , WANG H M , et al. Structural and morphological transformations of lignin macromolecules during bio-based deep eutectic solvent(DES) pretreatment[J]. ACS Sustainable Chemistry & Engineering, 2020, 8 (5): 2130- 2137. |
49 |
BARAKAT A , MAYERLAIGLE C , SOLHY A , et al. Mechanical pretreatments of lignocellulosic biomass: Towards facile and environmentally sound technologies for biofuels production[J]. RSC Advances, 2014, 4 (89): 48109- 48127.
doi: 10.1039/C4RA07568D |
50 |
QU Y S , LUO H , LI H Q , et al. Comparison on structural modification of industrial lignin by wet ball milling and ionic liquid pretreatment[J]. Biotechnology Reports, 2015, 6, 1- 7.
doi: 10.1016/j.btre.2014.12.011 |
51 |
BRITTAIN A D , CHRISANDINA N J , COOPER R E , et al. Quenching of reactive intermediates during mechanochemical depolymerization of lignin[J]. Catalysis Today, 2018, 302, 180- 189.
doi: 10.1016/j.cattod.2017.04.066 |
52 |
ZAKZESKI J , BRUIJININCX P C A , JONGERIUS A L , et al. The catalytic valorization of lignin for the production of renewable chemicals[J]. Chemical Reviews, 2010, 110 (6): 3552- 3599.
doi: 10.1021/cr900354u |
53 | YAN S G , MOBLEY J K , RALPH J , et al. Mechanochemical treatment facilitates two-step oxidative depolymerization of Kraft lignin[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (5): 5990- 5998. |
54 | DABRAL S , WOTRUBA H , HERNANDEZ J G , et al. Mechanochemical oxidation and cleavage of lignin β-O-4 model compounds and lignin[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (1): 3242- 3254. |
55 | CKAUFMAN RECHULSKI M D , MATS K , RICHTER U , et al. Mechanocatalytic depolymerization of lignocellulose performed on hectogram and kilogram scales[J]. Industrial & Engineering Chemistry Research, 2015, 54 (16): 4581- 4592. |
56 |
KAPPE C O . Microwave dielectric heating in synthetic organic chemistry[J]. Chemical Society Reviews, 2008, 37 (6): 1127- 1139.
doi: 10.1039/b803001b |
57 | PAN J Y , FU J , LU X Y . Microwave-assisted oxidative degradation of lignin model compounds with metal salts[J]. Energy & Fuels, 2015, 29 (7): 4503- 4509. |
58 |
DAI J H , STYLES G N , PATTI A F , et al. CuSO4/H2O2-catalyzed lignin depolymerization under the irradiation of microwaves[J]. ACS Omega, 2018, 3 (9): 10433- 10441.
doi: 10.1021/acsomega.8b01978 |
59 | PAN J Y , FUC C J , DENG S G , et al. Microwave-assisted degradation of lignin model compounds in imidazolium-based ionic liquids[J]. Energy & Fuels, 2014, 28 (2): 1380- 1386. |
60 |
ZHU G D , JIN D X , ZHAO L S , et al. Microwave-assisted selective cleavage of Cα-Cβ bond for lignin depolymerization[J]. Fuel Processing Technology, 2017, 161, 155- 161.
doi: 10.1016/j.fuproc.2017.03.020 |
61 | GONG J Y , IMBAULT A , FARNOOD R . The promoting role of bismuth for the enhanced photocatalytic oxidation of lignin on Pt-TiO2 under solar light illumination[J]. Applied Catalysis B: Environmental, 2017, 405, 296- 303. |
62 |
LIU H F , LI H J , LU J M , et al. Photocatalytic cleavage of C-C bond in lignin models under visible light on mesoporous graphitic carbon nitride through π-π stacking interaction[J]. ACS Catalysis, 2018, 8 (6): 4761- 4771.
doi: 10.1021/acscatal.8b00022 |
63 |
YOO H , LEE M W , LEE S , et al. Enhancing photocatalytic-O-4 bond cleavage in lignin model compounds by silver-exchanged cadmium sulfide[J]. ACS Catalysis, 2020, 10 (15): 8465- 8475.
doi: 10.1021/acscatal.0c01915 |
64 | CAO Y , WANG N , HE X , et al. Photocatalytic oxidation and subsequent hydrogenolysis of lignin β-O-4 models to aromatics promoted by in situ carbonic acid[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (11): 15032- 15039. |
65 | 李树媛. 可见光催化剂用于木质素解聚的研究[D]. 上海: 上海师范大学, 2019. |
LI S Y. Study on visible light catalyst for depolymerization of lignin[D]. Shanghai: Shanghai Normal University, 2019. | |
66 |
WANG H , QIU X Q , ZHONG R S , et al. One-pot in-situ preparation of a lignin-based carbon/ZnO nanocomposite with excellent photocatalytic performance[J]. Materials Chemistry and Physics, 2017, 199, 193- 202.
doi: 10.1016/j.matchemphys.2017.07.009 |
67 |
LI C H , WANG H M , NAGHADEH S B , et al. Visible light driven hydrogen evolution by photocatalytic reforming of lignin and lactic acid using one-dimensional NiS/CdS nanostructures[J]. Applied Catalysis B: Environmental, 2018, 227, 229- 239.
doi: 10.1016/j.apcatb.2018.01.038 |
68 |
TIAN L F , HU Y Z , GUO Y R , et al. Dual effect of lignin amine on fabrication of magnetic Fe3O4/C/ZnO nanocomposite in situ and photocatalytic property[J]. Ceramics International, 2018, 44 (12): 14480- 14486.
doi: 10.1016/j.ceramint.2018.05.062 |
69 |
LIN Y Y , LU S Y . Selective and efficient cleavage of lignin model compound into value-added aromatic chemicals with CuFe2O4 nanoparticles decorated on partially reduced graphene oxides via sunlight-assisted heterogeneous Fenton processes[J]. Journal of the Taiwan Institute of Chemical Engineers, 2019, 97, 264- 271.
doi: 10.1016/j.jtice.2019.02.007 |
70 |
BOSQUE I , MAGALLANES G , RIGOULET M , et al. Redox catalysis facilitates lignin depolymerization[J]. ACS Central Science, 2017, 3 (6): 621- 628.
doi: 10.1021/acscentsci.7b00140 |
71 |
GAO W L , LAM C M , SUN B G , et al. Selective electrochemical C-O bond cleavage of β-O-4 lignin model compounds mediated by iodide ion[J]. Tetrahedron, 2017, 73 (17): 2447- 2454.
doi: 10.1016/j.tet.2017.03.027 |
72 |
CAI P , FAN H X , CAO S , et al. Electrochemical conversion of corn stover lignin to biomass-based chemicals between Cu/NiMoCo cathode and Pb/PbO2 anode in alkali solution[J]. Electrochimica Acta, 2018, 264, 128- 139.
doi: 10.1016/j.electacta.2018.01.111 |
73 |
LI S Y , LI Z J , YU H , et al. Solar-driven lignin oxidation via hydrogen atom transfer with a dye-sensitized TiO2 photoanode[J]. ACS Energy Letters, 2020, 5 (3): 777- 784.
doi: 10.1021/acsenergylett.9b02391 |
74 |
WANG J Q , YAN C , ZHU L Y , et al. Solar binary chemical depolymerization of lignin for efficient production of small molecules and hydrogen[J]. Bioresource Technology, 2019, 272, 249- 258.
doi: 10.1016/j.biortech.2018.10.032 |
[1] | 梁孟珂, 陈静, 戴鹏, 马晓峰, 张猛, 罗振扬. 木质素基膨胀型阻燃剂的制备及其应用[J]. 林产化学与工业, 2021, 41(4): 10-16. |
[2] | 金灿, 刘云龙, 霍淑平, 吴国民, 刘贵锋, 孔振武. 木质素基多孔炭材料及其在水体净化中的应用研究进展[J]. 林产化学与工业, 2021, 41(4): 111-123. |
[3] | 李卓, 翁述贤, 宋飞, 任晓丽, 杨晓慧, 胡立红. 木质素基含氮磷阻燃剂的合成及热重分析[J]. 林产化学与工业, 2021, 41(3): 63-70. |
[4] | 刘金昱, 刘瑞霞, 邓萍萍, 刘德乡, 郭盟, 吴志平. 木质素离子印迹聚合物的制备及其对Cr(VI)吸附性能的研究[J]. 林产化学与工业, 2021, 41(2): 24-32. |
[5] | 李欣, 任宇, 刘建祥, 史正军, 郑志锋, 刘灿. 温度对木质素基酚醛树脂纤维固化行为的影响[J]. 林产化学与工业, 2021, 41(2): 33-38. |
[6] | 杨倩, 刘贵锋, 金灿, 孔振武. 路易斯酸复合Pt/ZrO2协同催化碱木质素还原降解制备酚类低聚物[J]. 林产化学与工业, 2020, 40(6): 37-49. |
[7] | 黄勇,刘沙沙,吴益霜,周建斌,张书. 基于模型化合物的生物质半焦催化性能研究[J]. 林产化学与工业, 2020, 40(5): 63-68. |
[8] | 朱恩清,史正军,刘守庆,杨静,王大伟,杨海艳. 基于不同发泡剂的木质素基泡沫炭的制备及性能研究[J]. 林产化学与工业, 2020, 40(4): 63-70. |
[9] | 钟磊,王超,吕高金,吉兴香,杨桂花,陈嘉川. 低共熔溶剂在木质素分离方面的研究进展[J]. 林产化学与工业, 2020, 40(3): 12-22. |
[10] | 侯兴隆,郭奇,建晓朋,吴迪超,许伟,刘军利. 响应面法优化设计木质素基活性炭的制备[J]. 林产化学与工业, 2020, 40(3): 115-122. |
[11] | 储秋露,陈雪艳,宋凯,王静,张晓东,施爱平. 两步法预处理对杨木酶水解及木质素吸附性能的影响[J]. 林产化学与工业, 2019, 39(6): 68-74. |
[12] | 卢传巍,郭晓亮,蔡青云,王春鹏,储富祥,王基夫. 甲基丙烯酸化木质素磺酸钙/聚丙烯酰胺复合水凝胶的制备与性能研究[J]. 林产化学与工业, 2019, 39(6): 75-80. |
[13] | 李宁,陈智糠,张一甫. 酚化木质素改性酚醛树脂胶黏剂的制备及性能表征[J]. 林产化学与工业, 2019, 39(6): 95-101. |
[14] | 陈雪艳, 储秋露, 王静, 张晓东, 施爱平. 两步法预处理脱除木质素对杨木酶水解的影响[J]. 林产化学与工业, 2019, 39(5): 73-79. |
[15] | 王兴佳, 乔炜, 肖达明, 李淑君. 铝氧单钠固体超强碱催化降解木质素的研究[J]. 林产化学与工业, 2019, 39(5): 80-86. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||