林产化学与工业 ›› 2021, Vol. 41 ›› Issue (5): 65-71.doi: 10.3969/j.issn.0253-2417.2021.05.010
张文杰(), 陈玉保, 刘莹(), 徐锐, 李兴勇, 胡良栋
收稿日期:
2020-10-29
出版日期:
2021-10-28
发布日期:
2021-11-04
通讯作者:
刘莹
E-mail:707088827@qq.com;542110131@qq.com
作者简介:
刘莹, 副教授, 研究方向为生物质能源开发与利用; E-mail: 542110131@qq.com基金资助:
Wenjie ZHANG(), Yubao CHEN, Ying LIU(), Rui XU, Xingyong LI, Liangdong HU
Received:
2020-10-29
Online:
2021-10-28
Published:
2021-11-04
Contact:
Ying LIU
E-mail:707088827@qq.com;542110131@qq.com
摘要:
在高压微型固定床中,以Pt-La/SAPO-11为催化剂,蓖麻油为原料进行一步加氢连续催化制备生物航空煤油,探索了不同反应温度、空速、氢气压力和氢气/蓖麻油体积比(氢油比)值对反应生成的C8~C16烷烃、C8-C16异构烷烃和C8~C16芳烃的选择性,以及脂肪酸甘油三酯转化率的影响,得到最佳工艺参数。在温度400℃、氢气压力4 MPa、空速1 h-1、氢油比值1 000的最优条件下,原料转化率为87.78%、C8~C16烷烃选择性为58.24%、C8~C16异构烷烃选择性17.32%、C8~C16芳烃选择性为10.72%。结合课题组前期研究,推测不饱和蓖麻油酸在Pt-La/SAPO-11催化剂上加氢转化为饱和蓖麻油酸,随后在催化剂的酸性位点生成中间产物醇、酸等中间产物,中间产物在金属位点与酸性位点上通过脱羟、脱羧等反应得到碳氢化合物,最后在加氢、裂化、异构化反应下得到航油组分C8~C16烷烃。
中图分类号:
张文杰, 陈玉保, 刘莹, 徐锐, 李兴勇, 胡良栋. Pt-La/SAPO-11催化剂一步加氢制备航空煤油及其反应过程探究[J]. 林产化学与工业, 2021, 41(5): 65-71.
Wenjie ZHANG, Yubao CHEN, Ying LIU, Rui XU, Xingyong LI, Liangdong HU. One-step Hydrogenation of Castor Oil Catalyzed by Pt-La/SAPO-11 Catalyst for Preparing of Aviation Kerosene[J]. Chemistry and Industry of Forest Products, 2021, 41(5): 65-71.
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