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林产化学与工业 ›› 2021, Vol. 41 ›› Issue (5): 100-112.doi: 10.3969/j.issn.0253-2417.2021.05.015

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过渡金属基催化剂催化5-羟甲基糠醛合成2, 5-呋喃二甲醛研究进展

白继峰1(), 杨雨1, 蒋志薪1, 程曼芳1, 张霖2, 王景芸1,*()   

  1. 1. 辽宁石油化工大学 石油化工学院, 辽宁 抚顺 113001
    2. 军委后勤保障部军需能源技术服务中心, 北京 100842
  • 收稿日期:2020-12-18 出版日期:2021-10-28 发布日期:2021-11-04
  • 通讯作者: 王景芸 E-mail:977927067@qq.com;wangjingyun0713@163.com
  • 作者简介:王景芸, 副教授, 博士, 硕士生导师, 研究领域为可再生资源转化利用; E-mail: wangjingyun0713@163.com
    白继峰(1992-), 男, 辽宁开原人, 硕士生, 主要从事生物质转化研究; E-mail: 977927067@qq.com
  • 基金资助:
    兴辽英才计划项目(XLYC1902085);辽宁省自然科学基金指导计划项目(20170540590);中石油创新基金项目(2018D-5007-0507)

Research Advance in Preparation of 2, 5-Furanedioic Acid by Oxidation of 5-Hydroxymethylfurfural over Transition Metal-based Catalysts

Jifeng BAI1(), Yu YANG1, Zhixin JIANG1, Manfang CHENG1, Lin ZHANG2, Jingyun WANG1,*()   

  1. 1. Department of Petrochemical, Liaoning Petrochemical University, Fushun 113001, China
    2. CMC Logistics Support Department Quartermaster Energy Technology Service Center, Beijing 100842, China
  • Received:2020-12-18 Online:2021-10-28 Published:2021-11-04
  • Contact: Jingyun WANG E-mail:977927067@qq.com;wangjingyun0713@163.com

摘要:

本文综述了近些年过渡金属基催化剂催化5-羟甲基糠醛(HMF)氧化制备2,5-呋喃二甲醛(DFF)的研究进展。重点介绍了锰基、铜基、钒基、铁/钴基及其他催化体系在HMF氧化制备DFF的应用。详细分析了不同反应条件对催化剂性能的影响,阐述了不同催化剂的反应机理,并总结了不同催化剂的优缺点。此外,在分析当前催化剂催化过程中存在问题的基础上,还对过渡金属基催化剂催化HMF氧化制备DFF的发展前景进行了展望。

关键词: 5-羟甲基糠醛, 2, 5-呋喃二甲醛, 催化氧化

Abstract:

This article reviews the recent research progress of preparation of 2, 5-furandiformaldehyde(DFF) by the oxidation of 5-hydroxymethylfurfural(HMF) with transition metal-based catalysts. The application of manganese-based, copper-based, vanadium-based, iron/cobalt-based and other catalytic systems in the preparation of DFF by HMF oxidation is mainly introduced. The effects of different reaction conditions on the catalytic performance of the catalyst are analyzed in detail, the reaction mechanism of different catalysts is explained, and the advantages and disadvantages of different catalysts are summarized. In addition, based on the analysis of the existed problems in the current catalyst catalysis process, the development prospects of the transition metal-based catalysts catalyzed by HMF oxidation to prepare DFF are also prospected.

Key words: 5-hydroxymethylfurfural, 2, 5-furandiformaldehyde, catalytic oxidation

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