木质素基多孔炭材料的制备及应用研究进展

doi:10.3969/j.issn.0253-2417.2022.01.017

林产化学与工业 ›› 2022, Vol. 42 ›› Issue (1): 131-138.doi: 10.3969/j.issn.0253-2417.2022.01.017

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木质素基多孔炭材料的制备及应用研究进展

侯兴隆¹^,², 许伟¹, 刘军利¹^,*()

1. 中国林业科学研究院林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业和草原局林产化学工程重点实验室; 江苏省生物质能源与材料重点实验室, 江苏南京 210042
2. 南京林业大学江苏省林业资源高效加工利用协同创新中心, 江苏南京 210037

收稿日期:2020-12-06 出版日期:2022-02-28 发布日期:2022-03-11
通讯作者: 刘军利 E-mail:liujunli1974@126.com
作者简介:刘军利, 研究员, 博士生导师, 研究领域为生物质热化学转化技术、多孔质炭材料的制备及其应用技术; E-mail: liujunli1974@126.com
侯兴隆(1995-), 男, 山东威海人, 硕士生, 从事多孔质炭材料的制备及应用研究
基金资助:
国家重点研发计划资助项目(2019YFB1503804);中国林科院中央级公益性科研院所基本科研业务费专项资金(CAFYBB2018SZ011);江苏省333人才项目(BRA2019293)

Research Progress in Preparation and Application of Lignin-based Porous Carbon Materials

Xinglong HOU¹^,², Wei XU¹, Junli LIU¹^,*()

1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China
2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China

Received:2020-12-06 Online:2022-02-28 Published:2022-03-11
Contact: Junli LIU E-mail:liujunli1974@126.com

摘要/Abstract

摘要：

木质素是无定型态的高度交联的多酚芳香族聚合物，来源广泛，碳含量丰富，适合用于多孔炭材料的制备。将木质素用于制备多孔炭是实现资源化利用，解决木质素难以大量高效利用而造成环境污染问题的重要途径。本文主要介绍了近些年来，以木质素为炭前驱体，通过物理、化学活化法制备出的以微孔为主的活性炭及采用模板法制备出的介孔炭材料工艺研究情况，对比分析了不同方法制备的多孔炭材料的孔道结构及形貌特点，以及其应用在吸附、催化和电化学方面取得的进展。

关键词: 活化, 模板法, 吸附, 催化, 电化学

Abstract:

Lignin is an amorphous, highly cross-linked polyphenol aromatic polymer with a wide range of sources and rich carbon content, and is suitable for the preparation of porous carbon materials. Using lignin to prepare porous carbon is an important way to solve the problem that lignin is difficult to be used efficiently. It can solve environmental pollution and realize resource utilization. This article mainly introduced the research status of the preparation of microporous activated carbon with lignin as carbon precursor by physical and chemical activation method and the preparation of mesoporous carbon materials by template method in recent years. The pore structure and morphology of porous carbon materials prepared by different methods were compared and analyzed, as well as their application progress in adsorption, catalysis and electrochemistry.

Key words: activation, template method, adsorption, catalysis, electrochemistry

中图分类号:

TQ35

侯兴隆, 许伟, 刘军利. 木质素基多孔炭材料的制备及应用研究进展[J]. 林产化学与工业, 2022, 42(1): 131-138.

Xinglong HOU, Wei XU, Junli LIU. Research Progress in Preparation and Application of Lignin-based Porous Carbon Materials[J]. Chemistry and Industry of Forest Products, 2022, 42(1): 131-138.

图/表 2

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制备方法 preparation method	原料 lignin	活化剂 activator	制备条件¹⁾ conditions	比表面积/(m²·g^-1) specific surface area	微孔孔容/ (cm³·g^-1) micropore volume	参考文献 reference
物理活化法 physical activation	桉树硫酸盐木质素 eucalyptus kraft lignin	CO₂	C: 350 ℃, 2 h; A: 850 ℃, 20 h	1853	0.57	[16]
物理活化法 physical activation	水解木质素 hydrolytic lignin	H₂O	C: 600 ℃, 2 h; A: 800 ℃, 2 h	865	0.365	[17]
化学活化法 chemical activation	桉树硫酸盐木质素 eucalyptus kraft lignin	ZnCl₂	A: 500 ℃, 1 h, 1∶2.3^*	1800	1.039	[22]
	桉树硫酸盐木质素 eucalyptus kraft lignin	H₃PO₄	A: 427 ℃, 2 h, 1∶2^*	1459	0.82	[23]
	水解木质素 hydrolytic lignin	KOH	A: 850 ℃, 15 min, 1∶4^*	2753	1.37	[24]

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木质素基多孔炭材料的制备及应用研究进展

Research Progress in Preparation and Application of Lignin-based Porous Carbon Materials

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