林产化学与工业 ›› 2022, Vol. 42 ›› Issue (5): 113-121.doi: 10.3969/j.issn.0253-2417.2022.05.016
李学琴1,2(), 刘鹏2, 吴幼青1, 雷廷宙2,*(), 吴诗勇1, 黄胜1
收稿日期:
2021-06-10
出版日期:
2022-10-28
发布日期:
2022-11-02
通讯作者:
雷廷宙
E-mail:lxq88889@126.com;leitingzhou@163.com
作者简介:
雷廷宙,研究员,博士生导师,研究领域为生物质能源及材料;E-mail: leitingzhou@163.com基金资助:
Xueqin LI1,2(), Peng LIU2, Youqing WU1, Tingzhou LEI2,*(), Shiyong WU1, Sheng HUANG1
Received:
2021-06-10
Online:
2022-10-28
Published:
2022-11-02
Contact:
Tingzhou LEI
E-mail:lxq88889@126.com;leitingzhou@163.com
摘要:
为促进生物质气化技术的发展及气化产物的利用,重点介绍了国内外生物质气化技术的发展及产业现状、气化炉类型及发展现状,提出了生物质气化技术的优缺点;同时,也发现虽然我国生物质资源丰富且生物质具有可再生性、污染较小、蕴藏量大、分布广泛、零碳排放等优异的特点,但由于其收-储-运体系不完善、资金链短缺及副产物较多等一系列问题导致其国际化困难。展望了我国生物质气化技术不仅要走扎实的基础研究和开发路径,也要考虑生物质气化技术的总体需求以及与其他技术的竞争等方面作为未来发展方向及重要攻关点,期望能为生物质气化技术的进一步发展及气化产物的高值化利用奠定坚实的基础。
中图分类号:
李学琴, 刘鹏, 吴幼青, 雷廷宙, 吴诗勇, 黄胜. 生物质气化技术的发展现状及展望[J]. 林产化学与工业, 2022, 42(5): 113-121.
Xueqin LI, Peng LIU, Youqing WU, Tingzhou LEI, Shiyong WU, Sheng HUANG. Development Status and Prospect of Biomass Gasification Technology[J]. Chemistry and Industry of Forest Products, 2022, 42(5): 113-121.
表1
典型的气化剂和燃气组成"
气化剂 gasification agents | H2 | O2 | N2 | CO | CO2 | CH4 | C2H2 | C2H4 | C2H6 | H2/CO |
空气air | 10.0 | 0.5 | 41.2 | 23.0 | 18.1 | 5.2 | 0.4 | 1.8 | 0.1 | 0.44 |
富氧oxygen-rich | 9.5 | 0.5 | 7.3 | 46.8 | 23.4 | 9.7 | 0.8 | 2.0 | 0.4 | 0.20 |
空气-水蒸气air-steam | 18.2 | 0.5 | 33.7 | 21.1 | 19.5 | 5.3 | 0.2 | 2.3 | 0.4 | 0.85 |
氧气-水蒸气oxygen- steam | 32.1 | 0.3 | 0.3 | 28.2 | 30.4 | 7.5 | 0.2 | 2.1 | 0.2 | 1.14 |
水蒸气steam | 50.8 | 0.3 | 0.3 | 20.3 | 19.6 | 7.1 | 0.3 | 1.8 | 0.2 | 2.50 |
表2
全球商用部分固定床和流化床气化炉[39-42]"
国家counrty | 类型type | 原料raw material | 规模scale |
美国America | 下吸式downdraft | 树木trees | 1 MW |
木屑wood chips,玉米棒corn cob | 40 kW | ||
丹麦Denmark | 上吸式upper suction | 皮革leather | 2-15 MW |
稻草straw, 木屑wood chips, 树皮bark | 1-15 MW | ||
下吸式downdraft | 木屑残渣wood chips residue | 0.5 MW | |
新西兰New Zealand | 下吸式downdraft | 木块wooden block, 木片piece, 柳条wicker | 30 kW |
法国France | 下吸式downdraft | 农业残渣agricultural residue | 100-600 MW |
英国Britain | 下吸式downdraft | 榛子壳haznut shell | 30 kW |
农业废物agricultural wastes | 300 kW | ||
印度India | 下吸式downdraft | 稻壳rice husk | 100 kg/h25-100 kW |
丹茶dan tea, 玉米棒corn cob, 木材wood | 128 kW | ||
比利时Belgium | 小型small scale | 木屑wood chips | 160 kW |
南非South Africa | 下吸式downdraft | 木块碎片wood block fragments, 煤coal | 30-500 kW |
芬兰Finland | 上吸式upper suction | 木片wood chips, 稻草straw, 泥炭peat | 4-5MW |
荷兰Holland | 下吸式downdraft | 稻壳rice husk | 150 kW |
中国China | 木屑wood chips | 200 kW | |
下吸式downdraft | 农作物残渣crop residue | 300 kW | |
稻壳rice shell | 200 kW | ||
流化床fluidized bed | 农林废弃物all kinds of agricultural and forestry wastes | 1 000 kW | |
循环流化床circulating fluidized bed | 农林废弃物all kinds of agricultural and forestry | 200-1 200 kW | |
秸秆straw, 木屑wood chips, 花生壳peanut shell | 5.5 MW |
表3
河南省秸秆资源的理论可获得量"
年份 year | 水稻 rice | 小麦 wheat | 玉米 corn | 豆类 beans | 薯类 potatoes | 花生 peanuts | 油菜 rape | 棉花 cotton | 麻类 hemp | 糖料 sugar | 烟叶 tobacco leaves |
2010 | 157.7 | 1323.5 | 1396.7 | 64.0 | 51.8 | 264.7 | 93.1 | 64.8 | 1.6 | 1.7 | 0.8 |
2011 | 158.8 | 1341.0 | 1449.4 | 65.3 | 52.8 | 266.0 | 81.0 | 55.4 | 1.8 | 1.7 | 0.8 |
2012 | 158.2 | 1384.0 | 1718.4 | 54.2 | 37.3 | 280.8 | 60.6 | 24.6 | 1.6 | 1.4 | 0.8 |
2013 | 155.0 | 1402.6 | 1808.2 | 59.3 | 34.5 | 290.4 | 58.0 | 16.9 | 1.6 | 1.4 | 0.9 |
2014 | 167.5 | 1453.6 | 1784.6 | 35.3 | 34.1 | 288.5 | 52.0 | 12.2 | 1.2 | 1.3 | 0.8 |
2015 | 167.3 | 1514.5 | 1955.1 | 33.5 | 34.0 | 295.3 | 48.4 | 9.8 | 1.2 | 1.1 | 0.8 |
2016 | 170.1 | 1553.8 | 1893.5 | 33.6 | 33.6 | 305.9 | 42.8 | 7.1 | 1.2 | 1.1 | 0.7 |
2017 | 162.4 | 1591.0 | 1854.0 | 36.6 | 33.4 | 327.9 | 44.1 | 6.4 | 1.0 | 1.0 | 0.7 |
2018 | 167.8 | 1547.1 | 2008.9 | 69.8 | 24.2 | 354.3 | 40.8 | 5.5 | 0.9 | 1.0 | 0.7 |
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