松香/生物基丙烯酸酯压敏胶的制备与性能研究

doi:10.3969/j.issn.0253-2417.2023.02.007

林产化学与工业 ›› 2023, Vol. 43 ›› Issue (2): 49-55.doi: 10.3969/j.issn.0253-2417.2023.02.007

松香/生物基丙烯酸酯压敏胶的制备与性能研究

祁思迈¹^,², 罗通¹^,², 刘美红¹^,², 王春鹏¹^,², 储富祥¹^,², 王基夫¹^,²^,*()

1. 中国林业科学研究院林产化学工业研究所; 江苏省生物质能源与材料重点实验室; 国家林业和草原局林产化学工程重点实验室; 林木生物质低碳高效利用国家工程研究中心, 江苏南京 210042
2. 南京林业大学江苏省林业资源高效加工利用协同创新中心, 江苏南京 210037

收稿日期:2022-02-15 出版日期:2023-04-28 发布日期:2023-04-26
通讯作者: 王基夫 E-mail:wjf118@126.com
作者简介:王基夫, 研究员, 博士生导师, 主要从事生物质材料功能化研究; E-mail: wjf118@126.com
祁思迈(1997-), 男, 河北石家庄人, 硕士生, 从事生物质材料功能化研究工作

Preparation and Properties of Pressure Sensitive Adhesives Derived from Rosin Bio-based Acrylate

Simai QI¹^,², Tong LUO¹^,², Meihong LIU¹^,², Chunpeng WANG¹^,², Fuxiang CHU¹^,², Jifu WANG¹^,²^,*()

1. Institute of Chemical Industry of Forest Products, CAF; Key Lab. of Biomass Energy and Material, Jiangsu Province; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing 210042, China
2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China

Received:2022-02-15 Online:2023-04-28 Published:2023-04-26
Contact: Jifu WANG E-mail:wjf118@126.com

摘要/Abstract

摘要：

以糠醛基单体甲基丙烯酸四氢糠基酯(THFMA)、歧化松香改性单体(DRM)为硬单体，及油脂基单体甲基丙烯酸月桂酯(LMA)为软单体，通过溶液聚合法分别合成了THFMA-LMA、DRM-LMA系列生物基压敏胶(PSA)，详细探讨了硬单体与软单体组成比例、单体分子结构等对PSA性能的影响。研究结果表明：随着PSA中硬单体THFMA质量分数由10%增加到50%时，持黏力从0.48 h提高到72 h；且当THFMA质量分数为30%时，PSA的综合性能最佳，THFMA30-LMA的初黏力为2.28 N，180°剥离强度为143.6 N/m，持黏力达到21.25 h。另外与THFMA相比，以DRM作为硬单体在增强PSA力学性能的同时，还提高了PSA的热稳定性。

关键词: 甲基丙烯酸月桂酯, 甲基丙烯酸四氢糠基酯, 歧化松香, 压敏胶

Abstract:

In this work, furfural-based monomer tetrahydrofurfuryl methacrylate(THFMA), disproportionated rosin-based monomer(DRM), and oil-based monomer lauryl methacrylate(LMA) were used as raw materials to prepare a series of bio-based pressure-sensitive adhesives(PSA) based on THFMA/DRM/LMA by solution polymerization method. The effects of hard monomer and soft monomer composition ratio and the monomer molecular structure on the performance of PSA were investigated in detail. The results showed that the adhesion increased from 0.48 to 72 h with the increase of hard monomer THFMA in PSA from 10% to 50%. When the content of THFMA was 30%, the comprehensive performance of PSA was the best. The tack of THFMA30-LMA was 2.28 N, the 180° peel strength was 143.6 N/m, and the shear resistance reached 21.25 h. In addition, compared with THFMA, using DRM as hard monomer could enhance the mechanical properties of PSA and improve the thermal stability of PSA.

Key words: lauryl methacrylate, tetrahydrofurfuryl methacrylate, disproportionated rosin, pressuresensitive adhesives

中图分类号:

TQ35

祁思迈, 罗通, 刘美红, 王春鹏, 储富祥, 王基夫. 松香/生物基丙烯酸酯压敏胶的制备与性能研究[J]. 林产化学与工业, 2023, 43(2): 49-55.

Simai QI, Tong LUO, Meihong LIU, Chunpeng WANG, Fuxiang CHU, Jifu WANG. Preparation and Properties of Pressure Sensitive Adhesives Derived from Rosin Bio-based Acrylate[J]. Chemistry and Industry of Forest Products, 2023, 43(2): 49-55.

图/表 10

图1

表1

图2

图3

图4

表2

图5

图6

图7

表3

参考文献 15

1	CHEN T T D , CARRODEGUAS L P , SULLEY G S , et al. Bio-based and degradable block polyester pressure-sensitive adhesives[J]. Angewandte Chemie International Edition, 2020, 59 (52): 23450- 23455. doi: 10.1002/anie.202006807
2	DROESBEKE M A, AKSAKAL R, SIMULA A, et al.Biobased acrylic pressure-sensitive adhesives[J/OL]. Progress in Polymer Science, 2021, 117: 101396[2022-01-08]. https://doi.org/10.1016/j.progpolymsci.2021.101396.
3	宋季轩, 陈锓, 许甄, 等. 可生物降解压敏胶的研究进展[J]. 中国胶粘剂, 2021, 30 (3): 62- 69.
	SONG J X , CHEN Q , XU Z , et al. Advances in biodegradable pressure sensitive glue[J]. China Adhesive, 2021, 30 (3): 62- 69.
4	刘伟, 王钟, 汪钟凯. 植物油脂基压敏胶的研究进展及动态[J]. 生物质化学工程, 2022, 56 (1): 47- 56.
	LIU W , WANG Z , WANG Z K . Research progress and dynamic state of plant oil-based pressure-sensitive adhesives[J]. Biomass Chemical Engineering, 2022, 56 (1): 47- 56.
5	WANG S , SHUAI L , SAHA B , et al. From tree to tape: Direct synthesis of pressure sensitive adhesives from depolymerized raw lignocellulosic biomass[J]. ACS Central Science, 2018, 4 (6): 701- 708. doi: 10.1021/acscentsci.8b00140
6	GALLAGHER J J , HILLMYER M A , REINEKE T M . Acrylic triblock copolymers incorporating isosorbide for pressure sensitive adhesives[J]. ACS Sustainable Chemistry & Engineering, 2016, 4 (6): 3379- 3387.
7	LEI Y F , WANG X L , LIU B W , et al. Fully bio-based pressure-sensitive adhesives with high adhesivity derived from epoxidized soybean oil and rosin acid[J]. ACS Sustainable Chemistry & Engineering, 2020, 8 (35): 13261- 13270.
8	林明涛, 王基夫, 刘玉鹏, 等. 含松香衍生物的乳液压敏胶的制备及性能分析[J]. 高分子材料科学与工程, 2009, 25 (9): 24- 27.
	LIN M T , WANG J F , LIU Y P , et al. Preparation and performance analysis of emulsion pressure sensitive glue containing songxia derivatives[J]. Science and Engineering of Polymer Materials Science and Engineering, 2009, 25 (9): 24- 27.
9	GHI P Y , HILL D J T , ODONNELL J H , et al. The copolymerisation of tetrahydrofurfuryl methacrylate and methyl methacrylate[J]. Polymer Gels & Networks, 1996, 4 (3): 253- 267.
10	鲁程程, 尹朝辉, 张玉红. 丙烯酸酯压敏胶的研究进展[J]. 胶体与聚合物, 2020, 38 (3): 141- 145.
	LU C C , YIN Z H , ZHANG Y H . Research progress of acrylate pressure sensitive adhesive[J]. Colloid and Polymer, 2020, 38 (3): 141- 145.
11	CUI C , LIU B , WU T , et al. A Hyperbranched polymer elastomer-based pressure sensitive adhesive[J]. Journal of Materials Chemistry A, 2022, 10 (3): 1257- 1269.
12	黄碧君. 增黏树脂在橡胶压敏胶中的应用研究[J]. 粘接, 2013, 34 (12): 46- 49.
	HUANG B J . The application of tackifying resin in rubber pressure sensitive glue[J]. Adhesive, 2013, 34 (12): 46- 49.
13	ZHANG K, SHANG S, SUN P, et al.Hydrogenated rosin ester latexes/waterborne polyacrylate blends for pressure-sensitive adhesives[J/OL]. Journal of Applied Polymer Science, 2016, 133(6): 42965[2022-01-08].https://doi.org/10.1002/app.42965.
14	WANG J , YUAN L , WANG Z , et al. Photoinduced metal-free atom transfer radical polymerization of biomass-based monomers[J]. Macromolecules, 2016, 49 (20): 7709- 7717.
15	YU J , LIU Y , LIU X , et al. Integration of renewable cellulose and rosin towards sustainable copolymers by "grafting from" ATRP[J]. Green Chemistry, 2014, 16 (4): 1854- 1864.

样品samples	硬单体/g hard monomer		软单体(LMA)/g soft monomer	T_g/ ℃
样品samples	THFMA	DRM	软单体(LMA)/g soft monomer	T_g/ ℃
THFMA10-LMA	5	0	44.5	-54.50
THFMA20-LMA	10	0	39.5	-44.10
THFMA30-LMA	15	0	34.5	-32.70
THFMA40-LMA	20	0	29.5	-20.00
THFMA50-LMA	25	0	24.5	-5.90
DRM10-LMA	0	5	44.5	-56.11
DRM20-LMA	0	10	39.5	-47.55
DRM30-LMA	0	15	34.5	-38.28
DRM40-LMA	0	20	29.5	-28.22
DRM50-LMA	0	25	24.5	-17.26

样品samples	M_w	M_n	M_w/M_n
THFMA10-LMA	129 110	50 854	2.539
THFMA20-LMA	129 805	55 619	2.334
THFMA30-LMA	105 646	44 258	2.387
THFMA40-LMA	79 160	39 348	2.012
THFMA50-LMA	83 310	38 668	2.154
DRM10-LMA	115 007	38 823	2.962
DRM20-LMA	126 338	47 288	2.672
DRM30-LMA	141 947	33 335	4.258
DRM40-LMA	143 427	35 731	4.014
DRM50-LMA	117 453	32 409	3.624

样品samples	T_5%/℃	T_50%/℃	T_max/℃
THFMA10-LMA	274.2	359.2	364.2
THFMA30-LMA	271.1	354.2	364.2
THFMA50-LMA	271.7	354.1	364.2
DRM10-LMA	263.4	375.9	383.4
DRM30-LMA	255.9	383.9	395.9
DRM50-LMA	233.4	385.4	398.4

[1]	郭晓亮, 祁思迈, 王春鹏, 储富祥, 王基夫. 乙基纤维素-脂松香-油脂基聚合物的合成及其压敏胶应用性能[J]. 林产化学与工业, 2022, 42(3): 90-96.
[2]	齐帆, 蔡照胜, 商士斌, 黄旭娟. 松香及改性松香对Sn0.7Cu钎料的助焊性能研究[J]. 林产化学与工业, 2015, 35(6): 53-57.
[3]	张金龙;芮果;葛圣才;王鹏翔;张佩祥. 松香歧化用钯炭催化剂的制备[J]. 林产化学与工业, 2010, 30(1): 63-66.
[4]	白丽娟;雷福厚;莫丽君;罗影;黄永忠. 歧化松香胺Schiff碱-铜配合物催化苯乙烯氧化反应的研究[J]. 林产化学与工业, 2007, 27(S1): 99-104.
[5]	胡立红;周永红;宋湛谦. 松香基聚葡萄糖苷的合成及性能[J]. 林产化学与工业, 2006, 26(1): 11-14.
[6]	林明涛;储富祥;马丽;周道兵;王基夫;王春鹏. 歧化松香(丙烯酸-2-羟基乙基酯)酯的合成[J]. 林产化学与工业, 2006, 26(04): 43-47.
[7]	王亚明;宋胜梅;周梅村;贾庆明;陕昭云. 非贵金属催化剂催化松香歧化反应研究[J]. 林产化学与工业, 2003, 23(2): 21-24.
[8]	曹德榕;魏晓惠;陈就记;林莉;徐社阳. 浅色松香树脂的制备及浅色机理初探[J]. 林产化学与工业, 2002, 22(04): 37-39.

松香/生物基丙烯酸酯压敏胶的制备与性能研究

Preparation and Properties of Pressure Sensitive Adhesives Derived from Rosin Bio-based Acrylate

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 15

相关文章 8

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们