酸性熔盐水合物解聚木质素及其改性酚醛泡沫的性能研究

doi:10.3969/j.issn.0253-2417.2018.05.016

林产化学与工业 ›› 2018, Vol. 38 ›› Issue (5): 115-121.doi: 10.3969/j.issn.0253-2417.2018.05.016

酸性熔盐水合物解聚木质素及其改性酚醛泡沫的性能研究

杨晓慧^1,2, 尚倩倩¹, 贾普友², 周永红^1,2

1. 中国林业科学研究院林业新技术研究所, 北京 100091;
2. 中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2018-03-30 出版日期:2018-10-25 发布日期:2018-11-06
通讯作者: 周永红,研究员,主要从事生物质化学转化与应用研究;E-mail:zyh@icifp.cn。 E-mail:zyh@icifp.cn
作者简介:杨晓慧(1980-),男,山东临沂人,副研究员,博士,主要从事生物质资源转化与利用研究
基金资助:
中国林科院中央级公益性科研院所基本科研业务费专项资金（CAFYBB2016SY027）；江苏省生物质能源与材料重点实验室基本科研业务费项目资助（JSBEM-S-201803）

Properties of Phenolic Foam Modified by Lignin Depolymerized in Molten Salt Hydrate

YANG Xiaohui^1,2, SHANG Qianqian¹, JIA Puyou², ZHOU Yonghong^1,2

1. Research Institute of Forestry New Technology, CAF, Beijing 100091, China;
2. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2018-03-30 Online:2018-10-25 Published:2018-11-06

摘要/Abstract

摘要： 利用无机离子液体（酸性熔盐水合物）实现了木质素的有效降解，并将其应用到改性酚醛泡沫的研究中。研究表明：木质素可被有效降解，重均相对分子质量从3 900降为1 600，分散系数也明显降低，从4.10降为1.78，从而可提高木质素改性产品的稳定性和重现性。另外，木质素解聚后，酚羟基含量大大提高，从而可以增强木质素的反应活性，也为提高木质素的利用度奠定了基础。通过解聚木质素改性酚醛泡沫的研究发现：木质素的取代量为30%时，木质素酚醛泡沫总体性能较好，其压缩强度为235kPa，氧指数为38.1%，导热系数0.028W/（m·K），属难燃型高效保温材料。

关键词: 熔盐水合物, 木质素, 解聚, 酚醛树脂, 酚醛泡沫

Abstract: In this paper, lignin was effectively depolymerized by using inorganic ionic liquid (acidic molten salt hydrate) and applied in the research of modified phenolic foam. The results showed that lignin could be effectively degraded, the relative weight average molecular weight (M_w) decreased from 3 900 to 1 600, and the polymer dispersity index (PDI) expressed by M_w/M_n also decreased from 4.10 to 1.78 markly which will lead to improvement of the stability and reproducibility in the lignin modified products. In addition, the phenolic hydroxyl content was greatly increased after lignin depolymerization, which can enhance the reactivity of lignin and lay a foundation for improving the utilization of lignin. Moreover, phenolic foam modified by 30% depolymerized lignin exhibited a good property with a compressive strength of 235 kPa, the limited oxygen index 38.1% and the coefficient of thermal conductivity 0.028 W/(m·K). These showed that the product might be non-combustible and efficient insulation materials.

Key words: molten salt hydrate, lignin, depolymerization, phenolic resin, phenolic foam

中图分类号:

TQ35

杨晓慧, 尚倩倩, 贾普友, 周永红. 酸性熔盐水合物解聚木质素及其改性酚醛泡沫的性能研究[J]. 林产化学与工业, 2018, 38(5): 115-121.

YANG Xiaohui, SHANG Qianqian, JIA Puyou, ZHOU Yonghong. Properties of Phenolic Foam Modified by Lignin Depolymerized in Molten Salt Hydrate[J]. Chemistry and Industry of Forest Products, 2018, 38(5): 115-121.

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酸性熔盐水合物解聚木质素及其改性酚醛泡沫的性能研究

Properties of Phenolic Foam Modified by Lignin Depolymerized in Molten Salt Hydrate

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