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林产化学与工业 ›› 2018, Vol. 38 ›› Issue (6): 1-10.doi: 10.3969/j.issn.0253-2417.2018.06.001

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腰果酚光固化材料的研究进展

陈健1,2, 吴国民1,2, 霍淑平1,2, 孔振武1,2   

  1. 1. 中国林业科学研究院 林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局 林产化学工程重点开放性实验室;江苏省 生物质能源与材料重点实验室, 江苏 南京 210042;
    2. 南京林业大学 江苏省林业资源高效加工利用协同创新中心, 江苏 南京 210037
  • 收稿日期:2018-09-21 出版日期:2018-12-25 发布日期:2018-12-27
  • 通讯作者: 孔振武,研究员,博士,博士生导师,主要从事生物基聚合物材料研究;E-mail:kongzwlhs@163.com。 E-mail:kongzwlhs@163.com
  • 作者简介:陈健(1980-),男,江苏扬州人,助理研究员,硕士,主要从事生物基材料研究工作
  • 基金资助:
    中国林科院中央级公益性科研院所基本科研业务费专项资金(CAFYBB2016MA007)

Research Progress of Cardanol Based UV-cured Materials

CHEN Jian1,2, WU Guomin1,2, HUO Shuping1,2, KONG Zhenwu1,2   

  1. 1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Procince, Nanjing 210042, China;
    2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
  • Received:2018-09-21 Online:2018-12-25 Published:2018-12-27

摘要: 光固化涂料具有固化速度快、节能环保等优势,在诸多领域得到应用。天然腰果酚可替代石油基酚类化合物广泛应用于涂料、胶黏剂、聚合物材料等领域。腰果酚含有酚羟基和侧链不饱和双键,具有较高的反应活性,可通过化学改性应用于光固化涂料。简单介绍了腰果酚的来源及分子结构,从腰果酚直接紫外光固化、酚羟基改性(酯化和醚化)、侧链改性及复合改性等角度,综述了近年来国内外有关腰果酚光固化材料的研究和应用进展,并展望了腰果酚光固化材料未来研究的热点。

关键词: 腰果酚, 光固化, 涂料, 材料

Abstract: UV curing coatings could be applied in many fields due to its advantages such as fast drying and curing rate, energy saving, environmental protection and so on. Cardanol derived from natural biomass resources could replace petroleum phenol to be used in coatings, adhesives, polymer materials and other fields. Cardanol had high reactivity resulting fromits phenolic hydroxyl group and unsaturated double bond,which has allowed it be widely used in UV-cured materials through chemical modification. This review briefly introduced the source and molecular structure of cardanol and mainly focused on research progress of the direct UV curing of cardanol and the cardanol modification including phenolic hydroxyl modification (esterification and etherification), side chain modification and composite modification.Inaddition, this review also covers the application in the field of cardanol based UV-cured materials and the future research hotspot of UV-cured materials.

Key words: cardanol, UV curing, coating, material

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