林产化学与工业 ›› 2021, Vol. 41 ›› Issue (2): 119-129.doi: 10.3969/j.issn.0253-2417.2021.02.016
徐开蒙1,2, 王智辉1, 史正军1,2, 吴佳喜1, 张钰禄1, 杜官本1,2,*()
收稿日期:
2020-07-27
出版日期:
2021-04-28
发布日期:
2021-05-08
通讯作者:
杜官本
E-mail:Guanben@swfu.edu.cn
作者简介:
杜官本, 教授, 博士生导师, 主要从事木材胶黏剂与生物质复合材料的研究; E-mail: Guanben@swfu.edu.cn基金资助:
Kaimeng XU1,2, Zhihui WANG1, Zhengjun SHI1,2, Jiaxi WU1, Yulu ZHANG1, Guanben DU1,2,*()
Received:
2020-07-27
Online:
2021-04-28
Published:
2021-05-08
Contact:
Guanben DU
E-mail:Guanben@swfu.edu.cn
摘要:
纤维素和壳聚糖是地球上储量最丰富的两种天然高分子,通过静电纺丝法将纤维素与壳聚糖高效复合可制备综合性能突出的绿色功能化纳米纤维新材料,并进一步拓展二者的应用领域。适宜溶剂体系的选用与开发是静电纺丝法制备高品质纳米纤维的重要前提和保证。基于此,本文综述了近年来国内外学者们对静电纺丝纤维素、壳聚糖单一纳米纤维以及两者复合纳米纤维主要溶剂体系(包括有机溶剂、水相溶剂和离子液体溶剂)的相关特性、溶解效果、溶解机理以及纳米纤维纺丝效果的研究进展,为纤维素、壳聚糖高附加值纳米化利用及其复合功能化纳米纤维的开发提供理论参考。
中图分类号:
徐开蒙, 王智辉, 史正军, 吴佳喜, 张钰禄, 杜官本. 纤维素/壳聚糖电纺纳米纤维溶剂体系研究进展[J]. 林产化学与工业, 2021, 41(2): 119-129.
Kaimeng XU, Zhihui WANG, Zhengjun SHI, Jiaxi WU, Yulu ZHANG, Guanben DU. Review of Solvent System for Electrospinning of Cellulose/Chitosan Nanofibers[J]. Chemistry and Industry of Forest Products, 2021, 41(2): 119-129.
表1
纤维素在不同溶剂体系中的静电纺丝纳米纤维对比"
溶剂体系类型type of solvent system | 溶剂体系特征characteristics of solvent system | 可纺质量分数/% elecrospinnable mass fraction | 纳米纤维直径/nmdiameter of nanofiber | 纳米纤维特征characteristic of nanofiber |
LiCl/DMAc | 稳定,回收困难,溶解度有限good stability, uneasy recycling, limited solubility | 1-3 | 100-750 | 需后处理needing post-treatment |
NMMO | 易氧化,溶液黏度大easy to oxidize, high solution viscosity | 2-4 | 207-750 | 易粘连,形貌不易控制sticky, difficult morphology control |
TFA | 固化快速,腐蚀性强,易挥发fast curing, strong corrosion and volatility | 1.3-5 | 16-367 | 直径及其分布较小small diameter and its narrow distribution |
NaOH/Urea/H2O | 价廉易得,溶解温度范围窄low cost, narrow dissolution temperature range | 2-4 | 400 | 表面粗糙,有絮状物rough surface with flocculent particles |
IL | 溶解能力强,电导率高strong solubility and high conductivity | 8-15 | 100-7750 | 稳定且光滑stable and smooth |
表2
壳聚糖在不同溶剂体系中的静电纺丝纳米纤维对比"
溶剂体系类型type of solvent system | 溶剂体系特征characteristic of solvent system | 可纺质量分数/%elecrospinnable mass fraction | 纳米纤维直径/nmdiameter of nanofiber | 纳米纤维特征characteristics of nanofiber |
HAc | 溶解时间长、浓度范围宽long dissolution time and wide concentration range | 1-90 | 130-310 | 稳定且光滑stable and smooth |
TFA | 固化快速,腐蚀性强,易挥发fast curing, strong corrosion and volatility | 6-8 | 40-610 | 有部分珠状物或粘连partial beads or adhesion |
IL | 溶解能力强,电导率高strong solubility and high conductivity | 3-12.79 | 40-453 | 稳定且光滑stable and smooth |
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