林产化学与工业 ›› 2021, Vol. 41 ›› Issue (3): 1-10.doi: 10.3969/j.issn.0253-2417.2021.03.001
赵振东1,2(), 王婧1,2,3, 卢言菊1,2, 陈玉湘1,2
收稿日期:
2020-11-10
出版日期:
2021-06-28
发布日期:
2021-07-01
作者简介:
赵振东(1960-), 男(白族), 云南昌宁人, 研究员, 博士生导师, 研究领域为萜类化学、松树病虫害化学、天然产物化学、应用化学等方面; E-mail: zdzhao@189.cn
基金资助:
Zhendong ZHAO1,2(), Jing WANG1,2,3, Yanju LU1,2, Yuxiang CHEN1,2
Received:
2020-11-10
Online:
2021-06-28
Published:
2021-07-01
摘要:
优质松树资源是松脂可持续、高附加值、精细化学利用的基础。根据松脂化学组成及结构特点,结合对松脂资源及其深加工利用产业现状的分析,从松脂精细化学利用角度讨论了个性化松脂资源需求。从松脂生产、加工、利用及效益等不同角度来看,需要具有产脂力强、产脂时间长、松脂品质好、易于加工等优良性能的集约化优质松脂资源,而从深加工利用角度看,更需要具备品质优良、有效成分含量高、化学组分均衡或特异性成分突出等特性的个性化松脂资源。研究选育能特产的个性化松脂资源,诸如海松酸型松香、异海松酸型松香、南亚松酸型松香、α-蒎烯型松节油、β-蒎烯型松节油、3-蒈烯型松节油、β-水芹烯型松节油、长叶烯型重松节油等产品对于松香、松节油的精细化、高附加值深加工利用具有重要的科学意义和应用价值。建议围绕马尾松、思茅松、湿地松、湿加松、南亚松等主要采脂树种,有针对性地开展松脂化学、精细化学品、基因组学、代谢组学、遗传育种、资源培育、林产化工等相关学科既交叉又综合的个性化研究工作。
中图分类号:
赵振东, 王婧, 卢言菊, 陈玉湘. 松脂精细化学利用对个性化松树资源的需求分析[J]. 林产化学与工业, 2021, 41(3): 1-10.
Zhendong ZHAO, Jing WANG, Yanju LU, Yuxiang CHEN. Demand Analysis of Individuation Pine Resources for Fine Chemical Utilization of Pine Oleoresin[J]. Chemistry and Industry of Forest Products, 2021, 41(3): 1-10.
1 | 王瑾, 聂影. 中国松香产业内贸易类型评价[J]. 南京林业大学学报(自然科学版), 2017, 41 (2): 203- 206. |
WANG J , NIE Y . Evaluation of the intra-industry trade type of Chinese rosin[J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2017, 41 (2): 203- 206. | |
2 | 董静曦, 郭辉军, 赵元藩, 等. 我国的采脂松树资源和松脂贮量——基于"连清"数据的估测[J]. 林业科学, 2009, 45 (12): 112- 117. |
DONG J X , GUO H J , ZHAO Y F , et al. Forest resources and estimated resin production of pines in China: Based on the data of successive nation-wide inventory of forest resources[J]. Scientia Silvae Sinicae, 2009, 45 (12): 112- 117. | |
3 |
董静曦, 郭辉军, 张子翼, 等. 近10年来我国松脂资源的动态变化——基于连清数据的动态评估[J]. 林业科学, 2016, 52 (12): 112- 122.
doi: 10.11707/j.1001-7488.20161214 |
DONG J X , GUO H J , ZHANG Z Y , et al. Dynamic change of pine resin resources in China in the last ten years: Based on the data of continuous forest resource inventory[J]. Scientia Silvae Sinicae, 2016, 52 (12): 112- 122.
doi: 10.11707/j.1001-7488.20161214 |
|
4 |
赵振东, 李冬梅, 张春玲, 等. 松脂含量快速评估模型的研究与应用[J]. 林产化学与工业, 2017, 37 (1): 21- 26.
doi: 10.3969/j.issn.0253-2417.2017.01.003 |
ZHAO Z D , LI D M , ZHANG C L , et al. Study and application of rapid evaluation model of oleoresin content[J]. Chemistry and Industry of Forest Products, 2017, 37 (1): 21- 26.
doi: 10.3969/j.issn.0253-2417.2017.01.003 |
|
5 | 粟子安. 中国松脂的化学组成[J]. 林产化学与工业, 1993, 13 (S1): 33- 40. |
SU Z A . Chemical constituents of oleoresin from the main Chinese pine species[J]. Chemistry and Industry of Forest Products, 1993, 13 (S1): 33- 40. | |
6 |
宋湛谦. 松香的精细化工利用(Ⅵ)——国内外现状与发展动向[J]. 林产化工通讯, 2003, 37 (3): 43- 45.
doi: 10.3969/j.issn.1673-5854.2003.03.012 |
SONG Z Q . Fine chemical utilization of rosin(Ⅵ): The domestic and abroad status and developing tendency[J]. Journal of Chemical Industry of Forest Products, 2003, 37 (3): 43- 45.
doi: 10.3969/j.issn.1673-5854.2003.03.012 |
|
7 |
赵振东, 刘先章. 松节油的精细化学利用(Ⅰ)——松节油及精细化学利用基础[J]. 林产化工通讯, 2001, 35 (1): 42- 47.
doi: 10.3969/j.issn.1673-5854.2001.01.012 |
ZHAO Z D , LIU X Z . Fine chemical utilization of turpentine(Ⅰ): Turpentine and the basis of fine chemical utilization[J]. Journal of Chemical Industry of Forest Products, 2001, 35 (1): 42- 47.
doi: 10.3969/j.issn.1673-5854.2001.01.012 |
|
8 | 农韦健, 陈小鹏, 梁杰珍, 等. 枞酸单离与应用研究进展[J]. 化工进展, 2014, 33 (5): 1259- 1264. |
NONG W J , CHEN X P , LIANG J Z , et al. Research progress of isolation and application of abietic acid[J]. Chemical Industry and Engineering Progress, 2014, 33 (5): 1259- 1264. | |
9 | 刘红军, 张猛, 周永红. 松脂中树脂酸的酸异构分离与枞酸分子结构[J]. 林业科学, 2010, 46 (8): 140- 144. |
LIU H J , ZHANG M , ZHOU Y H . Acid isomer separation of resin acids in rosin and abietic acid molecular structure[J]. Scientia Silvae Sinicae, 2010, 46 (8): 140- 144. | |
10 |
李兴迪, 赵振东, 陈玉湘, 等. 海松酸型树脂酸的分离及应用研究进展[J]. 生物质化学工程, 2008, 42 (3): 51- 54.
doi: 10.3969/j.issn.1673-5854.2008.03.011 |
LI X D , ZHAO Z D , CHEN Y X , et al. Progress on separation and application of pimaric-type resin acids[J]. Biomass Chemical Engineering, 2008, 42 (3): 51- 54.
doi: 10.3969/j.issn.1673-5854.2008.03.011 |
|
11 |
李兴迪, 陈玉湘, 赵振东, 等. 异海松酸分离制备的新方法[J]. 林产化学与工业, 2008, 28 (5): 21- 25.
doi: 10.3321/j.issn:0253-2417.2008.05.005 |
LI X D , CHEN Y X , ZHAO Z D , et al. New process for isolation and preparation of isopimaric acid[J]. Chemistry and Industry of Forest Products, 2008, 28 (5): 21- 25.
doi: 10.3321/j.issn:0253-2417.2008.05.005 |
|
12 |
李春成, 朱光, 李贞宜. 脱氢枞酸型聚丙烯成核剂的研究[J]. 高技术通讯, 2001, 11 (12): 87- 90.
doi: 10.3321/j.issn:1002-0470.2001.12.022 |
LI C C , ZHU G , LI Z Y . Study on dehydroabietic acid-type nucleating agent for polypropylene[J]. Chinese High Technology Letters, 2001, 11 (12): 87- 90.
doi: 10.3321/j.issn:1002-0470.2001.12.022 |
|
13 |
高红云, 哈成勇. 高纯β-蒎烯的制备[J]. 精细化工, 2006, 23 (11): 1134- 1137.
doi: 10.3321/j.issn:1003-5214.2006.11.022 |
GAO H Y , HA C Y . Preparation of high-purity β-pinene[J]. Fine Chemicals, 2006, 23 (11): 1134- 1137.
doi: 10.3321/j.issn:1003-5214.2006.11.022 |
|
14 |
米世伍, 范芳. 重质松节油催化反应制备高纯度长叶烯的研究[J]. 生物质化学工程, 2006, 40 (5): 28- 30.
doi: 10.3969/j.issn.1673-5854.2006.05.008 |
MI S W , FAN F . Study on catalytic reaction for preparation of high purity longifolene from heavy turpentine[J]. Biomass Chemical Engineering, 2006, 40 (5): 28- 30.
doi: 10.3969/j.issn.1673-5854.2006.05.008 |
|
15 |
王琳琳, 陈小鹏, 刘幽燕, 等. 松香树脂酸的单离与应用[J]. 化工进展, 2005, 24 (11): 1301- 1305.
doi: 10.3321/j.issn:1000-6613.2005.11.022 |
WANG L L , CHEN X P , LIU Y Y , et al. Isolation and application of rosin acids[J]. Chemical Industry and Engineering Progress, 2005, 24 (11): 1301- 1305.
doi: 10.3321/j.issn:1000-6613.2005.11.022 |
|
16 |
王迷霞, 徐士超, 卢言菊, 等. 异海松酸甲酯的合成与结构表征[J]. 林产化学与工业, 2015, 35 (6): 15- 20.
doi: 10.3969/j.issn.0253-2417.2015.06.003 |
WANG M X , XU S C , LU Y J , et al. Synthesis and structural characterization of methyl isopimarate[J]. Chemistry and Industry of Forest Products, 2015, 35 (6): 15- 20.
doi: 10.3969/j.issn.0253-2417.2015.06.003 |
|
17 | 韩春蕊, 宋湛谦. 枞酸衍生物的合成、表征与生物活性研究[J]. 现代化工, 2009, 29 (S2): 79- 82. |
HAN C R , SONG Z Q . Study on synthesis, characterization and biological activities of abietic acid derivatives[J]. Modern Chemical Industry, 2009, 29 (2): 79- 82. | |
18 | 刘娟娟, 赵振东, 卢言菊, 等. 异海松酸基酰腙化合物的合成及抗癌活性[J]. 精细化工, 2016, 33 (10): 1195- 1200. |
LIU J J , ZHAO Z D , LU Y J , et al. Synthesis and anticancer activity of acylhydrazone compounds from isopimaric acid[J]. Fine Chemicals, 2016, 33 (10): 1195- 1200. | |
19 | 刘娟娟, 卢言菊, 王婧, 等. 异海松酰(胺)基硫脲类衍生物的合成及其生物活性评价[J]. 有机化学, 2017, 37 (3): 731- 738. |
LIU J J , LU Y J , WANG J , et al. Synthesis and bioactivity evaluation of acylthiourea derivatives based on isopimaric acid[J]. Chinese Journal of Organic Chemistry, 2017, 37 (3): 731- 738. | |
20 | 刘娟娟, 赵振东, 卢言菊, 等. 异海松酰肼系列衍生物的合成与表征[J]. 化学试剂, 2017, 39 (5): 549- 552. |
LIU J J , ZHAO Z D , LU Y J , et al. Synthesis and characterization of isopimaric hydrazide derivatives[J]. Chemical Reagents, 2017, 39 (5): 549- 552. | |
21 | 蔡成辉, 付耿声. 使用优级松节油及湿钛催化剂直接异构制莰烯的探讨[J]. 福建林业科技, 1991, 18 (2): 28- 30. |
CAI C H , FU G S . Study on preparation of camphene by direct isomerization of superior turpentine and wet titanium catalyst[J]. Journal of Fujian Forestry Science & Technology, 1991, 18 (2): 28- 30. | |
22 | 李冬梅, 赵振东, 毕良武, 等. 松节油合成高纯度α-松油醇的研究[J]. 现代化工, 2008, 28 (2): 345- 348. |
LI D M , ZHAO Z D , BI L W , et al. Study on synthesis of high purity α-terpineol from turpentine oil[J]. Modern Chemical Industry, 2008, 28 (2): 345- 348. | |
23 |
赵振东, 刘先章. 松节油的精细化学利用(Ⅱ)——松节油合成日化香料(上)[J]. 林产化工通讯, 2001, 35 (2): 41- 46.
doi: 10.3969/j.issn.1673-5854.2001.02.011 |
ZHAO Z D , LIU X Z . Fine chemical utilization of turpentine(Ⅱ): Synthetic perfume of turpentine(upper)[J]. Journal of Chemical Industry of Forest Products, 2001, 35 (2): 41- 46.
doi: 10.3969/j.issn.1673-5854.2001.02.011 |
|
24 |
赵振东, 孙震, 刘先章. 松节油的精细化学利用(Ⅳ)——松节油合成日化香料(下)[J]. 林产化工通讯, 2001, 35 (4): 34- 40.
doi: 10.3969/j.issn.1673-5854.2001.04.009 |
ZHAO Z D , SUN Z , LIU X Z . Fine chemical utilization of turpentine(Ⅳ): Synthetic perfume of turpentine(lower)[J]. Journal of Chemical Industry of Forest Products, 2001, 35 (4): 34- 40.
doi: 10.3969/j.issn.1673-5854.2001.04.009 |
|
25 |
赵振东, 刘先章. 松节油的精细化学利用(Ⅴ)——松节油合成药理活性物质[J]. 林产化工通讯, 2001, 35 (5): 35- 40.
doi: 10.3969/j.issn.1673-5854.2001.05.010 |
ZHAO Z D , LIU X Z . Fine chemical utilization of turpentine(Ⅴ): Turpentine synthesis of pharmacological active substances[J]. Journal of Chemical Industry of Forest Products, 2001, 35 (5): 35- 40.
doi: 10.3969/j.issn.1673-5854.2001.05.010 |
|
26 | 冯金桃, 吴乾平. 湿加松新资源及其开发利用[J]. 林产化学与工业, 2005, 25 (S1): 91- 94. |
FENG J T , WU Q P . New resource of Pinus elliottii×P.caribaea and its exploitational utilization[J]. Chemistry and Industry of Forest Products, 2005, 25 (S1): 91- 94. | |
27 | 周晨晨, 李义良, 王哲, 等. 基于RNA-Seq技术的湿加松特定时期产脂差异基因筛选及表达分析[J]. 植物研究, 2021, 41 (3): 419- 428. |
ZHOU C C , LI Y L , WANG Z , et al. Screening and expression analysis of different genes for oleoresin production in the specific period of pinus elliottii×P.caribaea by RNA-Seq technology[J]. Bulletin of Botanical Research, 2021, 41 (3): 419- 428. | |
28 | 冯源恒, 杨章旗, 李火根, 等. 不同时期广西马尾松优良种源的遗传多样性变化趋势[J]. 南京林业大学学报(自然科学版), 2016, 40 (5): 41- 46. |
FENG Y H , YANG Z Q , LI H G , et al. A study on changes of genetic diversity for nearly 50 years in superior provenances of Pinus massoniana in Guangxi[J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2016, 40 (5): 41- 46. | |
29 | 冯源恒, 杨章旗, 李火根, 等. 广西马尾松第2代育种群体的组建[J]. 林业科学, 2017, 53 (1): 54- 61. |
FENG Y H , YANG Z Q , LI H G , et al. Construction of second-generation breeding population of Pinus massoniana in Guangxi[J]. Scientia Silvae Sinicae, 2017, 53 (1): 54- 61. | |
30 | 翁海龙, 陈宏伟, 段安安. 思茅松高产脂优树选择[J]. 西北林学院学报, 2010, 25 (3): 71- 74. |
WENG H L , CHEN H W , DUAN A A . Selection of plus-tree with high-rosin production for Pinus kesiya var.langbianensis[J]. Journal of Northwest Forestry University, 2010, 25 (3): 71- 74. | |
31 | 李思广, 付玉嫔, 蒋云东, 等. 高产脂思茅松松节油组分研究[J]. 四川林业科技, 2018, 39 (2): 33- 36. |
LI S G , FU Y P , JIANG Y D , et al. A study of turpentine composition of high-resin-yield Pinus kesiya var.langbianensis[J]. Journal of Sichuan Forestry Science and Technology, 2018, 39 (2): 33- 36. | |
32 | 陈小鹏, 王琳琳, 梁杰珍, 等. 一种膜下采集松脂的方法: CN103583314B[P]. 2017-02-15. |
CHEN X P, WANG L L, LIANG J Z, et al. Resin tapping method: CN103583314B[P]. 2017-02-15. | |
33 |
陈小鹏, 王琳琳, 祝远姣, 等. 松脂贮存过程的褐变作用及漂洗方法[J]. 林产化学与工业, 2004, 24 (4): 15- 19.
doi: 10.3321/j.issn:0253-2417.2004.04.004 |
CHEN X P , WANG L L , ZHU Y J , et al. Browning of pine gum during its storage and rinsing[J]. Chemistry and Industry of Forest Products, 2004, 24 (4): 15- 19.
doi: 10.3321/j.issn:0253-2417.2004.04.004 |
|
34 |
古研, 陈玉湘, 赵振东, 等. 松香中枞酸型树脂酸在酸作用下变化规律的研究(英文)[J]. 林产化学与工业, 2015, 35 (3): 73- 79.
doi: 10.3969/j.issn.0253-2417.2015.03.013 |
GU Y , CHEN Y X , ZHAO Z D , et al. Variations relationship of abietic-type acids under acid treatment[J]. Chemistry and Industry of Forest Products, 2015, 35 (3): 73- 79.
doi: 10.3969/j.issn.0253-2417.2015.03.013 |
|
35 | 国家林业局. GB/T 12901-2006脂松节油[S]. 北京: 中国标准出版社, 2006. |
State Forestry Administration, P.R. China. GB/T 12901-2006 Gum turpentine oil[S]. Beijing: Standards Press of China, 2006. | |
36 | 龙虎, 杨如春, 周萍, 等. 广东的湿地松松脂的主要化学组成及对其影响的因素[J]. 广东林业科技, 1987, (4): 9- 18. |
LONG H , YANG R C , ZHOU P , et al. Main chemical composition of Pinus elliottii resin from Guangdong and its influencing factors[J]. Guangdong Forestry Science and Technology, 1987, (4): 9- 18. | |
37 | 李思广, 付玉嫔, 蒋云东, 等. 高产脂思茅松松节油组分研究[J]. 四川林业科技, 2018, 39 (2): 33- 36. |
LI S G , FU Y P , JIANG Y D , et al. A study of turpentine composition of high-resin-yield Pinus kesiya var.langbianensis[J]. Journal of Sichuan Forestry Science and Technology, 2018, 39 (2): 33- 36. | |
38 | 李炽, 尹尧泽. 思茅松松节油中β-蒎烯含量的初步调查分析[J]. 林化科技通讯, 1983, 17 (10): 357- 361. |
LI C , YIN Y Z . Preliminary investigation and analysis of the content of β-pinenefrom Pinus kesiya var.langbianensis[J]. Journal of Science and Technology of Forestry Chemistry, 1983, 17 (10): 357- 361. | |
39 | 李炽. 思茅松松节油中β-蒎烯含量的研究[C]//中国树木提取物化学与利用学术讨论会论文集(上). 南宁: 中国林学会林产化学化工分会, 1989: 313-319. |
LI C. Study of content of β-pinene from Pinus kesiya var. langbianensis[C]//Proceedings of the Chinese symposium on the chemistry and utilization of tree extracts(part I), Nanning: Forestry Chemistry and Chemical Engineering Branch of Chinese Society of Forestry, 1989: 313-319. | |
40 |
李思广, 付玉嫔, 耿树香, 等. 高α-蒎烯思茅松无性系选择研究[J]. 福建林业科技, 2008, 35 (2): 78- 81.
doi: 10.3969/j.issn.1002-7351.2008.02.018 |
LI S G , FU Y P , GENG S X , et al. Study on clone selection of Pinus kesiya var.langbianensis with high content α-pinene in turpentine[J]. Journal of Fujian Forestry Science and Technology, 2008, 35 (2): 78- 81.
doi: 10.3969/j.issn.1002-7351.2008.02.018 |
|
41 | 中国林业科学研究院林产化学工业研究所. LY/T 1183-2014α-蒎烯[S]. 北京: 中国标准出版社, 2014. |
Institute of Chemical Industry of Forest Products, CAF. LYT 1183-2014α-Pinene[S]. Beijing: Standards Press of China, 2014. | |
42 | 罗嘉梁, 朱骏李, 仲训, 等. 高β-蒎烯的云南松(Pinus yunnanensis Franch.)调查研究[J]. 林产化学与工业, 1985, 5 (4): 1- 11. |
LUO J L , ZHU J L , ZHONG X , et al. Investigation on high β-pinene Pinus yunnanensis trees[J]. Chemistry and Industry of Forest Products, 1985, 5 (4): 1- 11. | |
43 |
付玉嫔, 李思广, 耿树香, 等. 高β-蒎烯含量思茅松松脂化学特征[J]. 氨基酸和生物资源, 2008, 30 (4): 29- 33.
doi: 10.3969/j.issn.1006-8376.2008.04.008 |
FU Y P , LI S G , GENG S X , et al. Chemical characteristics of high β-pinene content Pinus kesiya var.langbianensis[J]. Amino Acids & Biotic Resources, 2008, 30 (4): 29- 33.
doi: 10.3969/j.issn.1006-8376.2008.04.008 |
|
44 | 何丽芝, 王婧, 赵振东, 等. 3-蒈烯资源及其生物活性应用研究进展[J]. 林产化学与工业, 2011, 31 (3): 122- 126. |
HE L Z , WANG J , ZHAO Z D , et al. Research progress on resources and bioactivity applications of 3-carene[J]. Chemistry and Industry of Forest Products, 2011, 31 (3): 122- 126. | |
45 | 王婧. 3-蒈烯的精制及异构化反应研究[D]. 北京: 中国林业科学研究院, 2014. |
WANG J. Study on refining and isomerization of 3-carene[D]. Beijing: Chinese Academy of Forestry, 2014. | |
46 | 何丽芝. 3-蒈烯的制备、氢化及蒈烷溴化-酯化反应探索研究[D]. 北京: 中国林业科学研究院, 2012. |
HE L Z. Study on preparation, hydrogenation of 3-carene and bromination-esterification of carane[D]. Beijing: Chinese Academy of Forestry, 2012. | |
47 |
陈光英, 宋小平, 韩长日, 等. 加勒比松叶挥发油成分分析[J]. 中药材, 2001, 24 (9): 653- 654.
doi: 10.3321/j.issn:1001-4454.2001.09.017 |
CHEN G Y , SONG X P , HAN C R , et al. Analysis of volatile oil from leaves of Pinus caribaea[J]. Journal of Chinese Medicinal Materials, 2001, 24 (9): 653- 654.
doi: 10.3321/j.issn:1001-4454.2001.09.017 |
|
48 |
林之盼, 薛杨, 宿少锋, 等. 湿加松优良无性系选育与造林生长效果初步研究[J]. 热带农业科学, 2013, 33 (4): 12- 18.
doi: 10.3969/j.issn.1009-2196.2013.04.004 |
LIN Z P , XUE Y , SU S F , et al. Superior slash×caribbean pine clone breeding and afforestation growth effects[J]. Chinese Journal of Tropical Agriculture, 2013, 33 (4): 12- 18.
doi: 10.3969/j.issn.1009-2196.2013.04.004 |
|
49 |
陈玉湘, 赵振东, 李兴迪, 等. 海松酸型树脂酸生物活性及应用研究进展[J]. 林产化学与工业, 2008, 28 (4): 118- 122.
doi: 10.3321/j.issn:0253-2417.2008.04.025 |
CHEN Y X , ZHAO Z D , LI X D , et al. Progress of research on bio-activity and applications of pinaric-type resin acids[J]. Chemistry and Industry of Forest Products, 2008, 28 (4): 118- 122.
doi: 10.3321/j.issn:0253-2417.2008.04.025 |
|
50 |
陈玉湘, 王忠, 毕良武, 等. 海松酸型树脂酸资源分布及组成研究[J]. 生物质化学工程, 2008, 42 (4): 9- 12.
doi: 10.3969/j.issn.1673-5854.2008.04.003 |
CHEN Y X , WANG Z , BI L W , et al. Investigation on resource distribution and composition of pimaric-type resin acids[J]. Biomass Chemical Engineering, 2008, 42 (4): 9- 12.
doi: 10.3969/j.issn.1673-5854.2008.04.003 |
|
51 |
陈玉湘, 赵振东, 古研, 等. 松香中海松酸型树脂酸热作用变化规律的研究[J]. 林产化学与工业, 2009, 29 (2): 33- 38.
doi: 10.3321/j.issn:0253-2417.2009.02.007 |
CHEN Y X , ZHAO Z D , GU Y , et al. Study on thermal variation rule of pimaric-type acids in rosin[J]. Chemistry and Industry of Forest Products, 2009, 29 (2): 33- 38.
doi: 10.3321/j.issn:0253-2417.2009.02.007 |
|
52 |
陈玉湘, 赵振东, 古研, 等. 松香中海松酸型树脂酸在酸作用下的组成变化规律[J]. 精细化工, 2009, 26 (8): 818- 823.
doi: 10.3321/j.issn:1003-5214.2009.08.022 |
CHEN Y X , ZHAO Z D , GU Y , et al. Study on composition variation relationships of pimaric-type resin acids in rosin at acidic conditions[J]. Fine Chemicals, 2009, 26 (8): 818- 823.
doi: 10.3321/j.issn:1003-5214.2009.08.022 |
|
53 |
王石发. 柬埔寨南亚松松香和松节油的化学组成特征[J]. 林产化学与工业, 2007, 27 (5): 31- 36.
doi: 10.3321/j.issn:0253-2417.2007.05.007 |
WANG S F . Chemical composition characteristics of Pinus latteri Mason rosin and turpentine from the south of Cambodia[J]. Chemistry and Industry of Forest Products, 2007, 27 (5): 31- 36.
doi: 10.3321/j.issn:0253-2417.2007.05.007 |
|
54 | 徐阿生. 西藏高山松松脂资源及其开发利用前景[J]. 资源开发与市场, 1995, 11 (4): 158- 161. |
XU A S . Development and utilization prospect of resin resources of Pinus sylvestris in Tibet[J]. Resource Develepoment & Market, 1995, 11 (4): 158- 161. | |
55 | 宋湛谦. 中国松脂特征与松属分类[M]. 北京: 中国林业出版社, 1998. |
SONG Z Q . Characteristics of Oleoresin and Classification of Pinus in China[M]. Beijing: China Forestry Publishing House, 1998. | |
56 | 李淑秀. 红松明子抽提物——木松节油、选矿油、釜残油化学成分的研究[J]. 林产化学与工业, 1993, 13 (1): 83- 88. |
LI S X . Study on the chemical constituents of wood turpentine oil, flotation oil and distillation residue extracted from pin stumps[J]. Chemistry and Industry of Forest Products, 1993, 13 (1): 83- 88. |
[1] | 刘一繁, 姜宇, 韩有奇, 李淑君, 姜贵全, 韩世岩. 生物质基绿色荧光N掺杂碳点的制备及分析[J]. 林产化学与工业, 2021, 41(2): 79-85. |
[2] | 岳贤田, 曾韬, 凌清华, 王雪源. 不同介质下松脂蒸馏中松香树脂酸的异构化反应[J]. 林产化学与工业, 2018, 38(4): 124-128. |
[3] | 赵振东, 李冬梅, 张春玲, 毕良武, 王婧, 古研, 陈玉湘. 松脂含量快速评估模型的研究与应用[J]. 林产化学与工业, 2017, 37(1): 21-26. |
[4] | 彭密军, 吕强, 彭胜, 张昌伟, 张琳杰, 王志宏, 周云雷. 杜仲总木脂素及松脂醇二葡萄糖苷的纯化研究[J]. 林产化学与工业, 2014, 34(6): 88-92. |
[5] | 徐春明, 王英英, 李婷, 庞高阳, 李丹. 银杏叶总黄酮的微波提取及生物利用度研究[J]. 林产化学与工业, 2014, 34(4): 131-136. |
[6] | 闫金定. 我国生物质能源发展现状与战略思考[J]. 林产化学与工业, 2014, 34(4): 151-158. |
[7] | 姜贵全, 方桂珍, 师振鑫, 张卓睿, 庞久寅. 超临界CO2萃取除脂后再经纤维素酶辅助提取落叶松树皮原花青素[J]. 林产化学与工业, 2014, 34(2): 97-102. |
[8] | 姜永新;朱宏涛;王军民;张颖君;张加研;华燕;赵平. 松树皮原花青素片段化产物的LC-ESI-MS分析[J]. 林产化学与工业, 2013, 33(4): 117-120. |
[9] | 徐勇;;江寅申;左志凤;张行星;勇强;余世袁;. 阴离子交换树脂对玉米秸秆蒸汽爆破预处理液的选择性脱毒[J]. 林产化学与工业, 2012, 32(5): 11-18. |
[10] | 戚建华;姚增玉. 生物柴油原料树种文冠果的化学成分与综合利用研究进展[J]. 林产化学与工业, 2012, 32(2): 47-54. |
[11] | 孙小芹;庞慧;郭建林;彭斌;白明明;杭悦宇. 十字花科58属94种野生植物种子脂肪酸组分分析[J]. 林产化学与工业, 2011, 31(6): 46-54. |
[12] | 薄采颖;郑光耀;陈琰;周维纯;李若达;谢学容. 松树皮多酚的亚临界水提取及抗氧化活性初探[J]. 林产化学与工业, 2011, 31(6): 73-77. |
[13] | 黄森丽;陈小鹏;王琳琳;谢丹丹;梁杰珍. 超临界状态下松脂与甲醇反应产物的GC-MS分析[J]. 林产化学与工业, 2011, 31(5): 90-94. |
[14] | 毕良武;赵振东;韩路路;李大伟. 几种潜在的植物角鲨烯资源综述[J]. 林产化学与工业, 2011, 31(4): 102-108. |
[15] | 何丽芝;王婧;赵振东;陈玉湘;古研;. 3-蒈烯资源及其生物活性应用研究进展[J]. 林产化学与工业, 2011, 31(3): 122-126. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||