林产化学与工业 ›› 2022, Vol. 42 ›› Issue (2): 125-136.doi: 10.3969/j.issn.0253-2417.2022.02.017
• 综述评论 • 上一篇
林晓清1,2,3(), 陶顺辉1, 胡蕾1, 郑晓洁1, 张晓东1, 刘耀1
收稿日期:
2021-07-01
出版日期:
2022-04-28
发布日期:
2022-05-06
作者简介:
林晓清(1987-), 男, 福建泉州人, 副教授, 博士, 博士生导师, 研究领域为吸附与色谱分离工程、生物炼制化学品、可降解材料研发与应用; E-mail: linxiaoqing@gdut.edu.cn
基金资助:
Xiaoqing LIN1,2,3(), Shunhui TAO1, Lei HU1, Xiaojie ZHENG1, Xiaodong ZHANG1, Yao LIU1
Received:
2021-07-01
Online:
2022-04-28
Published:
2022-05-06
摘要:
石油资源日渐枯竭、白色污染日趋严重,以木质纤维素资源为原料制备生物基聚呋喃二甲酸乙二醇酯(PEF)已成为生物炼制与绿色化工领域研究的热点之一。与广泛应用的聚对苯二甲酸乙二醇酯(PET)和聚碳酸酯(PC)等石油基塑料相比,PEF不仅具有优异的热性能和机械强度,而且在气体阻隔性能上的优势更为明显,被认为是PET的完美替代品。然而,PEF存在断裂伸长率过低、产品颜色深、难以降解、深结晶速度慢等问题,因此,在实际应用中需要对其进行改性。本文重点综述了PEF改性研究的进展,包括共聚、共混等多种改性方法;总结了催化剂类型、不同二醇或二酸改性单体、反应进行方式以及添加剂等对PEF性能影响的规律,并展望了改性PEF的发展趋势和应用前景。
中图分类号:
林晓清, 陶顺辉, 胡蕾, 郑晓洁, 张晓东, 刘耀. 生物基聚2, 5-呋喃二甲酸乙二醇酯的改性研究进展[J]. 林产化学与工业, 2022, 42(2): 125-136.
Xiaoqing LIN, Shunhui TAO, Lei HU, Xiaojie ZHENG, Xiaodong ZHANG, Yao LIU. Research Progress in the Modification of Bio-based Poly(Ethylene 2, 5-Furandicarboxylate)[J]. Chemistry and Industry of Forest Products, 2022, 42(2): 125-136.
表1
典型呋喃基聚酯的力学和热学性能汇总1)"
聚合物 polymer | 二醇单体 diol monomer | 抗拉强度/MPa tensile strength | 断裂伸长率/% elongation at break | 杨氏模量/MPa Young's modulus | Tg/℃ | Tm/℃ | Td/℃ | 参考文献 reference |
PEF | 乙二醇ethylene | 85±9 | 5±1 | 2800±120 | 85 | 211 | 389 | [ |
PPF | 丙二醇1, 3-propanediol | 68.2 | 46 | 1550 | 55 | 180 | 360 | [ |
PBF | 1, 4-丁二醇1, 4-butanediol | 61.76±2.72 | 255±81 | 1460±99 | 40 | 171 | 328 | [ |
PPeF | 1, 5-戊二醇1, 5-butyl glycol | 14±2 | 320±11 | 23.9 | 342 | [ | ||
PHF | 1, 6-己二醇1, 6-hexanediol | 35.5 | 210 | 493 | 20 | 148 | 375 | [ |
POF | 1, 8-辛二醇1, 8-octanediol | 26.5±1.5 | 160±15 | 310.5±21 | -5 | 140 | [ | |
PNF | 1, 9-壬二醇1, 9-azelaic alcohol | 21.0±1.6 | 149±11 | 251.7±19 | -30 | 69 | [ | |
PDeF | 1, 10-癸二醇1, 10-decamethylene glycol | 11.4±1.2 | 135±17 | 201.9±15 | -8 | 116 | [ | |
PDoF | 1, 12-十二烷二醇1, 12-dodecanediol | 10.8±0.9 | 130±10 | 180.7±16 | -22 | 111 | [ | |
PM20F | 1, 20-二十烷二醇1, 20-eicosanediol | 8 | 107 | 358 | [ |
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