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林产化学与工业 ›› 2015, Vol. 35 ›› Issue (5): 149-158.doi: 10.3969/j.issn.0253-2417.2015.05.024

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生物质催化裂解制备芳烃化合物的研究进展

郑云武1,2, 杨晓琴1, 王霏1, 刘灿1, 郑志锋1, 顾继友2   

  1. 1. 云南省高校生物质化学炼制与合成重点实验室;西南林业大学 材料工程学院, 云南 昆明 650224;
    2. 东北林业大学 材料科学与工程学院, 黑龙江 哈尔滨 150040
  • 收稿日期:2015-03-30 出版日期:2015-10-25 发布日期:2015-10-24
  • 通讯作者: 郑志锋,教授,博士生导师,主要从事生物质能源以及生物质材料的研究;E-mail:zhengzhifeng666@163.com E-mail:zhengzhifeng666@163.com
  • 作者简介:郑云武(1983—), 男, 黑龙江大庆人, 讲师, 博士生, 主要从事生物质能源与生物基材料的研究
  • 基金资助:
    国家林业局948技术引进项目(2013-4-08);云南省教育厅重大项目(ZD2014012)

Research Progress of Aromatics Production from Catalytic Pyrolysis of Biomass

ZHENG Yun-wu1,2, YANG Xiao-qing1, WANG Fei1, LIU Can1, ZHENG Zhi-feng1, GU Ji-you2   

  1. 1. University Key Laboratory of Biomass Chemical Refinery & Synthesis, Yunnan Province; College of Materials Engineering, Southwest Forestry University, Kunming 650224, China;
    2. College of Materials Science and Engineering, Northeast Forestry University, Harbin 150040, China
  • Received:2015-03-30 Online:2015-10-25 Published:2015-10-24

摘要: 鉴于芳烃化合物重要的应用价值以及广阔的市场前景,详细阐述了生物质为原料催化转化制备高附加值芳烃化合物的研究进展,系统概述了生物质原料的种类、模型化合物的种类、沸石分子筛催化剂、介孔分子筛催化剂、催化剂的浸渍改性以及工艺条件等对生物质催化转化制备芳烃化合物的影响,进而探讨了催化热解机理,为生物质的全组分、高资源化利用提供新的方向。

关键词: 选择性催化裂解, 沸石微孔分子筛, 介孔分子筛, 浸渍改性, 芳烃化合物

Abstract: Due to the important application value and broad market prospect of aromatic hydrocarbons, the research progress on the production of aromatics from catalytic conversion of biomass was reviewed. The effects of feedstock, model compound, zeolite microporous molecular sieve catalyst, mesoporous molecular sieve catalyst and impregnation modification of catalyst as well as reaction condition on reaction selectivity and yield for the formation of aromatics hydrocarbons were summarized in detail. The reaction mechanism were further discussed. This review might provide a new direction for the total components and high value utilization of biomass.

Key words: selective catalytic pyrolysis, zeolite microporous molecular sieve, mesoporous molecular sieve, impregnation modification, aromatic hydrocarbons

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