林产化学与工业 ›› 2021, Vol. 41 ›› Issue (2): 130-140.doi: 10.3969/j.issn.0253-2417.2021.02.017
• 综述评论 • 上一篇
童乐1, 张乐1, 潘晖1,2, 祝慧敏1, 冯君锋1,2,*()
收稿日期:
2020-07-15
出版日期:
2021-04-28
发布日期:
2021-05-08
通讯作者:
冯君锋
E-mail:2018149@njfu.edu.cn
作者简介:
冯君锋, 副教授, 硕士生导师, 研究方向为木质素定向转化; E-mail: 2018149@njfu.edu.cn基金资助:
Le TONG1, Le ZHANG1, Hui PAN1,2, Huimin ZHU1, Junfeng FENG1,2,*()
Received:
2020-07-15
Online:
2021-04-28
Published:
2021-05-08
Contact:
Junfeng FENG
E-mail:2018149@njfu.edu.cn
摘要:
催化加氢脱氧(HDO)是将生物油中酚类化合物提质精炼为烷烃等液体燃料至关重要的方法,催化剂在其中起至关重要的作用。研究生物油模型化合物酚类的加氢脱氧催化过程,对于生物油提质精炼具有重要的借鉴意义。酚类化合物加氢脱氧催化剂主要包括贵金属催化剂、非贵金属催化剂和双金属催化剂等。文章总结了各类催化剂的优缺点,简述了各类催化剂在生物油模型化合物酚类加氢脱氧过程中的作用机理,并在底物转化率、产物选择性、催化剂稳定性等方面对催化剂进行了评估。
中图分类号:
童乐, 张乐, 潘晖, 祝慧敏, 冯君锋. 生物油模型化合物加氢脱氧催化剂的研究进展[J]. 林产化学与工业, 2021, 41(2): 130-140.
Le TONG, Le ZHANG, Hui PAN, Huimin ZHU, Junfeng FENG. Research Progress of Hydrodeoxygenation Catalysts for Bio-oil Model Compounds[J]. Chemistry and Industry of Forest Products, 2021, 41(2): 130-140.
表1
生物油模型化合物HDO反应典型的催化剂及其性能"
催化剂种类catalyst type | 反应物reactant | 催化剂catalyst | 温度/℃temp. | 压力/MPapressure | 转化率/%conversion | 主要产物(选择性)products(selectivity) | 参考文献reference |
贵金属负载型supported precious metal | 愈创木酚guaiacol | Ru/TiO2 | 260 | 1 | 100 | 环己烷(91.3%)cyclohexane | [ |
愈创木酚guaiacol | Ru/TiO2-ZrO2 | 220 | 3 | 94 | 环己醇(40%)cyclohexanol | [ | |
甲酚cresol | Ru/Nb2O5 | 250 | 0.5 | 56.8 | C7-C9芳烃(88%)C7-C9 aromatics | [ | |
非贵金属负载型supported non-precious metals | 苯酚phenol | Ni/γ-Al2O3 | 300 | 5 | 99 | 环己烷(90%)cyclohexane | [ |
愈创木酚guaiacol | Ni/SZ-3 | 300 | 5 | 100 | 烃类(100%)hydrocarbons | [ | |
苯酚phenol | Mo2C/TiO2 | 350 | 2.5 | 100 | 苯(90%)benzene | [ | |
两种非贵金属non-precious/non-precious metal | 愈创木酚guaiacol | Ni5Cu/SZ-3 | 300 | 5 | 100 | 环己烷(80.8%)cyclohexane | [ |
愈创木酚guaiacol | CoMoS | 300 | 4 | 100 | 苯和甲苯(98%)benzene and toluene | [ | |
愈创木酚guaiacol | NiCo/γ-Al2O3 | 200 | 5 | 96 | 环己醇(70%)cyclohexanol | [ | |
两种贵金属precious/precious metal | 4-丙基苯酚4-propylphenol | Pt-Ru/HZSM-5 | 110 | 0.1 | 100 | 丙基环己烷(100%)propyl cyclohexane | [ |
4-丙基苯酚4-propylphenol | Pt-Re/ZrO2 | 300 | 2 | 67 | 4-丙基苯(80%)4-propylbenzene | [ | |
贵金属+非贵金属precious/non-precious metal | 愈创木酚guaiacol | Pt-Mo/TiO2 | 285 | 4 | 94 | 环己烷(57.7%)cyclohexane | [ |
4-丙基苯酚4-propylphenol | Re-Ni/ZrO2 | 300 | 4 | 90 | 正丙基苯(54%)n-propylbenzene | [ | |
复合催化剂composite catalyst | 愈创木酚guaiacol | Pt/C+HZSM-5 | 250 | 4 | 90 | 环己烷(45.28%)cyclohexane | [ |
4-丙基苯酚4-propylphenol | Raney Ni+ Nafion/SiO2 | 110 | 0.1 | 100 | 丙基环己烷(100%)propyl cyclohexane | [ | |
苯酚phenol | Pd/C+La-BEA | 200 | 6 | 100 | 环己烷(98%)cyclohexane | [ | |
其他催化剂others | 苯酚phenol | PdCu/ZrO2 | 300 | 0.1 | 13.54 | 环己酮(74.91%)cyclohexanone | [ |
苯酚phenol | Ni-Fe/MCSs | 250 | 5 | 100 | 环己烷(93.8%)cyclohexane | [ |
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