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林产化学与工业 ›› 2021, Vol. 41 ›› Issue (2): 130-140.doi: 10.3969/j.issn.0253-2417.2021.02.017

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生物油模型化合物加氢脱氧催化剂的研究进展

童乐1, 张乐1, 潘晖1,2, 祝慧敏1, 冯君锋1,2,*()   

  1. 1. 南京林业大学, 化学工程学院, 江苏 南京 210037
    2. 南京林业大学, 江苏省林业资源高效加工利用协同创新中心; 江苏省高校农林生物质化学与利用国家重点实验室培育建设点, 江苏 南京 210037
  • 收稿日期:2020-07-15 出版日期:2021-04-28 发布日期:2021-05-08
  • 通讯作者: 冯君锋 E-mail:2018149@njfu.edu.cn
  • 作者简介:冯君锋, 副教授, 硕士生导师, 研究方向为木质素定向转化; E-mail: 2018149@njfu.edu.cn
    童乐(1997-), 男, 安徽滁州人, 硕士生, 主要从事生物质催化转化研究工作
  • 基金资助:
    江苏省生物质能源与材料重点实验室开放基金(JSBEM201903)

Research Progress of Hydrodeoxygenation Catalysts for Bio-oil Model Compounds

Le TONG1, Le ZHANG1, Hui PAN1,2, Huimin ZHU1, Junfeng FENG1,2,*()   

  1. 1. College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
    2. Jiangsu Co-Innovation Centre of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University; Jiangsu Provincial Key Lab. for the Chemistry and Utilization of Agro-Forest Biomass, Nanjing 210037, China
  • Received:2020-07-15 Online:2021-04-28 Published:2021-05-08
  • Contact: Junfeng FENG E-mail:2018149@njfu.edu.cn

摘要:

催化加氢脱氧(HDO)是将生物油中酚类化合物提质精炼为烷烃等液体燃料至关重要的方法,催化剂在其中起至关重要的作用。研究生物油模型化合物酚类的加氢脱氧催化过程,对于生物油提质精炼具有重要的借鉴意义。酚类化合物加氢脱氧催化剂主要包括贵金属催化剂、非贵金属催化剂和双金属催化剂等。文章总结了各类催化剂的优缺点,简述了各类催化剂在生物油模型化合物酚类加氢脱氧过程中的作用机理,并在底物转化率、产物选择性、催化剂稳定性等方面对催化剂进行了评估。

关键词: 生物油, 酚类化合物, 加氢脱氧, 催化剂

Abstract:

Hydrodeoxygenation(HDO) process of phenolic compound is an important process for upgrading and refining bio-oil to high value-added chemicals and high-quality liquid fuel, in which the catalyst plays a vital role. Research on the catalytic process of hydrodeoxygenation of bio-oil model compound phenols has important reference significance for bio-oil upgrading and refining. Phenolic compound hydrodeoxygenation catalysts mainly include precious metal catalysts, non-precious metal catalysts and bimetallic catalysts. This paper summarized the advantages and disadvantages of various catalysts, and briefly described the mechanism of various catalysts in the process of phenol hydrodeoxygenation. And the catalyst was evaluated for substrate conversion, product selectivity, and catalyst stability.

Key words: bio-oil, phenolic compounds, hydrodeoxygenation, catalyst

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