甘蔗渣基磷掺杂活性炭电极对Cu2+电吸附性能研究

doi:10.3969/j.issn.0253-2417.2022.03.006

摘要/Abstract

摘要：

以甘蔗渣为碳源、植酸为磷源和活化剂，制备了甘蔗渣基磷掺杂活性炭(PAC-900)，并将其作为电极用于铜离子的电吸附。采用氮气吸附-脱附等温线、XPS和SEM-EDX等对样品的孔隙结构、表面化学性质及元素组成进行表征；通过循环伏安(CV)、恒流充放电(GCD)实验对磷掺杂活性炭的电化学性能进行测试。研究结果表明：当Cu²⁺初始质量浓度为100 mg/L时，PAC-900对Cu²⁺的电吸附量高达86.85 mg/g，远高于未掺杂活性炭(C-900)的35.15 mg/g，循环吸附-脱附10次后吸附量仍可达45.38 mg/g。植酸活化可以使制得的磷掺杂活性炭比表面积高达1 671.75 m²/g，总孔容积和微孔容积分别达到1.33和0.09 cm³/g，其电化学性能和亲水性显著提高。磷掺杂活性炭对Cu²⁺的吸附过程主要受双电层吸附和法拉第吸附的影响，吸附等温线和吸附动力学分析表明吸附过程符合Freundich等温式和准二级动力学过程，说明吸附过程不仅存在单层吸附，也存在多层吸附；XPS和SEM-EDX分析表明P元素主要以C—P—O、C—O—P和C—P=O的形式存在，C—P极少，其中C—P＝O对Cu²⁺的法拉第吸附贡献最大。

关键词: 甘蔗渣, 磷掺杂, 活性炭, 电吸附, 铜离子

Abstract:

Bagasse-based phosphorus-doped activated carbon(PAC-900) was prepared with bagasse as carbon source, phytic acid as phosphorus source and activator, and used as electrode for the electrosorption of Cu²⁺. The pore structure, surface chemical properties and elemental composition of the samples were characterized by nitrogen adsorption-desorption isotherm, XPS and SEM-EDX. The research results showed that when the initial concentration of Cu²⁺ was 100 mg/L, the electrosorption of Cu²⁺ by PAC-900 was as high as 86.85 mg/g, which was much higher than 35.15 mg/g of undoped activated carbon(C-900). After 10 times of desorption, the adsorption capacity could still reach 45.38 mg/g. The activation of phytic acid could produce the activated carbon with the specific surface area as high as 1 671.75 m²/g, and the total pore volume and micropore volume of 1.33 cm³/g and 0.09 cm³/g, respectively, which could significantly improve its electrochemical performance and hydrophilicity. The adsorption process was mainly affected by the electric double layers adsorption and Faraday adsorption. The adsorption isotherm and adsorption kinetic process analysis showed that the adsorption process conformed to the Freundich isotherm and pseudo-second-order kinetic process, it indicated that there was not only single-layer adsorption but also multi-layer adsorption in the adsorption process; XPS and SEM-EDX analysis results showed that the P element mainly existed in the form of C—P—O, C—O—P and C—P＝O, and C—P was very rare, among which C—P=O contributed the most to the Faradaic adsorption of Cu²⁺.

Key words: bagasse, phosphorus-doped, activated carbon, electrosorption, copper ions

中图分类号:

TQ35

熊永志, 刘艳艳, 王贵龙, 卢贝丽, 黄彪, 林冠烽. 甘蔗渣基磷掺杂活性炭电极对Cu²⁺电吸附性能研究[J]. 林产化学与工业, 2022, 42(3): 41-48.

Yongzhi XIONG, Yanyan LIU, Guilong WANG, Beili LU, Biao HUANG, Guanfeng LIN. Electrosorption of Copper Ions on Bagasse-based Phosphorus-doped Activated Carbon Electrode[J]. Chemistry and Industry of Forest Products, 2022, 42(3): 41-48.

图/表 8

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参考文献 28

1	KAPOOR A , VIRARAGHAVAN T . Fungal biosorption—An alternative treatment option for heavy metal bearing wastewaters: A review[J]. Bioresource Technology, 1995, 53 (3): 195- 206.
2	CHIRWA E M N , WANG Y T . Hexavalent chromium reduction by Bacillus sp.in a packed-bed bioreactor[J]. Environmental Science & Technology, 1997, 31 (5): 1446- 1451.
3	唐受印, 戴友芝, 汪大翚. 废水处理工程[M]. 北京: 化学工业出版社, 1998: 207- 225.
	TANG S Y , DAI Y Z , WANG D H . Wastewater Treatment Engineering[M]. Beijing: Chemical Industry Press, 1998: 207- 225.
4	唐兆民, 张景书. 电镀废水的处理现状与发展趋势[J]. 国土与自然资源研究, 2004, (2): 69- 71.
	TANG Z M , ZHANG J S . Treatment actuality and development trend of waste water in electroplating industry[J]. Territory & Natural Resources Study, 2004, 2, 69- 71.
5	惠秀娟. 环境毒理学[M]. 北京: 化学工业出版社, 2003: 800.
	HUI X J . Environmental Toxicology[M]. Beijing: Chemical Industry Press, 2003: 800.
6	CHEN R , SHEEHAN T , JING L N , et al. Capacitive deionization and electrosorption for heavy metal removal[J]. Environmental Science: Water Research & Technology, 2020, 6, 258- 282.
7	GANG W , QIAN B Q , QIANG D , et al. Highly mesoporous activated carbon electrode for capacitive deionization[J]. Separation & Purification Technology, 2013, 103, 216- 221.
8	ZOU L D , MORRIS G , QI D D . Using activated carbon electrode in electrosorptive deionisation of brackish water[J]. Desalination, 2008, 225 (1/2/3): 329- 340.
9	RYOO M W , SEO G . Improvement in capacitive deionization function of activated carbon cloth by titania modification[J]. Water Research, 2003, 37 (7): 1527- 1534. doi: 10.1016/S0043-1354(02)00531-6
10	WANG H , ZHANG D S , YAN T T , et al. Three-dimensional macroporous graphene architectures as high performance electrodes for capacitive deionization[J]. Journal of Materials Chemistry A, 2013, 1 (38): 11778- 11789. doi: 10.1039/c3ta11926b
11	XU X T, PAN L K, LIU Y, et al. Facile synthesis of novel graphene sponge for high performance capacitive deionization[J/OL]. Scientific Reports, 2015, 5(1): 1-9[2021-07-20]. https://doi.org/10.1038/srep08458.
12	DONG Q , WANG G , WU T T , et al. Enhancing capacitive deionization performance of electrospun activated carbon nanofibers by coupling with carbon nanotubes[J]. Journal of Colloid and Interface Science, 2015, 446, 373- 378. doi: 10.1016/j.jcis.2014.12.065
13	TSAI Y C , DOONG R A . Activation of hierarchically ordered mesoporous carbons for enhanced capacitive deionization application[J]. Synthetic Metals, 2015, 205, 48- 57. doi: 10.1016/j.synthmet.2015.03.026
14	TIAN S C, WU J, ZHANG X H, et al. Capacitive deionization with nitrogen-doped highly ordered mesoporous carbon electrodes[J/OL]. Chemical Engineering Journal, 2020, 380: 1-12[2021-07-20]. https://doi.org/10.1016/j.cej.2019.122514.
15	PEI X , DREWES J E , HEIL D , et al. Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology[J]. Water Research, 2008, 42 (10/11): 2605- 2617.
16	WANG G , DONG Q , LING Z , et al. Hierarchical activated carbon nanofiber webs with tuned structure fabricated by electrospinning for capacitive deionization[J]. Journal of Materials Chemistry, 2012, 22 (41): 21819- 21823. doi: 10.1039/c2jm34890j
17	HAN B , CHENG G , WANG Y K , et al. Structure and functionality design of novel carbon and faradaic electrode materials for high-performance capacitive deionization[J]. Chemical Engineering Journal, 2019, 360, 364- 384. doi: 10.1016/j.cej.2018.11.236
18	PUZIY A M , PODDUBNAYA O I , GAWDZIK B , et al. Phosphorus-containing carbons: Preparation, properties and utilization[J]. Carbon, 2020, 157, 796- 846. doi: 10.1016/j.carbon.2019.10.018
19	LIU Y C , HUANG B B , LIN X X , et al. Biomass-derived hierarchical porous carbons: Boosting the energy density of supercapacitors via an ionothermal approach[J]. Journal of Materials Chemistry A, 2017, 5 (25): 13009- 13018. doi: 10.1039/C7TA03639F
20	QIAN Y, JIANG S, LI Y, et al. In situ revealing the electroactivity of P—O and P—C bonds in hard carbon for high-capacity and long-life Li/K-ion batteries[J/OL]. Advanced Energy Materials, 2019, 9(34): 1-10[2021-07-20]. https://doi.org/10.1002/aenm.201901676.
21	HU X W , FAN M Y , ZHU Y Y , et al. Biomass-derived phosphorus-doped carbon materials as efficient metal-free catalysts for selective aerobic oxidation of alcohols[J]. Green Chemistry, 2019, 21, 5274- 5283. doi: 10.1039/C9GC01910C
22	JIANG Z L , SUN H , SHI W K , et al. P-doped hive-like carbon derived from pinecone biomass as efficient catalyst for Li-O₂ battery[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (16): 14161- 14169.
23	MOSSAD M , ZOU L . A study of the capacitive deionisation performance under various operational conditions[J]. Journal of Hazardous Materials, 2012, 213/214, 491- 497. doi: 10.1016/j.jhazmat.2012.02.036
24	CAO Z L, ZHANG C, YANG Z X, et al. Preparation of carbon aerogel electrode for electrosorption of copper ions in aqueous solution[J/OL]. Materials, 2019, 12(11): 1-9[2021-07-20]. https://doi.org/10.3390/ma12111864.
25	ZHU Y D, HUANG Y, CHEN C, et al. Phosphorus-doped porous biomass carbon with ultra-stable performance in sodium storage and lithium storage[J/OL]. Electrochimica Acta, 2019, 321: 1-10[2021-07-20]. https://doi.org/10.1016/j.electacta.2019.134698.
26	YANG K L , YING T Y , YIACOUMI S , et al. Electrosorption of ions from aqueous solutions by carbon aerogel: An electrical double-layer model[J]. Langmuir, 2001, 17 (6): 1961- 1969. doi: 10.1021/la001527s
27	杨旋, 郑新宇, 吕建华, 等. 碱/尿素溶解体系制备氮掺杂活性炭及其电化学性能研究[J]. 林产化学与工业, 2021, 41 (2): 10- 16.
	YANG X , ZHENG X Y , LÜ J H , et al. Preparation of nitrogen-doped activated carbon from alkali/urea dissolution system and its electrochemical properties[J]. Chemistry and Industry of Forest Products, 2021, 41 (2): 10- 16.
28	SEVILLA M , FUERTES A B . Direct synthesis of highly porous interconnected carbon nanosheets and their application as high-performance supercapacitors[J]. ACS Nano, 2014, 8 (5): 5069- 5078. doi: 10.1021/nn501124h

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甘蔗渣基磷掺杂活性炭电极对Cu²⁺电吸附性能研究

Electrosorption of Copper Ions on Bagasse-based Phosphorus-doped Activated Carbon Electrode

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