乙酰丙酸酯催化合成研究进展

doi:10.3969/j.issn.0253-2417.2022.03.018

摘要/Abstract

摘要：

近年来，乙酰丙酸作为一种重要的生物基平台化合物吸引了广泛的关注，可合成多种具有高附加值的化学品，用于替代燃料、食用香料、塑化剂等领域，尤其是作为替代燃料为可持续发展提供了可行的参考方案。本文综述了近期生物质转化领域涉及乙酰丙酸酯催化合成的研究进展，介绍了乙酰丙酸酯化、糠醇醇解、单糖转化以及纤维素原料转化等方法催化合成乙酰丙酸酯的反应性能与机理，并对乙酰丙酸酯的合成进行了总结与展望。

关键词: 乙酰丙酸酯, 酯化, 糠醇, 单糖, 纤维素

Abstract:

In recent years, levulinic acid has been considered as a key biobased platform compound and attracted wide attention, which can be utilized in the synthesis of many high value-added chemicals. Among them, levulinates, as a class of important chemical products, can be used in alternative fuels, edible spices, plasticizers and other fields, especially as alternative fuels, which provides a feasible reference scheme for sustainable development. In this paper, the recent research progress on the catalytic synthesis of levulinates in the field of biomass conversion was reviewed. The reaction performances and related mechanisms were introduced involving in several approaches, such as the esterification of levulinic acid, the alcoholysis of furfuryl alcohol, the conversion of monosaccharides and cellulosic materials, respectively. The synthesis of levulinates was summarized and prospected.

Key words: levulinate ester, esterification, furfuryl alcohol, monosaccharide, cellulose

中图分类号:

TQ35

李磊, 王敏超, 马娇, 许占威, 张雅静, 贾松岩. 乙酰丙酸酯催化合成研究进展[J]. 林产化学与工业, 2022, 42(3): 135-146.

Lei LI, Minchao WANG, Jiao MA, Zhanwei XU, Yajing ZHANG, Songyan JIA. Recent Progresses on the Catalytic Synthesis of Levulinate Esters[J]. Chemistry and Industry of Forest Products, 2022, 42(3): 135-146.

图/表 7

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原料 feedstock	催化剂 catalyst	反应条件 reaction conditions	产物(收率)¹⁾ product(yield)	文献 reference
小麦秸秆wheat straw	[HSO₃-BMIM]HSO₄	200 ℃，1 h	EL(16.23%)	[69]
小麦秸秆wheat straw	H₂SO₄	190 ℃，1 h	EL(18.11%)	[70]
浮萍duckweed	[C₃H₆SO₃HPy]HSO₄	2 MPa N₂，170 ℃，5 h	ML(73.7%)，EL(59.8%)，PL(51.8%)，BL(56.9%)	[71]
浮萍duckweed	H₂SO₄	200 ℃，3 h	EL(55.2%)	[72]

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