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›› 2013, Vol. 33 ›› Issue (4): 101-107.doi: 10.3969/j.issn.0253-2417.2013.04.019

• 1研究报告 • Previous Articles     Next Articles

Dynamic Analysis of Adsorption Behaviour of n-Butane in Granular Activated Carbon

GUO Hao, DENG Xian-lun, LIU Xiao-min, WANG Guo-dong, ZHU Guang-zhen   

  1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab.for Biomass Chemical Utilization; Key and Open Lab.of Forest Chemical Engineering, SFA; Key Lab.of Biomass Energy and Material, Jiangsu province, Nanjing 210042, China
  • Received:2012-06-19 Revised:1900-01-01 Online:2013-08-30 Published:2013-08-30

Abstract: In this paper, wood-based granular activated carbon was used to study adsorption kinetics of n-butane. The effects of the adsorption temperature, the n-butane concentration and the n-butane flow rate were investigated. Then the date was fit by first order kinetics model, pseudo-second order kinetic model, Elovich kinetic model and Ben nahum kinetic model. The results showed that with the increasing of temperature, the adsorption amount of n-butane decreased. This indicated that adsorption of n-butane in activated carbon was an exothermic reaction. With the increasing of the n-butane concentration, n-butane adsorption performance also increased, but the adsorption time did not reduce. The flow rate of n-butane significantly influenced adsorption rate and adsorption time, but it had minor influence on the amount of n-butane adsorbed at equilibrium. It is also found that the R2 of Bangham equation is more than 0.99, which is much higher than the other three kinetic equation. Therefore the absorption kinetics is well satisfied with Bangham equation.

Key words: activated carbon, n-butane, adsorption kinetics

CLC Number: