表面活性剂对有机硅包覆松香基环氧树脂微胶囊的影响

doi:10.3969/j.issn.0253-2417.2014.01.005

Abstract

Abstract: A novel microcapsule was prepared from silica encapsulating maleopimaric acid glycidyl ester type epoxy resin (MPTGE) by sol-gel process. In these microcapsules system, MPTGE was used as the core material, and tetraethyl orthosilicate(TEOS) acted as the shell material. Some ionic, nonionic, macromolecular surfactants and a rosin-basd surfactant (MP) which was synthesized from MPTGE and polyoxyalkylene were used as the stabilizer. The effects of different surfactants and concentrations on the particle size and distribution of the encapsulated microcapsules were investigated. The surface morphology, particle size and distribution of microcapsules were characterized by optical microscope, scanning electronic microscope and zeta size analyzer, respectively. Experimental results indicated that the surfactant MP synthesized from MPTGE was favorable to form TEOS encapsulating MPTGE microcapsules. The microcapsules had smooth and compact outer surface when the amount of MP was close to 16.7 %.

Key words: surfactant, microcapsules, silicone, maleopimaric acid, epoxy resin

CLC Number:

TQ35

LIN Guang-yuan, WU Guo-min, KONG Zhen-wu. Effects of Surfactants on Silica Encapsulating Maleopimaric Acid Glycidyl Ester Type Epoxy Resin[J]. Chemistry and Industry of Forest Products, 2014, 34(1): 25-30.

References

[1] PARK J H, YE M, PARK K.Biodegradable polymers for microencapsulation of drugs[J].Molecules, 2005, 10(1):146-161.
[2] GIRAUD S, BOURBIGOT S, ROCHERY M, et al.Microencapsulation of phosphate:Application to flame retarded coated cotton[J].Polymer Degradation and Stability, 2002, 77(2):285-297.
[3] TONA VÁSQUEZ R V, JIMÉNEZ ESTELLER L, BOJARSKI A D.Multiscale modeling approach for production of perfume microcapsules[J].Chemical Engineering and Technology, 2008, 31(8):1216-1222.
[4] WHITE S R, SOTTOS N R, GEUBELLE P H, et al.Autonomic healing of polymer composites[J].Nature, 2001, 409(6822):794-797.
[5] WANG Chun-shan, SHIEH J Y.Phosphorus-containing epoxy resin for an electronic application[J].Journal of Applied Polymer Science, 1999, 73(3):356-361.
[6] 袁彦超, 容敏智, 章明秋.三聚氰胺-甲醛树脂包裹环氧树脂微胶囊的制备及表征[J].高分子学报, 2008(5):472-480.
[7] ZHANG Huan-zhi, WANG Xiao-dong, WU De-zhen.Silica encapsulation of n-octadecane via sol-gel process:A novel microencapsulated phase-change material with enhanced thermal conductivity and performance[J].Journal of Colloid and Interface Science, 2010, 343(1):246-255.
[8] FANG Gui-yin, CHEN Zhi, LI Hui.Synthesis and properties of microencapsulated paraffin composites with SiO₂ shell as thermal energy storage materials[J].Chemical Engineering Journal, 2010, 163(1/2):154-159.
[9] 沈敏敏, 刘治猛, 哈成勇, 等.马来海松酸缩水甘油酯的合成[J].广州化学, 2001, 26(2):21-26.
[10] 孔振武.马来海松酸类环氧树脂的合成及其表征[D].北京:中国林业科学研究院博士学位论文, 1994.
[11] 倪卓, 杜学晓, 邢锋, 等.表面活性剂对自修复环氧树脂微胶囊的影响[J].深圳大学学报:理工版, 2008, 25(4):351-357.
[12] 李岚, 袁莉, 梁国正, 等.表面活性剂对聚脲甲醛包覆双环戊二烯微胶囊的影响[J].精细化工, 2006, 23(5):429-434.
[13] 刘洋, 黄焕, 孔振武, 等.非离子型水性萜烯基环氧树脂乳化剂的合成与特性[J].林产化学与工业, 2009, 29(5):23-29.
[14] 赵立英, 马会茹, 孙志刚, 等.非离子型活性乳化剂及其水性环氧树脂的制备和性能[J].化学学报, 2010, 68(2):174-180.
[15] 施雪珍, 陈铤, 顾国芳.水性环氧树脂乳液的研制[J].功能高分子学报, 2002, 15(3):306-310.

Effects of Surfactants on Silica Encapsulating Maleopimaric Acid Glycidyl Ester Type Epoxy Resin

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