超声波处理对木质素磺酸钠物化性能的影响

doi:10.3969/j.issn.0253-2417.2014.02.012

Abstract

Abstract: Sodium lignosulfonate (LS) was treated directly by ultrasonication. The effects of ultrasonication time, power and pH on the sodium lignosulfonate were studied in present study. The physicochemical properties of sodium lignosulfonate (LS) and sodium lignosulfonate treated with ultrasonication (ULS) were investigated by UV, FT-IR, ¹H NMR and TGA. The application of ultrasonication on sodium lignosulfonate for different time (15, 45, 60 and 120 minutes) resulted in the increment of phenolic hydroxyl to 0.71%, 0.74%, 0.81% and 0.84% from 0.65%, respectively.Ultrasonication was applied to 10 g sodium lignosulfonate that dissolved in 100 mL distilled water. With the ascending powder of ultrasonication from 100 to 300 W, phenolic content of sodium lignosulfonate increased from 0.69% to 0.92%. The pH exhibited the most noticeable effect on the ultrasonication. Phenolic content reached to 1.58% as the pH was 0. FT-IR, UV and ¹H NMR showed that ultrasound might cause partial disruption of aromatic rings and sulfonic acid groups of sodium lignosulfonate. TG analysis illustrated that ultrasonication had a complex influence on thermal ability of sodium lignosulfonate due to the simultaneous degradation and cross linking reactions. When sodium lignosulfonate aqueous solution was treated by ultrasonication (300 W, 20 kHz) for 60 min, degradation had an disadvantageous effect on the thermal stability of ULS between 200-600 ℃. However, when sodium lignosulfonate aqueous solution (pH=0,adjusted by concentrated sulfuric acid) was treated by ultrasonication (150 W, 40 kHz) for 60 min, ULS showed that the better one was over 680 ℃ because of the cross linking reactions.

Key words: ultrasonic treatment, sodium lignosulfonate, physicochemical properties, characterization

CLC Number:

TQ35

ZHOU Bao-wen, HA Cheng-yong, DENG Lian-li, MO Jian-qiang, SUN Chun-ning, SHEN Min-min. Effect of Ultrasonic Treatment on Physicochemical Properties of Sodium Lignosulfonate[J]. Chemistry and Industry of Forest Products, 2014, 34(2): 67-72.

References

[1] 穆有炳, 施娟娟, 王春鹏, 等.木质素在木材胶黏剂中的应用[J].生物质化学工程, 2009, 43(3):42-46.
[2] VOITL T, VON ROHR P R.Demonstration of a process for the conversion of kraft lignin into vanillin and methyl vanillate by acidic oxidation in aqueous methanol[J].Industrial & Engineering Chemistry Research, 2010, 49(7):3501-3503.
[3] CHIWETELU C I, HORNOF V, NEALE G H, et al.Use of mixed surfactants to improve the transient interfacial tension behaviour of heavy oil/alkaline systems[J].The Canadian Journal of Chemical Engineering, 1994, 72(3):534-540.
[4] HAMMA H, KUBO S, YAMADA T, et al.Conversion of technical lignins to amphiphilic derivatives with high surface activity[J].Journal of Wood Chemistry and Technology, 2010, 30(2):164-174.
[5] DOUGLAS G N.Recovering hydrocarbon with surfactants from lignin:US, 4739040[P].1988-04-19.
[6] 邱学青, 欧阳新平, 杨东杰, 等.一种环保型碱木质素改性酚醛树脂胶粘剂及其制备方法:中国, CN101358120A[P].2008-09-18.
[7] WANG Ming-cun, LEITCH M, XU Chun-bao.Synthesis of phenol-formaldehyde resol resins using organosolv pine lignins[J].European Polymer Journal, 2009, 45(12):3380-3388.
[8] HU Li-hong, ZHOU Yong-hong, LIU Rui-jie, et al.Synthesis of foaming resol resin modified with oxidatively degraded lignosulfonate[J].Industrial Crops and Products, 2013, 44:364-366.
[9] ALSON M V, RODGUEZ J J, OLIET M, et al.Characterization and structural modification of ammonic lignosulfonate by methylolation[J].Journal of Applied Polymer Science, 2001, 82(11):2661-2668.
[10] ASAKURA Y, NISHIDA T, MATSUOKA T, et al.Effects of ultrasonic frequency and liquid height on sonochemical efficiency of large-scale sonochemical reactors[J].Ultrasonics Sonochemistry, 2008, 15(3):244-250.
[11] SHIRSATH S R, SONAWANE S H, GOGATE P R.Intensification of extraction of natural products using ultrasonic irradiations:A review of current status[J].Chemical Engineering and Processing:Process Intensification, 2012, 53:10-23.
[12] MASON T J, LORIMER J P.Sonochemistry:Theory, Applications and Uses of Ultrasound in Chemistry[M].Chichester:Ellis Horwood, 1988.
[13] MASON T J, PANJWNYK L, LORIMER J P.The uses of ultrasound in food technology[J].Ultrasonics Sonochemistry, 1996, 3(3):S253-S260.
[14] SUN Run-cang, SUN X F, XU X P.Effect of ultrasound on the physicochemical properties of organosolv lignins from wheat straw[J].Journal of Applied Polymer Science, 2002, 84(13):2512-2522.
[15] GARCÍA A, ALRIOLS M G, LABIDI J.Evaluation of the effect of ultrasound on organosolv black liquor from olive tree pruning residues[J].Bioresource Technology, 2012, 108:155-161.
[16] GARCÍA A, ALRIOLS M G, LLANO-PONTE R, et al.Ultrasound-assisted fractionation of the lignocellulosic material[J].Bioresource Technology, 2011, 102(10):6326-6330.
[17] LI Ming-fei, SUN Shao-ni, XU Feng, et al.Ultrasound-enhanced extraction of lignin from bamboo (Neosinocalamus affinis):Characterization of the ethanol-soluble fractions[J].Ultrasonics Sonochemistry, 2012, 19(2):243-249.
[18] YUNUS R, SALLEH S F, ABDULLAH N, et al.Effect of ultrasonic pre-treatment on low temperature acid hydrolysis of oil palm empty fruit bunch[J].Bioresource Technology, 2010, 101(24):9792-9796.
[19] SUTKAR V S, GOGATE P R.Design aspects of sonochemical reactors:Techniques for understanding cavitational activity distribution and effect of operating parameters[J].Chemical Engineering Journal, 2009, 155(1/2):26-36.
[20] WEXLER A S.Characterization of lignosulfonates by ultraviolet spectrometry:Direct and difference spectrograms[J].Analytical Chemistry, 1964, 36(1):213-221.
[21] SECA A M L, CAVALEIRO J A S, DOMINGUES F M J, et al.Structural characterization of the lignin from the nodes and internodes of Arundo donax reed[J].Journal of Agricultural and Food Chemistry, 2000, 48(3):817-842.
[22] LUTNAES B F, MYRVOLD B O, LAUTEN R A, et al.¹H and ¹³C NMR data of benzylsulfonic acids-model compounds for lignosulfonate[J].Magnetic Resonance in Chemistry, 2008, 46(3):299-305.

Effect of Ultrasonic Treatment on Physicochemical Properties of Sodium Lignosulfonate

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LIU Yijun, YUAN Yuan, LIU Yangyang, ZHANG Fan, LI Jihua. Effects of Different Drying Methods on Physicochemical Properties and Essential Oil Quality of Melaleuca alternifolia Cheel [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 77-82.
[2]	SHI Shuang, HU Fang, MIAO Zechao, CAI Hetian, LI Dezhao. Recent Advances in Ultrasonic Treatment of Waste Paper Fibers [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 17-24.
[3]	LU Yanju, ZHAO Zhendong, WANG Jing, XU Shichao, BI Liangwu, CHEN Yuxiang. Synthesis and Biological Activity of Isopimaric Furfural Acylhydrazone Derivatives [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 43-48.
[4]	ZHOU Fanglang, ZHENG Zhifeng, YANG Jing, YANG Haiyan, DENG Jia, SHI Zhengjun. Preparation and Characterization of Lignin Based Phenolic Foam [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 103-109.
[5]	HUANG Jing, BAO Han, ZHANG Xia, MO Yue, LUO Jinyue, LIU Zuguang. Synthesis and Characterization of 3'-(3,3-Dimethylbicyclo[2.2.1] hept-2-ylidene)-5'-phenyl-isoxazoline [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 110-116.
[6]	SHI Chun, LI Tiancheng, YANG Jing, YANG Haiyan, DENG Jia, SHI Zhengjun. Preparation and Characterization of Cellulose Acetate Films Derived from Bamboo [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 70-76.
[7]	LIU Dandan, HAN Weifan, JIANG Jianxin, ZHU Liwei. Technology of Microwave-assisted Extraction of Sapindus Peel Polysaccharide and Its Antioxidant Activity [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 109-116.
[8]	WANG Xuan, LIU Zhu, ZHANG Yaoli, PAN Biao. Characterization Methods of Wood Ultrastructure and Its Research Progress [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 1-10.
[9]	LI Qiaoguang, LIU He, LI Jianfang, SHANG Shibin, SONG Zhanqian. Synthesis of Rosin Based Crosslinking Agent and Its Effect on Properties of Cured Silicone Rubber [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 87-93.
[10]	LU Chuanwei, LIU Shaofeng, WANG Chunpeng, CHU Fuxiang, WANG Jifu. Synthesis and Characterization of Thermoplastic Materials Derived from Cellulose, Furfural and Grease [J]. Chemistry and Industry of Forest Products, 2017, 37(6): 43-48.
[11]	WANG Peng, QIN Ying, FU Yingjuan, WANG Zhaojiang, ZHANG Fengshan. Structural Character of Dissolved and Colloidal Lignin in Hydrolysate from Poplar Woodchips Autohydrolysis [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 59-66.
[12]	LIU Shaofeng, LU Chuanwei, WANG Chunpeng, CHU Fuxiang, WANG Jifu. Synthesis and Characterization of 2-Methacryloyloxyisopro-panol Ester of Dehydroabietic Acid [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 89-94.
[13]	BO Caiying, HU Lihong, YANG Xiaohui, ZHENG Minrui, ZHANG Meng, ZHOU Yonghong. Preparation and Characterization of Phenolic Foams Modified by Lignin-based Polyurethane Prepolymers [J]. Chemistry and Industry of Forest Products, 2017, 37(1): 63-72.
[14]	DING Shasha, HUANG Lixin, ZHANG Caihong, XIE Pujun, ZHANG Qiong, DENG Yejun. Optimization of Extraction Technology of Dietary Fiber from Olive Pomace and Its Physicochemical Characteristics [J]. Chemistry and Industry of Forest Products, 2017, 37(1): 116-122.
[15]	MA Yu-feng, WANG Chun-peng, CHU Fu-xiang. Effect of Molybdenum Trioxide on Flame Retardant Properties of Phenolic Foams Halogen-free System [J]. Chemistry and Industry of Forest Products, 2016, 36(3): 73-80.