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Chemistry and Industry of Forest Products ›› 2015, Vol. 35 ›› Issue (3): 73-79.doi: 10.3969/j.issn.0253-2417.2015.03.013

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Variations Relationship of Abietic-type Acids under Acid Treatment

GU Yan1, CHEN Yu-xiang1,2, ZHAO Zhen-dong1, LI Dong-mei1, BI Liang-wu1, WANG Jing1   

  1. 1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab.for Biomass Chemical Utilization; Key and Open Lab.of Forest Chemical Engineering, SFA; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
    2. Jiangsu Qianglin Bioenergy Co., Ltd., Liyang 213364, China
  • Received:2014-08-26 Online:2015-06-25 Published:2015-07-03

Abstract: Slash pine (P.elliottii) rosin and masson pine (P.massoniana) rosin were treated using different type of acids at different time.The variation relationships of abietic-type acids were analyzed through the content changes of abietic-type acids and dehydroabietic acid.The results showed that isomerization took place among palustric acid,abietic acid and neoabietic acid,and at the same time dehydrogenation and decarboxylation occurred under acid treatment.The rates of isomerization,dehydrogenation and decarboxylation were affected by the type of acid,acid strength and treating time.With the increase of acid strength,the speed of isomerization,dehydrogenation and decarboxylation increased.

Key words: rosin, abietic-type acids, isomerization, dehydrogenation

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