乌桕油皂微波催化快速裂解制备可再生燃油研究

doi:10.3969/j.issn.0253-2417.2015.05.009

Abstract

Abstract: Preparation of renewable fuel was studied with saponificated China tallow seed oil and stillingia oil as raw materials using microwave pyrolysis. The effects of reaction power and temperature on the yield of pyrolysis products were investigated. The optimum conditions were obtained as pyrolysis power 700 W, pyrolysis temperature 450 ℃. The corresponding liquid yields were 75.26% and 77.01% for microwave pyrolysis oil from saponificated China tallow seed oil and stillingia oil, respectively. The GC-MS analysis indicated that the main components of the product were C8-C18 alkanes, alkenes, ring-containing alkanes and aromatic hydrocarbon. Pyrolysis oil properties were also determined. The results indicated that the pyrolysis oil from saponificated China tallow seed oil had higher heat value, lower density and viscosity with the comparation of pyrolysis oil from saponificated China tallow stillingia oil, which was similar to 0^# diesel. Freezing point and cold filter plugging point of the pyrolytic products have good low temperature fluidity, which are better than those of the biodiesel.

Key words: China tallow seed oil, China tallow stillingia oil, microwave pyrolysis, renewable fuel

CLC Number:

TQ35
S216.2

WANG Yun-pu, CHENG Fang-yuan, LIU Yu-huan, RUAN Rong-sheng, LIU Ying-yu, MA Wen, YANG Qian, HUANG Yi-ning. Preparation of Renewable Fuel from Saponificated China Tallow Oil by Fast Pyrolysis Reaction Assisted with Microwave[J]. Chemistry and Industry of Forest Products, 2015, 35(5): 53-57.

References

[1] 徐俊明,肖国民,周永红,等.油脂热化学转化制备可再生液体燃料油研究进展[J].化工进展,2011,30(7):1456-1460. XU Jun-ming,XIAO Guo-min,ZHOU Yong-hong,et al.Renewable biofuel production from thermal-chemical conversion of triglyceride[J].Chemical Industry and Engineering Progress,2011,30(7):1456-1460.
[2] 陈洁,蒋剑春,聂小安,等.催化裂解与催化酯化工艺耦合制备桐油基类石化柴油燃料[J].林产化学与工业,2012,32(2):25-29. CHEN Jie,JIANG Jian-chun,NIE Xiao-an,et al.Diesel-like fuel obtained from tung oil using pyrolysis and esterification coupling[J].Chemistry and Industry of Forest Products,2012,32(2):25-29.
[3] WANG Wei-cheng,THAPALIYA N,CAMPOS A,et al.Hydrocarbon fuels from vegetable oils via hydrolysis and thermo-catalytic decarboxylation[J].Fuel,2012,95(5):622-629.
[4] ALMEIDA T M,BISPO M D,CARDOSO A R T,et al.Preliminary studies of bio-oil from fast pyrolysis of coconut fibers[J].Journal of Agricultural and Food Chemistry,2013,61(28):6812-6821.
[5] ABNISA F,ARAMI-NIYA A,DAUD W M A W,et al.Characterization of bio-oil and bio-char from pyrolysis of palm oil wastes[J].Bioenergy Research,2013,6(2):830-840.
[6] GAO Yin-yu,CHEN Wen-wei,LEI Han-wu,et al.Optimization of transesterification conditions for the production of fatty acid methyl ester (FAME) from Chinese tallow kernel oil with surfactant-coated lipase[J].Biomass and Bioenergy,2009,33(2):277-282.
[7] EGLOFF G,MORRELL J C,THOMAS C L,et al.The catalytic cracking of aliphatic hdrocarbons[J].Journal of American Chemical Society,1939,61(12):3571-3580.
[8] EGLOFF G,NELSON E F.Cracking alaskan fur-seal oil[J].Industrial and Engineering Chemistry,1933,25(4):386-387.
[9] CHANG Chia-chu,WAN Shen-wu.China's motor fuels from tung oil[J].Industrial and Engineering Chemistry,1947,39 (12):1543-1548.
[10] FORTES I C P,BAUGH P J.Study of calcium soap pyrolysates derived from Macauba fruit (Acrocomia sclerocarpa M.).Derivatization and analysis by GC/MS and CI-MS[J].Journal of Analytical and Applied Pyrolysis,1994,29(2):153-167.
[11] WIGGERS V R,WISNIEWSKI A,MADUREIRA L A S,et al.Biofuels from waste fish oil pyrolysis:Continuous production in a pilot plant[J].Fuel,2009,88(11):2135-2141.
[12] MORGAN T,SANTILLAN-JIMENEZ E,HARMAN-WARE A E,et al.Catalytic deoxygenation of triglycerides to hydrocarbons over supportednickel catalysts[J].Chemical Engineering Journal,2012,189/190:346-355.
[13] SANTILLAN-JIMENEZ E,MORGAN T,LACNY J,et al.Catalytic deoxygenation of triglycerides and fatty acids to hydrocarbons over carbon-supported nickel[J].Fuel,2013,103(1):1010-1017.
[14] LAPPI H,ALEN R.Production of vegetable oil-based biofuels:Thermochemical behavior of fatty acid sodium salts during pyrolysis[J].Journal of Analytical and Applied Pyrolysis,2009,86(2):274-280.
[15] LAPPI H,ALEN R.Pyrolysis of vegetable oil soaps:Palm,olive,rapeseed and castor oils[J].Journal of Analytical and Applied Pyrolysis,2011,91(1):154-158.
[16] WANG Yun-pu,LIU Yu-huan,RUAN Rong-sheng,et al.Mechanism of hydrocarbon generation from sodium stearate decarboxylation by microwave assisted pyrolysis[J].Acta Chimica Sinica,2012,70(2):114-120.
[17] WANG Yun-pu,LIU Yu-huan,RUAN Rong-sheng,et al.Microwave-assisted decarboxylation of sodium oleate and renewable hydrocarbon fuel production[J].China Petroleum Processing & Petrochemical Technology,2013,15(3):19-27.
[18] WANG Yun-pu,LIU Yu-huan,RUAN Rong-sheng,et al.Investigation of hydrocarbon generation mechanism by polarizing the carboxy-group of fatty acid salt with microwave radiation[J].Asian Journal of Chemistry,2014,26(2):369-375.
[19] 刘玉环,王允圃,王应宽,等.微波裂解光皮树油皂化物脱羧制备烃类燃料研究[J].农业机械学报,2012,43(2):106-111. LIU Yu-huan,WANG Yun-pu,WANG Ying-kuan,et al.Microwave-assisted pyrolysis of swida wilsoniana fruit oil soap for preparing renewable hydrocarbon fuel via selective decarboxylation[J].Transactions of the Chinese Society for Agricultural Machinery,2012,43(2):106-111.
[20] KUBTOV A,LUO Yan,VOV J,et al.New path in the thermal cracking of triacylglycerols (canola and soybean oil)[J].Fuel,2011,90(8):2598-2608.
[21] HERSKOWITZ M.Reaction system for production of diesel fuel from vegetable and animals oils:USA,US 2008/0066374 Al[P].2008-04-20.

Preparation of Renewable Fuel from Saponificated China Tallow Oil by Fast Pyrolysis Reaction Assisted with Microwave

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