木质素模型物紫丁香酚基丙三醇-β-愈创木基丙醚的合成与结构表征

doi:10.3969/j.issn.0253-2417.2015.05.011

Abstract

Abstract: A novel lignin model compound named guaiacylglycerol-β-guaiacyl ether (SG) was synthesized from acetosyringone via bromination, substitution, hydroxyl methylation and reduction reaction. Its structure was characterized by FT-IR, ¹H NMR, ¹³C NMR, HRMS and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis showed that the compound was of triclinic system, space group P-1 with a=0.724 20(14), b=1.077 0(2), c=1.2054(2) nm, β=90.43(3)°, V=0.858 0(3) nm³, Z=2, M_r=350.36, F(000)=372, μ(MoKα)=0.104 mm^-1, D_C=1.356 g/cm³, λ=0.071 073 nm, the final R=0.060 2 and wR=0.162 1. In addition, the dimer was formed through intermolecular hydrogen bonds in crystal packing of the title compound.

Key words: lignin, model compound, synthesis, structure characterization, single-crystal X-ray diffraction

CLC Number:

TQ35
O621.3

YANG Xiao-hui, XIAO Guo-min, JIANG Jian-chun, ZHOU Yong-hong. Synthesis and Characterization of A Novel Lignin Model Compound Named Guaiacylglycerol-β-guaiacyl Ether[J]. Chemistry and Industry of Forest Products, 2015, 35(5): 65-70.

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Synthesis and Characterization of A Novel Lignin Model Compound Named Guaiacylglycerol-β-guaiacyl Ether

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