AB-8大孔树脂吸附黑枸杞中花青素行为研究

doi:10.3969/j.issn.0253-2417.2016.04.011

Abstract

Abstract: The adsorption performance of AB-8 resin for anthocyanin from Lycium ruthenicum Murray and adsorption mechanism were analyzed by equilibrium adsorption experiment, isothermal adsorption experiment and column adsorption experiment. The results showed that the adsorption kinetics process of AB-8 resin for anthocyanin could well fit with Elovich kinetic model. The linear straight of regression displayed that the Freundlich model was more suitable. Moreover, the enthalpy changes were positive and the absolute value was less than 40 kJ/mol. This indicated the adsorptions of AB-8 resin for anthocyanins were endothermic and physical changes. The Gibbs free energy changes were negative. It indicated that the adsorption process occurred spontaneously. The positive value of entropy changes indicated the increased randomness during the adsorption process. The adsorption mechanism was complicated and the adsorption process was mainly affected by particle diffusion. Adams-Bohart model analysis showed that in the process of column adsorption purification anthocyanins, the flow of mobile phase and the bed height should be reduced and the quality of anthocyanin concentrations should be increased.

Key words: anthocyanin, kinetics, thermodynamics, adsorption mechanism, separation purification

CLC Number:

TQ35

WANG Hong, FU Yan-qiu, HAN Jing, ZHAO Yu-ming, LIU Dong. Adsorption Behavior of AB-8 Resin for Anthocyanins from Lycium ruthenicum Murray[J]. Chemistry and Industry of Forest Products, 2016, 36(4): 79-86.

References

[1] LIU Zeng-gen,SHU Qing-yan,WANG Lei,et al.Genetic diversity of the endangered and medically important Lycium ruthenicum Murr.revealed by sequence-related amplified polymorphism (SRAP) markers[J].Biochemical Systematics and Ecology,2012,45:86-97.
[2] PENG Qiang,LV Xiao-peng,XU Qing-song,et al.Isolation and structural characterization of the polysaccharide LRGPI from Lycium ruthenicum[J].Carbohydrate Polymers,2012,90(1):95-101.
[3] ZHENG Jie,DING Chen-xu,WANG Liang-sheng,et al.Anthocyanins composition and antioxidant activity of wild Lycium ruthenicum Murr.from Qinghai-Tibet Plateau[J].Food Chemistry,2011,126(3):859-865.
[4] LIU Tong-xun,CAO Yan-ni,ZHAO Mou-ming.Extraction optimization,purification and antioxidant activity of procyanidins from hawthorn (C.pinnatifida Bge.var.major) fruits[J].Food Chemistry,2010,119(4):1656-1662.
[5] HAREYAMA M D,IMAI M D K,KUBO K.Effect of radiation on the expression of carcinoembryonic antigen of human gastric adenocarcinoma cells[J].Cancer,1991,67(9):2269-2274.
[6] DU Xue-ling,YUAN Qi-peng,LI Ye.Equilibrium,thermodynamics and breakthrough studies for adsorption of solanesol onto macroporous resins[J].Chemical Engineering and Processing,2008,47(8):1420-1427.
[7] ZHOU Hua-ying,LIU Chun-zhao.Microwave-assisted extraction of solanesol from tobacco leaves[J].Journal of Chromatography A,2006,1129(1):135-139.
[8] ZHAO Yu-hua,WANG Yu-wen,SHI Jun-ping.Exact multiplicity of solution and S-shaped bifurcation curve for a class of semilinear elliptic equations[J].Journal of Mathematical Analysis and Applications,2007,331(1):263-278.
[9] 陈莉华,张俊生,朱士龙.大孔吸附树脂对湘西节节草多糖的吸附特性及机理[J].林产化学与工业,2013,33(5):55-60. CHEN Li-hua,ZHANG Jun-sheng,ZHU Shi-long.Adsorption characteristics and mechanism of macroporous resin to polysaccharide from Equisetum ramosissimum Desf.[J].Chemistry and Industry of Forest Products,2013,33(5):55-60.
[10] CHARPE T W,RATHOD V K.Separation of glycyrrhizic acid from licorice root extract using macroporous resin[J].Food and Bioproducts Processing,2015,93:51-57.
[11] DU Zhan-quan,WANG Kun,TAO Yuan,et al.Purification of baicalin and wogonoside from Scutellaria baicalensis extracts by macroporous resin adsorption chromatography[J].Journal of Chromatography B,2012,908:143-149.
[12] XIONG Qing-ping,ZHANG Qiang-hua,ZHANG Dan-yan,et al.Preliminary separation and purification of resveratrol from extract of peanut (Arachis hypogaea) sprouts by macroporous adsorption resins[J].Food Chemistry,2014,145:1-7.
[13] 李春阳,许时婴,王璋.香草醛-盐酸法测定葡萄籽、梗中原花青素含量的研究[J].食品科学,2004,25(2):157-161. LI Chun-yang,XU Shi-ying,WANG Zhang.Vanillin-HCl assay for the proanthocyanidins content of grape seed and stem[J].Food Science,2004,25(2):157-161.
[14] ZOU Shu-ping,LIU Miao,WANG Qiu-liang,et al.Preparative separation of echinocandin B from Aspergillus nidulans broth using macroporous resin adsorption chromatography[J].Journal of Chromatography B,2015,978/979:111-117.
[15] CRINI G,PEINDY H N,GIMBERT F,et al.Removal of C.I.Basic Green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent:Kinetic and equilibrium studies[J].Separation and Purification Technology,2007,53(1):97-110.
[16] ÖZAGCAR M S,S,ENGIL Í A.Adsorption of metal complex dyes from aqueous solutions by pine sawdust[J].Bioresource Technology,2005,96(7):791-795.
[17] MARTINEZ S,STERN I.Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in the low carbon steel/mimosa tannin/sulfuric acid system[J].Applied Surface Science,2002,199(1/2/3/4):83-89.
[18] KHAMBHATY Y,MODY K,BASHA S,et al.Kinetics,equilibrium and thermodynamic studies on biosorption of hexavalent chromium by dead fungal biomass of marine Aspergillus niger[J].Chemical Engineering Journal,2009,145(3):489-495.
[19] KHAMBHATY Y,MODY K,BASHA S.Efficient removal of Brilliant Blue G (BBG) from aqueous solutions by marine Aspergillus wentii:Kinetics,equilibrium and process design[J].Ecological Engineering,2012,41:74-83.
[20] ÖZAGCAR M,ŞENGIL Í A.Adsorption of reactive dyes on calcined alunite from aqueous solutions[J].Journal of Hazardous Materials,2003,98(1/2/3):211-224.
[21] BULUT E,ÖZACAR M,S,ENFIL Í A.Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite[J].Journal of Hazardous Materials,2008,154(3):613-622.
[22] TONG K S,KASSIM M J,AZRAA A.Adsorption of copper ion from its aqueous solution by a novel biosorbent Uncaria gambir:Equilibrium,kinetics,and thermodynamic studies[J].Chemical Engineering Journal,2011,170(1):145-153.
[23] HAN Run-ping,WANG Yi,ZOU Wei-hua,et al.Comparison of linear and nonlinear analysis in estimating the Thomas model parameters for methylene blue adsorption onto natural zeolite in fixed-bed column[J].Journal of Hazardous Material,2007,145(1/2):331-335.
[24] TATYCOSTODES V C,FAUDUET H,PORTE C,et al.Removal of lead (Ⅱ) ions from synthetic and real effluents using immobilized Pinus sylvestris sawdust:Adsorption on a fixed-bed column[J].Journal of Hazardous Materials,2005,B123(1/2/3):135-144.
[25] GHORAI S,PANT K K.Equilibrium,kinetics and breakthrough studies for adsorption of fluoride on activated alumina[J].Separation and Purification Technology,2005,42(3):265-271.

Adsorption Behavior of AB-8 Resin for Anthocyanins from Lycium ruthenicum Murray

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