纳米羧甲基淀粉在微涂纸中的应用

doi:10.3969/j.issn.0253-2417.2017.05.014

Abstract

Abstract: In this study, the nano carboxymethy starch(NCMS) was prepared by dual screw extrusion and was used as coating adhesive in micro weight coated paper(MWC). The results showed that the surface of NCMS particle was smooth and it had excellent film-forming and high film strength. The tensile strength of film can reach to 4.67 MPa,breaking elongation 26.9%. The negative charge density of NCMS is lower than that of common oxidized starch. For the paper coating formula of micro weight coated paper, when the dosage of NCMS used as the coating adhesive was 14%, the water retention properties of coating was increased evidently and the water retention value was 43.6 g/m²; the IGT printing surface strength of MWC was 0.89 m/s; the longitudinal and transverse tensile index was 47.8 and 21.7(N·m)/g separately; the ink absorption of MWC was 36.8% and 61% separately. Comparing with 20% common oxidized starch coating formulation,the water retention properties of coating was increased by 25.3%, coating viscosity was decreased by 12.4%, and the IGT printing surface strength and tensile index of MWC were improved in different degree.

Key words: nano carboxymethyl starch, coating, adhesive, paper properties

CLC Number:

TQ35
TS727

CHEN Qijie, DONG Xufang, ZHOU Liling, ZHENG Xueming, WANG Ping. Application of Nano Carboxymethyl Starch in Micro Weight Coated Paper[J]. Chemistry and Industry of Forest Products, 2017, 37(5): 107-112.

References

[1] LE C D,BRAS J,DUFRESNE A. Starch nanoparticles:A review[J]. Biomacromolecules,2010,11(5):1139-1153.
[2] CORRE D L,ANGELLIER C H. Preparation and application of starch nanoparticles for nanocomposites:A review[J]. Reactive & Functional Polymers,2014,8(5):97-120.
[3] 王晨飞,杨亮,崔萍. 羧甲基淀粉研究新进展[J]. 染整技术,2016,38(11):1-5. WANG C F,YANG L,CUI P. New research development of carboxymethyl starch[J]. Textile Dyeing and Finishing Journal,2016,38(11):1-5.
[4] 刘金刚,曹振雷,彭建军,等. 施胶压榨微量涂布技术[J]. 中国造纸,2003,22(4):26-29. LIU J G,CAO Z L,PENG J J,et al. Size press slight coating technology[J].China Pulp & Paper,2003,22(4):26-29.
[5] DU Y,ZANG Y H,DU J. Effects of starch on latex migration and on paper coating properties[J]. Industrial & Engineering Chemistry Research,2011,50(16):9781-9786.
[6] 王旭青,周小凡. 用淀粉代替部分胶乳对涂布纸性能的影响[J]. 南京林业大学学报:自然科学版,2011,35(1):79-82. WANG X Q,ZHOU X F. Effect of replacing latex with starch on coated paper properties[J]. Journal of Nanjing Forestry University:Natural Science Edition,2011,35(1):79-82.
[7] 陈启杰,晏永祥,张雄飞.一种纳米羧甲基淀粉的制备方法:CN 2013104684975[P].2015-08-12. CHEN Q J,YAN Y X,ZHANG X F. A method of preparing the nano carboxymethyl starch:CN 2013104684975[P].2015-08-12.
[8] 王绍清,王琳琳,范文浩,等. 扫描电镜法分析常见可食用淀粉颗粒的超微形貌[J]. 食品科学,2011,32(15):74-79. WANG S Q,WANG L L,FAN W H,et al. Morphological analysis of common edible starch granulces by scanning electron microscopy[J]. Food Science,2011,32(15):74-79.
[9] 陈夫山,谢来苏,魏德津,等. 用胶体滴定法测定聚合物的电荷[J]. 中国造纸,2000,19(2):32-37. CHEN F S,XIE L S,WEI D J,et al. Charge of the polymer was measured by colloidal titration[J]. China Pulp and Paper,2000,19(2):32-37.
[10] LÓPEZ O V,GARCÍA M A. Starch films from a novel(Pachyrhizus ahipa) and conventional sources:Dev1lopment and characterization[J]. Materials Science & Engineering C,2012,32(7):1931-1940.
[11] 曹晶晶,杨益琴.TEMPO/NaBr/NaClO体系下氧化淀粉的制备及其结构性能表征[J].南京林业大学学报:自然科学版,2011,35(2):88-92. CAO J J,YANG Y Q. Preparation and structure characterization of oxidized starch in TEMPO/NaBr/NaClO oxidation system[J]. Journal of Nanjing Forestry University:Natural Science Edition,2011,35(2):88-92.
[12] 陈启杰,董徐芳,周丽玲,等. 挤压法制备玉米纳米淀粉及其表征[J]. 食品与机械,2017,33(5):40-44. CHEN Q J,DONG X F,ZHOU L L,et al. Preparation and characterization of corn nano-starch by screw extrusion[J]. Food & Machinery,2017,33(5):40-44.
[13] 王奇琦. 影响高固含量涂料流变特性因素的研究[D]. 南京:南京林业大学硕士学位论文,2014. WANG Q Q. Study on the factors affecting the rheological properties of high solid content coatings[D].Nanjing:Master Degree Thesis of Nanjing Forest University,2014.
[14] 杜艳芬,刘金刚,王比松,等.淀粉基生物胶乳纸张涂料的流变性研究[J].纸和造纸,2015,34(1):40-43. DU Y F,LIU J G,WANG B S,et al.Study on rheological of paper coating with starch-based bio-latex[J]. Paper and Papermaking,2015,34(1):40-43.
[15] 王兴,张美云,罗英. 浅析纸张的光学性能[J].黑龙江造纸,2012,40(3):37-39. WANG X,ZHANG M Y,LUO Y. Analysis of paper optical properties[J]. Helongjiang Papermaking,2012,40(3):37-39.
[16] 杨保宏,李志健. 涂布对纸张光泽度和印刷光泽度的影响[J]. 纸和造纸,2011,30(3):31-33. YANG B H,LI Z J. Impacts of coating on paper gloss and printing performance[J]. Paper and Papermaking,2011,30(3):31-33.
[17] JONCKHERREE E,MABIRE F. Improving the water fastness of high quality matt and glossy ink-jet printing papers[J]. Paper Technology,2003,44:38-44.
[18] 郝妮. 低定量涂布纸原纸浆料特性的研究[D]. 西安:陕西科技大学硕士学位论文,2006. HAO N. Study on the pulp properties of LWC[D].Xi'an:Master Degree Thesis of Shaanxi University of Technology,2006.
[19] PRASAD V,SHAIKH A J,KATHE A A,et al. Functional behaviour of paper coated with zinc oxide-soluble starch nanocomposites[J]. Journal of Materials Processing Technology,2010,210(14):1962-1967.

Application of Nano Carboxymethyl Starch in Micro Weight Coated Paper

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	CHEN Jian, WU Guomin, HUO Shuping, KONG Zhenwu. Research Progress of Cardanol Based UV-cured Materials [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 1-10.
[2]	WANG Rongxing, ZHANG Zuxin, CHEN Riqing, ZHAO Linwu, WANG Chunpeng, CHU Fuxiang. Synthesis of Phenol-urea-formaldehyde Resin and Its Reaction Mechanism [J]. Chemistry and Industry of Forest Products, 2018, 38(1): 101-109.
[3]	XIAO Shaobo, YU Yun, YANG Ningning, HUANG Qiongtao, YANG Yan, LIAO Youwei. Preparation and Performance of Regenerated Nitrocellulose Lacquer [J]. Chemistry and Industry of Forest Products, 2017, 37(3): 95-100.
[4]	XU Wei, LIU Junli, MIAO Cunbiao, SUN Kang, SONG Yaoguang. Preparation and Properties of Formed Activated Carbon Coated by Ethyl Cellulose [J]. Chemistry and Industry of Forest Products, 2017, 37(2): 49-56.
[5]	QIAO Zhi-bang, GU Ji-you, CAO Jun, TAN Hai-yan, ZHANG Yan-hua. Thermal Decomposition Kinetics of Room Temperature Cured Starch-based Wood Adhesive [J]. Chemistry and Industry of Forest Products, 2016, 36(1): 85-91.
[6]	WU Zhi-gang, DU Guan-ben, LEI Hong, WANG Hui, XI Xue-dong, CAO Ming, LIAO Jing-jing. Modification of Soy Protein-based Adhesives by a New Phenol Formaldehyde Resin [J]. Chemistry and Industry of Forest Products, 2016, 36(1): 119-126.
[7]	WANG Shu-min, SHI Jun-you. Durability of Aqueous Polymer Isocyanate Wood Adhesive [J]. Chemistry and Industry of Forest Products, 2015, 35(2): 25-30.
[8]	LIU Juan, YU Xiang-dong, WANG Chun-peng, BU Hong-zhong, CHEN Ri-qing. Properties of Halogen-free Flame Retardant EVA Copolymer Emulsion Adhesive [J]. Chemistry and Industry of Forest Products, 2014, 34(5): 139-144.
[9]	XING Zhen-zhen, WU Wei-qian, ZENG Tao. Tackifying Effect of Sweetgum Resin in SIS Hot Melt Adhesive [J]. Chemistry and Industry of Forest Products, 2014, 34(2): 51-55.
[10]	LU Xin-cheng;JIANG Jian-chun;MENG Zhong-lei;SUN Kang;XIE Xin-ping. Preparation and Properties of Formed Biomass Charcoal [J]. , 2013, 33(2): 81-84.
[11]	WU Hong;WANG Ji-fu;CHU Fu-xiang;WANG Chun-peng;LIU Mei-hong;LIN Ming-tao;. The UV Curing Kinetics of Acrylic Rosin(β-Acryloxyl Ethyl) Ester [J]. , 2011, 31(5): 76-80.
[12]	SHI Wei-sheng;GE Zhen-yang;TANG Hui;WANG Ya-ming. Study on Degradation Behavior of Tung Oil as Coating Material in Soil [J]. , 2010, 30(3): 49-52.
[13]	WU Hong;LIN Ming-tao;WANG Ji-fu;WANG Chun-peng;CHU Fu-xiang;LIU Mei-hong;. Study on Properties and Performance of UV-curing Coating of 2-Hydroxyethyl Acrylate/Acrylic Rosin Derivatives [J]. , 2010, 30(2): 43-46.
[14]	CHAI Xi-juan;ZHANG Jia-yan;HU Huan-jun. Study on Preparation of Biodegradable Foamed Material from Bagasse Fiber Using Microwave Irradiation [J]. , 2009, 29(S1): 165-168.
[15]	FANG Hong-xia;WU Qiang-lin;ZHANG Lei. Preparation of Liquefied-lignosulfonate-based Phenol-formaldehyde Adhesive with Environmentally—Benign Property [J]. , 2009, 29(4): 92-96.