端氨基纳米纤维素的制备及对Pb(Ⅱ)的吸附性能研究

doi:10.3969/j.issn.0253-2417.2018.06.002

Abstract

Abstract: Carboxylated nanocellulose(CNC) was synthesized from eucalyptus pulp by using 2,2,6,6-tetramethylpiperidinyl-1-oxy radical(TEMPO) oxidation, then dialdehyde-based nanocellulose(DANC) was synthesized by sodium periodate oxidation. Finally, the amino modification of DANC was carried out by Schiff base reaction with diethylenetriamine to obtain amino-terminated nanocellulose(ANCC). The structure and properties of nanocellulose were characterized by various methods. The results showed that DANC had an aldehyde group of 2.95 mmol/g and ANCC had an amino group of 1.7 mmol/g. The amino group on DETA was successfully grafted to nanocellulose. In the chain, the molecular chain became longer and the thermal stability of the ANCC improved. The adsorption properties of ANCC on Pb(Ⅱ) showed that, under the conditions of room temperature, dosage of ANCC adsorbent 0.1 g, initial mass concentration of adsorption solution 400 mg/L, pH value 5 and adsorption time 3 h, the adsorption capacity was 210.15 mg/g. The adsorption followed the pseudo second order kinetics equation and Langmiur adsorption isotherm, which indicated that the adsorption process was mainly chemical adsorption of single molecular layer.

Key words: eucalyptus pulp, nanocellulose, aminolation, adsorption

CLC Number:

TQ35

CHEN Jinwei, SHANG Shibin, SHEN Minggui, WANG Dan, FU Fei, CAI Zhaosheng. Preparation of Amino Acid-terminated Nanocellulose and Adsorption Properties of Pb(Ⅱ)[J]. Chemistry and Industry of Forest Products, 2018, 38(6): 11-19.

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Preparation of Amino Acid-terminated Nanocellulose and Adsorption Properties of Pb(Ⅱ)

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