Chemistry and Industry of Forest Products ›› 2019, Vol. 39 ›› Issue (2): 96-102.doi: 10.3969/j.issn.0253-2417.2019.02.014
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Xincheng LU1,2,3(),Jianchun JIANG1,2,*(),Jing HE3,Kang SUN1,2,Yunjuan SUN1,2
Received:
2018-11-29
Online:
2019-04-25
Published:
2019-05-08
Contact:
Jianchun JIANG
E-mail:xinze1983@163.com;bio-energy@163.com
Supported by:
CLC Number:
Xincheng LU,Jianchun JIANG,Jing HE,Kang SUN,Yunjuan SUN. Preparation and Properties of Wood Vinegar from Pyrolysis of Fir Sawdust Under Different Temperatures[J]. Chemistry and Industry of Forest Products, 2019, 39(2): 96-102.
Table 2
Composition of wood vinegar at different temperature range"
类别 class | 有机物名称 compounds | 分子式 molecular formula | 组分GC含量/ %GC contents of organic compounds | |||
0~150 ℃ | ≥150~250 ℃ | ≥250~350 ℃ | ≥350~450 ℃ | |||
酸类 acids | 乙酸 acetic acid | C2H4O2 | 2.75 | 9.17 | 1.67 | 1.66 |
丙酸 propanoic acid | C3H6O2 | — | 3.18 | — | — | |
庚酸 heptylic acid | C7H14O2 | 13.79 | — | — | 14.00 | |
戊酸 pentanoic acid | C6H12O2 | 44.65 | 6.75 | 2.03 | 13.95 | |
3-甲氧基-4-羟基苯甲酸 3-methoxy-4-hydroxybenzoic acid | C9H10O4 | 3.65 | 3.76 | 13.68 | — | |
酚类 phenols | 苯酚 phenol | C6H6O | 2.66 | 1.07 | — | 1.20 |
2-甲氧基苯酚 2-methoxy phenol | C7H8O2 | 3.99 | 6.99 | 8.21 | 8.03 | |
2-甲基苯酚 2-methyl phenol | C7H8O | — | 1.78 | — | — | |
3-甲基苯酚 3-methyl phenol | C7H8O | 1.03 | 2.20 | — | — | |
麦芽酚 maltol | C6H6O2 | — | 2.52 | 1.67 | — | |
4-甲基-2-甲氧基苯酚 4-methyl-2-methoxy phenol | C8H10O2 | 1.27 | 7.35 | 1.78 | 5.00 | |
邻苯二酚 1, 2-benzenediol | C6H6O2 | 13.17 | 4.68 | — | 9.79 | |
4-乙基-2-甲氧基苯酚 4-ethyl-2-methoxy phenol | C9H12O2 | — | 4.22 | 22.91 | — | |
丁子香酚 eugenol | C10H12O2 | — | 4.18 | — | — | |
4-丙烯基-2-甲氧基苯酚 4-propenyl-2-methoxy phenol | C10H12O2 | — | 4.10 | 8.13 | — | |
4-丙基-2-甲氧基苯酚 4-propyl-2-methoxy phenol | C10H14O2 | — | 3.22 | 10.27 | 9.62 | |
2, 6-二甲氧基苯酚 2, 6-dimethoxy phenol | C9H12O2 | — | — | 1.16 | — | |
3-甲基邻苯二酚 3-methyl-1, 2-benzenediol | C7H8O2 | 3.57 | — | — | 1.43 | |
4-甲基邻苯二酚 4-methyl-1, 2-benzenediol | C7H8O2 | 4.40 | — | — | 11.03 | |
酮类 ketones | 1-羟基-2-丁酮 1-hydroxy-2-butanone | C4H8O2 | — | 1.38 | — | — |
丙酮 acetone | C3H6O | 1.54 | 2.75 | 0.94 | 0.81 | |
2-呋喃酮 2-furanone | C4H4O2 | — | 2.54 | — | — | |
1, 2-环戊二酮 1, 2-cyclopentanedione | C5H6O2 | — | 2.25 | 2.75 | 2.43 | |
3-甲基-1, 2-环戊二酮 3-methyl-1, 2-cyclopentanedione | C6H8O2 | 1.67 | 3.58 | 3.00 | 1.18 | |
4-羟基-3-甲氧基苯乙酮 4-hydroxy-3-methoxyhypnone | C9H10O3 | — | 2.08 | 3.71 | 11.92 | |
3-甲氧基苯乙酮 3-methoxyhypnone | C9H9O2 | — | — | 7.55 | — | |
醛类 aldehydes | 糠醛 furfural | C5H4O2 | — | 4.65 | 0.99 | 1.78 |
5-甲基-2-糠醛 5-methyl-2-furfural | C6H6O2 | — | 1.61 | 1.99 | — | |
5-羟甲基糠醛 5-hydroxymethylfurfural | C6H7O3 | — | 7.10 | 2.19 | — | |
香草醛 vanillin | C8H8O3 | — | 3.79 | — | — | |
醇类 alcohols | 2-呋喃甲醇 2-furfuryl alcohol | C5H6O2 | — | — | 1.28 | — |
4-羟基-3-甲氧基苯乙醇 4-hydroxy-3-methoxy phenethyl alcohol | C9H12O3 | 1.86 | 3.10 | 4.09 | 6.17 |
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