生物质催化制备甲烷的反应路径和催化剂研究进展

doi:10.3969/j.issn.0253-2417.2019.03.001

Abstract

Abstract:

Methane is the hydrocarbon with highest hydrogen-carbon ratio, and is a kind of clean energy with high combustion calorific value as well. During the preparation of methane from biomass, biomass fermentation and biomass syngas fermentation are limited by the temperature sensitivity of active bacteria. This paper introduces the research progress of reaction mechanism and corresponding catalyst system of biomass synthesis gas to methane by chemical catalysts. The reaction mechanism of CO methanation and CO₂ methanation in syngas, as well as the effects of active ingredients, supports and promoters in catalysts on methanation are mainly discussed. At the same time, the catalytic hydrothermal method of biomass with mild reaction conditions is also introduced. The reaction route and research progress in recent years are briefly described. Finally, methanation reaction mechanism and efficient, stable catalysts are perspective remarked from the technical point of view.

Key words: biomass, methane, catalytic hydrothermal method

CLC Number:

TQ35

Chiliu CAI,Changhui ZHU,Haiyong WANG,Chenguang WANG,Qiying LIU,Longlong MA. Research Progress of Reaction Path and Catalysts Used in Catalytic Conversion Process of Biomass to Methane[J]. Chemistry and Industry of Forest Products, 2019, 39(3): 1-9.

Figures/Tables 4

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Fig.2

Table 1

Table 2

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催化剂¹⁾ catalyst	制备方法 preparation method	温度/℃ temperature	压力/MPa pressure	空速/(mL·g^-1·h^-1) space velocity	CO转化率/% CO conversion	甲烷选择性/% CH₄ selectivity	文献来源 literature
40%Ni/Al₂O₃	溶胶-凝胶法sol-gel	230	1	8160	96.5	76.8	[13]
4.2%Ni/SiC	浸渍法impregnation	500	3	4006	96.7	100	[14]
20%Ni-Mg/Al₂O₃	浸渍法impregnation	400	0.1	30000	100	80	[15]
23%Ni-TiO₂	超声波法ultrasonic	280	0.1	38800 h^-1	52	95	[16]
10%Ni/MCM-41	浸渍法impregnation	450	1.5	20745	61.4	77.5	[17]
10%Ni/MCM-41	水热法hydrothermal	350	0.1	12000	97.9	88.2	[18]
10%Ni-Mo/MCM-41	浸渍法impregnation	280	0.1	12000	100	80	[19]
30%Ni-10%Fe/Al₂O₃-AX	溶胶-凝胶法sol-gel	230	1	8160	99.4	86.8	[20]

催化剂¹⁾ catalyst	制备方法 preparation method	温度/℃ temperature	压力/MPa pressure	空速/(mL·g^-1·h^-1) space velicity	CO₂转化率/% CO₂ conversion	甲烷选择性/% CH₄ selectivity	文献来源 literature
10%Ni/Al₂O₃	浸渍法impregnation	400	0.1	7200	57.8	94	[21]
Ni/MSN	溶胶-凝胶法sol-gel	300	0.1	50000	64.1	99.9	[22]
15%Ni-TiO₂	沉积沉淀法deposition-precipitation	218	0.1	2400	50	99	[23]
Ni/CeO₂	硬模板法hard template	360	0.1	45000	91.1	100	[24]
Ni-Ru/Al₂O₃	共沉淀法coprecipitation	350	0.1	9000	70	—	[25]
Ru-CeO₂/Al₂O₃	浸渍法impregnation	300	0.1	10000	60	99	[26]
Ni/MC γ-Al₂O₃	浸渍法impregnation	300	0.1	9000	74	100	[27]
2%La-10%Ni/ γ-Al₂O₃	浸渍法impregnation	450	0.15	7200	70	95	[28]
Co_0.4Ni/SiO₂	浸渍法impregnation	300	0.1	13200	58	—	[29]
Pt/Zr₆O₄(OH)₄	浸渍法-双溶剂法impregnation-double solvent	350	0.1	1650	50	36	[30]

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Research Progress of Reaction Path and Catalysts Used in Catalytic Conversion Process of Biomass to Methane

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