木材胶黏剂研究进展

doi:10.3969/j.issn.0253-2417.2020.02.001

Abstract

Abstract:

The consumption of wood adhesive in China is huge. However, the main wood adhesive based on formaldehyde is still prevalent. In recent years, environment friendly adhesives such as non-formaldehyde adhesives and biomass adhesives have developed rapidly. Herein, the recent research and application of wood adhesives including urea-formaldehyde resin adhesives, phenolic resin adhesives, melamine-formaldehyde resin adhesives, protein adhesives, lignin adhesives, starch adhesives, tannins adhesives, isocyanate adhesive, emulsion adhesives and pyrolysis biological oil adhesives were reviewed. The development trend and the research direction of wood adhesives were also prospected.

Key words: wood industry, adhesive, research development, development trend

CLC Number:

TQ43
TQ35

Yufeng MA,Xuan'ang GONG,Chunpeng WANG. Research Progress in Wood Adhesives[J]. Chemistry and Industry of Forest Products, 2020, 40(2): 1-15.

Figures/Tables 7

Table 1

Fig.1

Fig.2

Table 2

Properties of wood-based panels with soybean protein adhesives by different modifiers"

原料 raw materials	改性剂 modifiers	参照标准 reference standards	胶合强度¹⁾/MPa bonding strength	耐水等级 water resistant level
豆粕蛋白粉 soybean meal protein powder	水性聚酰胺、乙二醛、异氰酸酯 aqueous polyamide, glyoxal, isocyanate	GB/T 17657—1999	＞0.7^[30]	Ⅱ
	封闭的异氰酸酯 closed isocyanate	GB/T 9846.1— 2004	0.8~1.0^[31]	Ⅱ
大豆分离蛋白 soybean protein isolate	硫脲、三聚磷酸钠、二氧化硅 thiourea, sodium tripolyphosphate, silicon dioxide	GB/T 17657—1999	2.12(D)/1.01(W)^[32]	Ⅱ
	聚酰胺多胺环氧氯丙烷 polyamide polyamine epichlorohydrin	GB/T 17657—1999	1.12(W)^[33]	Ⅰ
	尿素、聚乙烯醇、异氰酸酯、酰胺类聚合物urea, polyvinyl alcohol, isocyanate, amide polymers	GB/T 17657—1999	＞0.7^[34]	Ⅱ
	乙二醇二缩水甘油醚、二乙烯三胺 ethylene glycol diglycidyl ether, diethy-enetriamine	GB/T 17657—2013	0.9, 1.27, 1.15 (W)^[35]	Ⅱ
大豆豆粕粉 soybean meal powder	氢氧化钠、乙醇、硫脲、十二烷基硫酸钠 sodium hydroxide, ethanol, thiourea, lauryl sodium sulfate	GB/T 9846.1—2004	0. 98(W)^[36]	Ⅱ
	硅烷偶联剂、乙二醇二缩水甘油醚 silane coupling agent, ethylene glycol diglycidyl ether	GB/T 17657—2013	0.98~1.06 ^[37]	Ⅱ
	丙烯酰胺、聚丙烯酸钠 acrylamide, sodium polyacrylate	GB/T 17657—1999	1.20(W)^[38]	Ⅰ
	十一碳烯酸 undecylenic acid	ASTM D2339—98	5.99~6.67(D)/ 2.04~3.30(W)^[39]	Ⅱ
	环氧氯丙烷、环氧树脂 epichlorohydrin, epoxy resin	GB/T 17657—1999	0.9~0.95(W)^[40]	Ⅰ
脱脂豆粉 defatted soybean meal	苯酚、甲醛 phenol, formaldehyde	GB/T 17657—1999	0.82~1.47 ^[41]	Ⅰ
	环氧树脂、三聚氰胺-甲醛树脂 epoxy resin, melamine-formaldehyde resin	GB/T 9846.1—2004	0.93^[42]	Ⅰ
	环氧树脂、三聚氰胺-甲醛树脂 epoxy resin, melamine-formaldehyde resin	GB/T 9846.3—2004	0.81(W)^[43]	Ⅰ

Table 2

Fig.3

Fig.4

Fig.5

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醛脲比 molar ratio of formaldehyde to urea	改性剂 modifier	改性剂作用类别 type of action of modifier	胶合板性能the properties of plywood		参考文献 references
醛脲比 molar ratio of formaldehyde to urea	改性剂 modifier	改性剂作用类别 type of action of modifier	耐水性等级 water resistance grade	甲醛释放量等级 formaldehyde emission grade	参考文献 references
1.3	纳米二氧化钛nano-TiO₂	共混blend	Ⅱ	E₀	[5]
1.2	二乙醇胺、三聚氰胺 diethanolamine, melamine	共聚copolymerization		E₀	[6]
1.5	秸秆乙醇残渣 straw ethanol residue	共聚/共混 copolymerization/blend	Ⅱ	E₀	[7]
1.5	羟甲基化秸秆乙醇残渣 hydroxy methylated straw residue for ethanol	共混blend	Ⅱ	E₀	[8]

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