Chemistry and Industry of Forest Products ›› 2020, Vol. 40 ›› Issue (2): 117-124.doi: 10.3969/j.issn.0253-2417.2020.02.016
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Bozheng LI1,Dongmei BI1,*(),Yongjun LI1,2,Mei JIANG1
Received:
2019-09-05
Online:
2020-04-28
Published:
2020-04-27
Contact:
Dongmei BI
E-mail:bidongmei@sdut.edu.cn
CLC Number:
Bozheng LI,Dongmei BI,Yongjun LI,Mei JIANG. Catalytic Pyrolysis of Biomass to Produce Specific High Value-added Furans and Aldehydes Chemicals[J]. Chemistry and Industry of Forest Products, 2020, 40(2): 117-124.
Table 1
Proximate, ultimate and material analysis results of drying different materials %"
原料 samples | 纤维素 cellulose | 半纤维素 hemicellulose | 木质素 lignin | 元素分析elemental analysis(wd) | 工业分析ultimate analysis(wd) | ||||||
C | H | O* | N | 固定炭 fixed carbon | 挥发分 volatiles | 灰分 ash | |||||
油菜秸秆rape straw | 35.41 | 17.84 | 21.64 | 48.52 | 5.74 | 45.23 | 0.51 | 15.27 | 79.18 | 5.55 | |
玉米秸秆corn straw | 32.54 | 18.34 | 22.02 | 47.46 | 5.78 | 46.32 | 0.44 | 12.26 | 80.59 | 7.15 | |
樟木粉camphor wood powder | 37.62 | 12.65 | 34.74 | 53.16 | 6.12 | 40.34 | 0.38 | 13.35 | 86.14 | 0.51 |
Table 2
Distribution of furans and aldehydes in the bio-oil of three raw materials"
原料 samples | 化合物 compounds | GC含量GC content/% | ||
无催化剂catalyst-free | ZnCl2 | |||
油菜秸秆 rape straw | 醛类 aldehyde | 多聚甲醛paraformaldehyde | 0.63 | 0.35 |
二乙醇缩甲醛diethoxy methane | — | 1.16 | ||
羟基乙醛hydroxy-acetaldehyde | 1.42 | — | ||
丁二醛butanedial | 2.58 | — | ||
5-乙酰氧基甲基-2-呋喃醛5-acetoxymethylfurfural | 1.05 | |||
呋喃类 furan | 糠醛furfural | 3.81 | 29.49 | |
糠醇furanmethanol | 1.99 | — | ||
5-甲基糠醛5-methylfurfural | 0.42 | 2.45 | ||
2(5H)呋喃酮2(5H)-furanone | 1.11 | 1.27 | ||
玉米秸秆 corn straw | 醛类 aldehyde | 多聚甲醛paraformaldehyde | — | 0.58 |
二乙醇缩甲醛diethoxy methane | — | 1.93 | ||
呋喃类 furan | 糠醛furfural | 5.54 | 29.30 | |
糠醇furanmethanol | 2.96 | — | ||
5-甲基糠醛5-methylfurfural | 0.96 | 3.54 | ||
5-羟甲基糠醛5-hydroxymethylfurfural | 3.38 | — | ||
2(5H)呋喃酮2(5H)-furanone | 1.01 | 2.55 | ||
樟木粉 camphor wood powder | 醛类 aldehyde | 多聚甲醛paraformaldehyde | 0.97 | 1.57 |
二乙醇缩甲醛diethoxy methane | — | 3.92 | ||
4-羟基-3, 5-二甲氧基-苯甲醛syringaldehyde | 1.11 | — | ||
呋喃类 furan | 糠醛furfural | 4.46 | 46.22 | |
糠醇furanmethanol | 1.55 | — | ||
5-甲基糠醛5-methylfurfural | 0.33 | 4.65 | ||
5-羟甲基糠醛5-hydroxymethylfurfural | 0.59 | — |
Table 4
The contents of high value-added chemicals in bio-oil of different materials %"
原料samples | 多聚甲醛 paraformaldehydel | 糠醛furfural | 5-甲基糠醛5-methylfurfural | |||||
无催化剂 catalyst-free | ZnCl2 | 无催化剂 catalyst-free | ZnCl2 | 无催化剂 catalyst-free | ZnCl2 | |||
油菜秸秆rape straw | 0.16 | 0.11 | 0.98 | 5.59 | 0.11 | 0.46 | ||
玉米秸秆corn straw | — | 0.07 | 1.37 | 5.67 | 0.23 | 0.69 | ||
樟木粉camphor wood powder | 0.35 | 0.24 | 1.61 | 7.10 | 0.23 | 0.72 |
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