脱氢枞酸三芳胺基D-π-A型荧光化合物的光谱性能及应用

doi:10.3969/j.issn.0253-2417.2020.04.011

Abstract

Abstract:

Dehydroabietic acid-based triarylamine(b) was synthesized via esterification, bromination, and C-N coupling, using dehydroabietic acid as starting material, then a D-π-A type compound (DTPA-I) with dehydroabietic acid-based triarylamine was synthesized by bromination, and C-C coupling. The ultraviolet absorption spectrum and fluorescence emission spectrum of DTPA-I were studied and it was also used as fluorescent probe to detect the water content in polar organic solvents. The results showed that compound DTPA-I showed a new absorption peak with the maximum adsorption wavelength of 474 nm in the UV absorption spectrum and its maximum wavelength of fluorescence emission red-shifted from 374 to 603 nm, compared with compound b; the maximum absorption wavelength and fluorescence emission wavelength of DTPA-I in different polar solvents had big shift, and the absorbance and fluorescence intensity were also different, which indicated the compound had significant solvatochromism effect. When DTPA-I was used as fluorescent probe to detect water content in solvents dioxane, DMSO and DMF, the fluorescence intensity of DTPA-I linearly decreased with the increase of concentration of water in solvents.The detection limit for water content in dioxane was as low as 0.089%.

Key words: dehydroabietic acid-based triarylamine, D-π-A compound, solvatochromism, detection

CLC Number:

TQ351
O657.3

Yanan GAO,Hong GAO,Shibin SHANG,Zhanqian SONG. Spectra Properities and Application of Dehydroabietic Acid Triarylamine Based D-π-A Type Fluorescent Compound[J]. Chemistry and Industry of Forest Products, 2020, 40(4): 79-85.

Figures/Tables 6

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Spectra Properities and Application of Dehydroabietic Acid Triarylamine Based D-π-A Type Fluorescent Compound

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