烯丙基酯型腰果酚光固化单体的合成与性能研究

doi:10.3969/j.issn.0253-2417.2020.05.005

Abstract

Abstract:

The type-I cardanol with allyl ester group(GMA-C) was synthesized by the reaction of cardanol and glycidyl methacrylate(GMA), and further reacted with methacrylic anhydride(MAA) to prepare the type-II cardanol with allyl ester group (MAA-GMA-C). The chemical structure of the products were characterized by FT-IR, ¹H NMR and ¹³C NMR. The UV curing properties of the prouducts, mechanical properties and chemical resistance of the cured film were investigated. The results showed that the cardanols with allyl ester group could be cured under UV irradiation for 40 s, the pencil hardness of the film could reach 4H, the adhesion force could reach grade two, and the cured film had better properties of water resistance, ethanol tolerance and acid resistance.

Key words: cardanol, glycidyl methacrylate, UV curing, synthesis, property

CLC Number:

TQ35

Jian CHEN,Guomin WU,Shuping HUO,Zhenwu KONG. Synthesis and Properties of Photocurable Monomers from Cardanol with Allyl Ester Group[J]. Chemistry and Industry of Forest Products, 2020, 40(5): 34-42.

Figures/Tables 11

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References 19

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样品 samples	羟值/(mg·g^-1) hydroxyl value	碘值/(g·g^-1) iodine value	黏度/(mPa·s，25 ℃) viscosity	物理性质 physical properties
甲基丙烯酸缩水甘油酯GMA	—	1.77	6	无色透明液体colorless transparent liquid
腰果酚cardanol	201	2.60	65	棕灰色液体brown-grey liquid
烯丙基酯-Ⅰ型腰果酚GMA-C	140	1.29	300	酒红色透明液体claret transparent liquid
烯丙基酯-Ⅱ型腰果酚MAA-GMA-C	20	1.04	240	酒红色透明液体claret transparent liquid

编号 No.	单体 monomer	辐照时间/s irradiation time	铅笔硬度 pencil hardness	附着力/级 adhesion/grade	柔韧性/mm flexibility	抗冲击强度impact strength/cm
编号 No.	单体 monomer	辐照时间/s irradiation time	铅笔硬度 pencil hardness	附着力/级 adhesion/grade	柔韧性/mm flexibility	正冲 square impact	反冲 reverse impact
A1	GMA-C	40	＜2B	1	0.5	＞50	＞50
A2	GMA-C	50	＜2B	1	0.5	＞50	＞50
A3	GMA-C	60	B	1	0.5	＞50	＞50
A4	GMA-C	70	B	1	0.5	＞50	＞50
A5	GMA-C	80	F	1	0.5	＞50	＞50
A6	GMA-C	90	F	1	0.5	＞50	＞50
A7	GMA-C	120	H	1	0.5	＞50	＞50
A8	GMA-C	180	2H	1	0.5	＞50	＞50
B1	MAA-GMA-C	40	B	＞7	15	5	5
B2	MAA-GMA-C	50	F	＞7	15	5	5
B3	MAA-GMA-C	60	H	7	15	5	5
B4	MAA-GMA-C	70	H	7	15	5	5
B5	MAA-GMA-C	80	H	4	10	5	5
B6	MAA-GMA-C	90	2H	3	10	5	5
B7	MAA-GMA-C	120	2H	2	10	5	5
B8	MAA-GMA-C	180	4H	2	5	5	5

试剂 reagent	浸泡时间 soaking time	GMA-C	MAA-GMA-C
H₂O	7 d	+	+
无水乙醇ethanol	7 d	+	+
5% NaCl	7 d	+	+
10% HCl	3 d	+	+
10% H₂SO₄	3 d	+	+
10% NaOH	3 h	-	-

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Synthesis and Properties of Photocurable Monomers from Cardanol with Allyl Ester Group

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