非酶法催化木质纤维原料转化制备低聚木糖研究进展

doi:10.3969/j.issn.0253-2417.2020.06.015

Abstract

Abstract:

Xylo-oligosaccharides(XOS), as one of the most effective prebiotics, are widely applied in medicine and health production, food additive, pet food and feed, etc. The production of XOS by enzymatic hydrolysis has the disadvantages of low efficiency, long production cycle and high cost, which is difficult for large-scale industrial production. Therefore, non-enzymatic production of XOS has become a hot spot in recent years. This paper introduced the chemical structure, physicochemical properties and biological properties of XOS. Then, the process, technological characteristics, XOS yield and relative merits of non-enzymatic catalysis methods(such as acid hydrolysis, steam explosion, autohydrolysis, subcritical CO₂ and inorganic salt treatment) were systematically summarized. Finally, the suggestions for future research on XOS were provided based on the understanding of problems existing in the current research.

Key words: xylo-oligosaccharides, lignocellulosic materials, prebiotics, industrial scale, non-enzymatic methods

CLC Number:

TQ35

Weiwei ZHANG, Bo ZHANG, Leping ZHANG, Jianxin JIANG. Progress on Production of Xylo-oligosaccharides from Lignocellulosic Materials by Non-enzymatic Catalysis[J]. Chemistry and Industry of Forest Products, 2020, 40(6): 118-128.

Figures/Tables 5

Table 1

Table 2

Fig.1

Table 3

Fig.2

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原料 raw material	酸 acid	温度/℃ temp	时间/min time	XOS/ %	木糖/% xylose	糠醛/(g·L^-1) furfural	5-HMF/ (g·L^-1)	文献 reference
玉米芯 corncob	玉米芯 corncob	150	30	22.54	11.39	0.97	0.28	[53]
玉米芯 corncob	玉米芯 corncob	150	30	9.38	4.10	0.09	0.05	[53]
甘蔗渣 sugarcane bagasse	甘蔗渣 sugarcane bagasse	145	60	22.77	1.12	0.02	0.01	[63]
玉米芯 corncob	玉米芯 corncob	140	60	17.52	0.70			[64]
玉米芯 corncob	玉米芯 corncob	150	60	34.42	6.00			[64]
玉米芯 corncob	玉米芯 corncob	160	60	38.30	11.85			[64]
甘蔗渣 sugarcane bagasse	甘蔗渣 sugarcane bagasse	150	30	39.10	7.88	0.46	0.09	[66]
杨树锯屑 poplar sawdust	杨树锯屑 poplar sawdust	170	30	37.60	19.19	0.26		[67]
玉米芯 corncob	玉米芯 corncob	154	47	56.20	17.44			[69]
玉米芯 corncob	玉米芯 corncob	145	75	54.16	22.31	0.23	0.24	[70]

原料 raw material	温度/℃ temp.	时间/min time	总XOS/% total XOS	XOS(D_P 2-5)/ %	木糖/% xylose	糠醛/(g·L^-1) furfural	文献 reference
竹子 bamboo	180	30	47.49	19.16	4.79	0.36	[74]
榛子壳 hazelnut shell	190	5	62	10	4.10		[26]
甘蔗渣 sugarcane bagasse	180	10	30.86	9.13	0.08		[10]
甘蔗渣 sugarcane bagasse	200	10	51.28	50.35	14.59		[10]

原料 raw material	温度/℃ temp.	时间/min time	CO₂压力/MPa CO₂ pressure	XOS/% XOS	木糖/% xylose	糠醛/(g·L^-1) furfural	文献 reference
开心果壳pistachio	182		5	65.0	2.4	0.3	[51]
玉米秸秆corn straw	170	40	5	44.40	4.8	0.34	[57]
甘蔗渣sugarcane bagasse	160	60	5	51.01	8.41	1.21	[75]
小麦秸秆wheat straw	210	1.74	6	70.6	16.1	3.2	[76]

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Progress on Production of Xylo-oligosaccharides from Lignocellulosic Materials by Non-enzymatic Catalysis

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