Chemistry and Industry of Forest Products ›› 2021, Vol. 41 ›› Issue (1): 85-92.doi: 10.3969/j.issn.0253-2417.2021.01.012
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Keming ZHU1,2(), Dechao WANG3, Yongfeng ZHU3, Wenbin LI1,2, Yunwu ZHENG1,2, Zhifeng ZHENG3,*()
Received:
2020-06-29
Online:
2021-02-28
Published:
2021-03-03
Contact:
Zhifeng ZHENG
E-mail:zhukm1739@163.com;zhifeng.zheng@xmu.edu.cn
CLC Number:
Keming ZHU, Dechao WANG, Yongfeng ZHU, Wenbin LI, Yunwu ZHENG, Zhifeng ZHENG. Catalytic Upgrading of Cellulose Pyrolysis Vapor for Furan Compounds[J]. Chemistry and Industry of Forest Products, 2021, 41(1): 85-92.
Table 2
Elemental analysis of catalysts"
催化剂 catalysts | 质量分数mass fraction/% | 原子百分比atomic percentage/% | |||||||||||
O | Na | Al | Si | Co | Sn | O | Na | Al | Si | Co | Sn | ||
NaY | 45.47 | 8.85 | 11.79 | 33.88 | — | — | 58.36 | 7.90 | 8.97 | 24.77 | — | — | |
Co/NaY | 53.44 | 5.18 | 8.74 | 25.14 | 7.49 | — | 68.00 | 4.59 | 6.60 | 18.22 | 2.59 | — | |
Sn/NaY | 55.11 | 3.81 | 8.45 | 24.18 | — | 8.45 | 70.94 | 3.42 | 6.45 | 17.73 | — | 1.47 | |
Co-Sn/NaY | 53.81 | 3.33 | 8.01 | 22.28 | 4.00 | 8.57 | 70.98 | 3.06 | 6.26 | 16.74 | 1.43 | 1.52 |
Table 3
Distribution of cellulose pyrolysis products obtained with different catalysts %"
催化剂 catalysts | 呋喃类 furans | 酮类 ketones | 醛类 aldehydes | 醇类 alcohols | 酸类 acids | 酯类 esters | 糖类 saccharides | 碳氢化合物 hydro carbon | 其他 others |
无 | 15.34 | 5.35 | 1.13 | 2.03 | 9.71 | 0 | 58.97 | 1.52 | 5.95 |
MnCo2O4 | 17.10 | 5.38 | 2.16 | 10.32 | 13.79 | 0 | 29.20 | — | 22.05 |
OMS-2 | 0 | 0 | 3.46 | 6.56 | 77.16 | 3.91 | 0 | — | 8.91 |
NaY | 48.16 | 1.16 | 2.89 | 8.58 | 24.40 | 0 | 0 | 12.09 | 2.72 |
Table 4
Product distribution of cellulose and NaY in different proportions %"
纤维素与NaY的质量比 mass ratio of cellulose to NaY | 呋喃类 furans | 酮类 ketones | 醛类 aldehydes | 醇类 alcohols | 酸类 acids | 糖类 saccharides | 碳氢化合物 hydrocarbon | 其他 others |
1:6 | 38.19 | 9.92 | 2.52 | 5.35 | 0.38 | 21.54 | 2.78 | 19.34 |
1:10 | 41.70 | 1.27 | 4.72 | 1.64 | 9.01 | 0 | 6.38 | 35.30 |
1:14 | 48.16 | 1.14 | 2.89 | 8.58 | 24.40 | 0 | 12.09 | 2.72 |
1:18 | 24.50 | 2.01 | 0.70 | 9.26 | 18.49 | 0 | 10.01 | 29.95 |
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