纳米纤维素疏水改性的研究进展

doi:10.3969/j.issn.0253-2417.2021.03.016

Abstract

Abstract:

Nanocellulose is a kind of nano-sized cellulose extracted from natural cellulose. It not only has the basic characteristics of cellulose, but also has large specific surface area, unique strength and optical properties originated from nano-size. However, the presence of free hydroxyl groups in cellulose is hydrophilic, which reduces the stiffness of nanocellulose materials in humid environments and limits its application fields. Therefore, hydrophobic modification of nanocellulose can expand its scope of application. This article reviewed the methods of hydrophobic modification of nanocellulose in recent years, including physical adsorption modification, esterification/acetylation modification, graft copolymerization, silane coupling agent modification, etc., and summarized the research results of the above methods, as well as the advantages and disadvantages. And the future development direction was prospected in order to provide reference for hydrophobic modification research.

Key words: nanocellulose, hydrophobic modification, esterification, graft copolymerization

CLC Number:

TQ35
TS721

Lingyuan WANG, Lanfeng HUI. Research Progress of Hydrophobic Modification of Nanocellulose[J]. Chemistry and Industry of Forest Products, 2021, 41(3): 125-133.

Figures/Tables 7

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References 53

1	ABITBOL T , RIVKIN A , CAO Y , et al. Nanocellulose, a tiny fiber with huge applications[J]. Current Opinion in Biotechnology, 2016, 39, 76- 88. doi: 10.1016/j.copbio.2016.01.002
2	HEATH L , THIELEMANS W . Cellulose nanowhisker aerogels[J]. Green Chemistry, 2010, 12 (8): 1448- 1453. doi: 10.1039/c0gc00035c
3	任新乐, 赵书乾, 王建泽, 等. 纳米纤维素在食品包装中的应用[J]. 齐鲁工业大学学报, 2020, 34 (2): 13- 18.
	REN X L , ZHAO S Q , WANG J Z , et al. Application of nanocellulose fibers in food packaging[J]. Journal of Qilu University of Technology, 2020, 34 (2): 13- 18.
4	FIGUEIREDO A , EVTUGUIN D , SARAIVA J . Effect ofhighpressure treatment on structure and properties of cellulose in eucalypt pulps[J]. Cellulose, 2010, 17 (6): 1193- 1202. doi: 10.1007/s10570-010-9454-2
5	MISSOUM K , BELGACEM M N , BRAS J . Nanofibrillated cellulose surface modification: A Review[J]. Materials, 2013, 6 (5): 1745- 1766. doi: 10.3390/ma6051745
6	SAITO T , KIMURA S , NISHIYAMA Y , et al. Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose[J]. Biomacromolecules, 2007, 8 (8): 2485- 2491. doi: 10.1021/bm0703970
7	ROL F , BELGACEM M N , GANDINI A , et al. Recent advances in surface-modified cellulose nanofibrils[J]. Progress in Polymer Science, 2019, 88, 241- 264. doi: 10.1016/j.progpolymsci.2018.09.002
8	SAKAKIBARA K , YANO H , TSUJII Y . Surface engineering of cellulose nanofiber by adsorption of diblock copolymer dispersant for green nanocomposite materials[J]. ACS Applied Materials & Interfaces, 2016, 8 (37): 24893- 24900.
9	LOZHECHNIKOVA A , DAX D , VARTIAINEN J , et al. Modification of nanofibrillated cellulose using amphiphilic block-structured galactoglucomannans[J]. Carbohydrate Polymers, 2014, 110, 163- 172. doi: 10.1016/j.carbpol.2014.03.087
10	KONTTURI K S , BIEGAJ K W , MAUTNER A , et al. Noncovalent surface modification of cellulose nanopapers by adsorption of polymers from aprotic solvents[J]. Langmuir, 2017, 33 (23): 5707- 5712. doi: 10.1021/acs.langmuir.7b01236
11	SYVERUD K , XHANARI K , CHINGA-CARRASCO G , et al. Films made of cellulose nanofibrils: surface modification by adsorption of a cationic surfactant and characterization by computer-assisted electron microscopy[J]. Journal of Nanoparticle Research, 2010, 13 (2): 773- 782.
12	XHANARI K , SYVERUD K , CHINGA-CARRASCO G , et al. Reduction of water wettability of nanofibrillated cellulose by adsorption of cationic surfactants[J]. Cellulose, 2011, 18 (2): 257- 270. doi: 10.1007/s10570-010-9482-y
13	SOUZA A G D , LIMA G F D , COLOMBO R , et al. A new approach for the use of anionic surfactants: Nanocellulose modification and development of biodegradable nanocomposites[J]. Cellulose, 2020, 27 (10): 5707- 5728. doi: 10.1007/s10570-020-03160-3
14	HABIBI Y . Key advances in the chemical modification of nanocelluloses[J]. Chemical Society Reviews, 2014, 45 (20): 1519- 1542.
15	YAN Y , AMER H , ROSENAU T , et al. Dry, hydrophobic microfibrillated cellulose powder obtained in a simple procedure using alkyl ketene dimer[J]. Cellulose, 2016, 23 (2): 1189- 1197. doi: 10.1007/s10570-016-0887-0
16	SHIMIZU M , SAITO T , FUKUZUMI H , et al. Hydrophobic, ductile, and transparent nanocellulose films with quaternary alkylammonium carboxylates on nanofibril surfaces[J]. Biomacromolecules, 2014, 15 (11): 4320- 4325. doi: 10.1021/bm501329v
17	SHIMIZU M , SAITO T , ISOGAI A . Water-resistant and high oxygen-barrier nanocellulose films with interfibrillar cross-linkages formed through multivalent metal ions[J]. Journal of Membrane Science, 2016, 500, 1- 7. doi: 10.1016/j.memsci.2015.11.002
18	LI M C , MEI C , XU X , et al. Cationic surface modification of cellulose nanocrystals: Toward tailoring dispersion and interface in carboxymethyl cellulose films[J]. Polymer, 2016, 107, 200- 210. doi: 10.1016/j.polymer.2016.11.022
19	杨爽, 柴新宇, 聂双喜, 等. 纳米纤维素的疏水性及分散性研究进展[J]. 中国造纸, 2017, 36 (10): 61- 67. doi: 10.11980/j.issn.0254-508X.2017.10.012
	YANG S , CHAI X Y , NIE S X , et al. Research progress on improving dispersibility and hydrophobicity of nanocellulose[J]. China Pulp & Paper, 2017, 36 (10): 61- 67. doi: 10.11980/j.issn.0254-508X.2017.10.012
20	位浩, 刘飞, 王锦文, 等. 纤维素纳米纸的疏水改性及应用研究[J]. 材料科学与工艺, 2019, 27 (4): 30- 41.
	WEI H , LIU F , WANG J W , et al. Hydrophobic modification and application of cellulose nanopaper[J]. Materials Science and Technology, 2019, 27 (4): 30- 41.
21	MULYADI A , DENG Y . Surface modification of cellulose nanofibrils by maleated styrene block copolymer and their composite reinforcement application[J]. Cellulose, 2016, 23 (1): 519- 528. doi: 10.1007/s10570-015-0787-8
22	HU W , CHEN S , XU Q , et al. Solvent-free acetylation of bacterial cellulose under moderate conditions[J]. Carbohydrate Polymers, 2011, 83 (4): 1575- 1581. doi: 10.1016/j.carbpol.2010.10.016
23	MASHKOUR M , AFRA E , RESALATI H , et al. Moderate surface acetylation of nanofibrillated cellulose for the improvement of paper strength and barrier properties[J]. RSC Advances, 2015, 5 (74): 60179- 60187. doi: 10.1039/C5RA08161K
24	SETHI J , FAROOQ M , SAIN S , et al. Water resistant nanopapers prepared by lactic acid modified cellulose nanofibers[J]. Cellulose, 2018, (7): 1- 10.
25	ZHOU X , LIN X , WHITE K L , et al. Effect of the degree of substitution on the hydrophobicity of acetylated cellulose for production of liquid marbles[J]. Cellulose, 2016, 23 (1): 811- 821. doi: 10.1007/s10570-015-0856-z
26	SINGH M , KAUSHIK A , AHUJA D , et al. Surface functionalization of nanofibrillated cellulose extracted from wheat straw: Effect of process parameters[J]. Carbohydrate Polymers, 2016, 150, 48- 56. doi: 10.1016/j.carbpol.2016.04.109
27	HUANG F , WU X , YU Y , et al . Acylation of cellulose nanocrystals with acids/trifluoroacetic anhydride and properties of films from esters of CNCs[J]. Carbohydrate Polymers, 2017, 155, 525- 534. doi: 10.1016/j.carbpol.2016.09.010
28	YAGYU H, IFUKU S, NOGI M.Acetylation of optically transparent cellulose nanopaper for high thermal and moisture resistance in a flexible device substrate[J/OL]. Flexible & Printed Electronics, 2017, 2(1): 1-7[2020-01-04].https://doi.org/10.1088/2058-8585/aa60f4.
29	YU H , ZHANG S , WANG Y , et al. Covalent modification of nanocellulose(NCC) by functionalized graphene oxide(GO) and the study of adsorption mechanism[J]. Composite Interfaces, 2020, (1): 1- 14.
30	ODIAN G G . Principles of Polymerization[M]. NewYork: McGraw-Hill Book Companies, 2004: 535- 593.
31	ROY D , SEMSARILAR M , GUTHRIE J T , et al. Cellulose modification by polymer grafting: A review[J]. Chemical Society Reviews, 2009, 38 (7): 2046- 2064. doi: 10.1039/b808639g
32	TIAN C , FU S Y , MENG Q J , et al. New insights into the material chemistry of polycaprolactone-grafted cellulose nanofibrils/polyurethane nanocomposites[J]. Cellulose, 2016, 23 (4): 2457- 2473. doi: 10.1007/s10570-016-0980-4
33	STENSTAD P , ANDRESEN M , TANEM B S , et al. Chemical surface modifications of microfibrillated cellulose[J]. Cellulose, 2008, 15 (1): 35- 45. doi: 10.1007/s10570-007-9143-y
34	AHMADI M , BEHZAD T , BAGHERI R , et al. Topochemistry of cellulose nanofibers resulting from molecular and polymer grafting[J]. Cellulose, 2017, 24 (5): 2139- 2152. doi: 10.1007/s10570-017-1254-5
35	邱素艳, 高森, 林振宇, 等. 点击化学最新进展[J]. 化学进展, 2011, 23 (4): 637- 648.
	QIU S Y , GAO S , LIN Z Y , et al. Advances in click chemistry[J]. Progress in Chemistry, 2011, 23 (4): 637- 648.
36	KEMPE K , KRIEG A , BECER C R , et al. "Clicking" on/with polymers: A rapidly expanding field for the straightforward preparation of novel macromolecular architectures[J]. Chemical Society Reviews, 2012, 41 (1): 176- 191. doi: 10.1039/C1CS15107J
37	BENKADDOUR A , JRADI K , ROBERT S , et al. Study of the effect of grafting method on surface polarity of tempo-oxidized nanocellulose using polycaprolactone as the modifying compound: Esterification versus click-chemistry[J]. Nanomaterials, 2013, 3 (4): 638- 654. doi: 10.3390/nano3040638
38	ZHOU L , HE H , LI M , et al. Grafting polycaprolactone diol onto cellulose nanocrystals via click chemistry: Enhancing thermal stability and hydrophobic property[J]. Carbohydrate Polymers, 2018, 189, 331- 341. doi: 10.1016/j.carbpol.2018.02.039
39	NONGBE M C , BRETEL G , EKOU L , et al. Cellulose paper azide as a molecular platform for versatile click ligations: Application to the preparation of hydrophobic paper surface[J]. Cellulose, 2018, 25, 1395- 1411. doi: 10.1007/s10570-017-1647-5
40	SHARMA C, BHARDWAJ N K, PATHAK P.Static intermittent fed-batch production of bacterial nanocellulose from black tea and its modification using chitosan to develop antibacterial green packaging material[J/OL]. Journal of Cleaner Production, 2021, 279: 1-20[2020-01-04].https://doi.org/10.1016/j.jclepro.2020.123608.
41	LIANG J, WANG R, CHEN R.The impact of cross-linking mode on the physical and antimicrobial properties of a chitosan/bacterial cellulose composite[J/OL]. Polymers, 2019, 11(3): 1-15[2020-03-03].https://doi.org/10.3390/polym11030491.
42	何文, 李吉平, 金辉, 等. 毛竹纳米纤维素的烷基化改性[J]. 南京林业大学学报(自然科学版), 2016, 40 (2): 144- 148.
	HE W , LI J P , JIN H , et al. Research on the alkylation modification of cellulose nanofiber separated from moso bamboo[J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2016, 40 (2): 144- 148.
43	KHALIL H P S A , BHAT A H , YUSRA A F I . Green composites from sustainable cellulose nanofibrils: A review[J]. Carbohydrate Polymers, 2012, 87 (2): 963- 979. doi: 10.1016/j.carbpol.2011.08.078
44	GOUSSÉ C , CHANZY H , EXCOFFIER G , et al. Stable suspensions of partially silylated cellulose whiskers dispersed in organic solvents[J]. Polymer, 2002, 43 (9): 2645- 2651. doi: 10.1016/S0032-3861(02)00051-4
45	郑闪闪, 杭建忠, 孙小英, 等. 苯基三甲氧基硅烷改性纳米纤维素纸基阻隔涂层的制备及性能[J]. 高分子材料科学与工程, 2020, 36 (3): 120- 125.
	ZHENG S S , HANG J Z , SUN X Y , et al. Preparation and properties of phenyltrimethoxysilane modified nano-cellulose paper-based barrier coating[J]. Polymer Materials Science &Engineering, 2020, 36 (3): 120- 125.
46	LU J , ASKELAND P , DRZAL L T , et al. Surface modification of microfibrillated cellulose for epoxy composite applications[J]. Polymer, 2008, 49 (5): 1285- 1296. doi: 10.1016/j.polymer.2008.01.028
47	KHANJANZADEH H , BEHROOZ R , BAHRAMIFAR N , et al. Corrigendum to "Surface chemical functionalization of cellulose nanocrystals by 3-aminopropyltriethoxysilane"[J]. International Journal of Biological Macromolecules, 2018, 106, 1288- 1296. doi: 10.1016/j.ijbiomac.2017.08.136
48	ANDRESEN M , JOHANSSON L S , TANEM B S , et al. Properties and characterization of hydrophobized microfibrillated cellulose[J]. Cellulose, 2006, 13 (6): 665- 677. doi: 10.1007/s10570-006-9072-1
49	XHANARI K , SYVERUD K , STENIUS P , et al. Emulsions stabilized by microfibrillated cellulose: The effect ofhydrophobization, concentration and O/W ratio[J]. Journal of Dispersion Science and Technology, 2011, 32 (3): 447- 452. doi: 10.1080/01932691003658942
50	ZHOU T, WEI H, TAN H, et al.Strongly anisotropic thermal conductivity and adequate breathability of bilayered films for heat management of on-skin electronics[J/OL]. 2D Materials, 2018, 5(3): 1-28[2020-03-03].https://doi.org/10.1088/2053-1583/aabc19.
51	CHEN S , SONG Y , XU F , et al. Highly transparent and hazy cellulose nanopaper simultaneously with a self-cleaning superhydrophobic surface[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (4): 5173- 5181.
52	HU D C , MA W S , ZHANG Z L , et al. Dual bio-inspired design of highly thermally conductive and superhydrophobic nanocellulose composite films[J]. ACS Applied Materials & Interfaces, 2020, 12 (9): 11115- 11125.
53	KAHAVITA K D H N , SAMARASEKARA A M P B , AMARASINGHE D A S , et al. Nanofibrillated cellulose reinforced polypropylene composites: Influence of silane(SI-69) surface modification[J]. Cellulose Chemistry and Technology, 2020, 54 (7/8): 789- 797.

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Research Progress of Hydrophobic Modification of Nanocellulose

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