Chemistry and Industry of Forest Products ›› 2021, Vol. 41 ›› Issue (4): 124-134.doi: 10.3969/j.issn.0253-2417.2021.04.016
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Received:
2020-08-14
Online:
2021-08-28
Published:
2021-08-31
Contact:
Ting WANG
E-mail:thundersking@nefu.edu.cn
CLC Number:
Mengzhu LI, Ting WANG. Research Progress in Inhibiting Repolymerization of Lignin Degradation Intermediates[J]. Chemistry and Industry of Forest Products, 2021, 41(4): 124-134.
Table 1
Several supercritical organic solvents commonly used for lignin depolymerization"
超临界溶剂 supercritical solvent | 催化剂1) catalyst | 条件 conditions | 底物 substrate | 产品(产量) products(yield) | 参考文献 references |
甲醇methanol | Cu20La20PMO | 310 ℃,6 h | 桐树木质素 candlenut lignin | 生物油bio-oil (98%) | [ |
Ag掺杂的Mn2O3纳米片 Ag-doped Mn2O3 nanosheets | 180 ℃,2 h | 碱性木质素 alkali lignin | 液态乙醇liquid alcohols (42.5%) | [ | |
Fe3+,H2O2 | 250 ℃,3 h 6.5 MPa | 甜高粱渣木质素 sweet sorghum bagasse lignin | 酚醛树脂phenolic oil (75.85%) | [ | |
乙醇ethanol | Ru/C,Ni/ZSM-5,CuNiAl | 290 ℃,3 h | 碱性木质素 alkali lignin | 生物油bio-oil (81.8%) | [ |
WO3/γ-Al2O3 | 320 ℃,8 h | 酶解木质素 enzymatic hydrolysis lignin | 烷基酚alkylphenols (86.9%) | [ | |
Ru/C-MgO-ZrO2 | 320 ℃,4 h, 3 MPa-H2 | 有机溶剂木质素 organosolv lignin | 生物油bio-oil (76.2%), 酚类单体phenolic monomer(31.44%) | [ | |
丙酮acetone | 甲酸 formic acid | 300-370 ℃,10 MPa | 硬木hardwood, 麦秆木质素 wheat straw lignin | 丁香酚syringol (3.6%), 丁香酸syringic acid (2.0%) | [ |
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