Chemistry and Industry of Forest Products ›› 2022, Vol. 42 ›› Issue (1): 131-138.doi: 10.3969/j.issn.0253-2417.2022.01.017
Xinglong HOU1,2, Wei XU1, Junli LIU1,*()
Received:
2020-12-06
Online:
2022-02-28
Published:
2022-03-11
Contact:
Junli LIU
E-mail:liujunli1974@126.com
CLC Number:
Xinglong HOU, Wei XU, Junli LIU. Research Progress in Preparation and Application of Lignin-based Porous Carbon Materials[J]. Chemistry and Industry of Forest Products, 2022, 42(1): 131-138.
Table 1
Pore structure of activated carbon with different lignin"
制备方法 preparation method | 原料 lignin | 活化剂 activator | 制备条件1) conditions | 比表面积/(m2·g-1) specific surface area | 微孔孔容/ (cm3·g-1) micropore volume | 参考文献 reference |
物理活化法 physical activation | 桉树硫酸盐木质素 eucalyptus kraft lignin | CO2 | C: 350 ℃, 2 h; A: 850 ℃, 20 h | 1853 | 0.57 | [ |
水解木质素 hydrolytic lignin | H2O | C: 600 ℃, 2 h; A: 800 ℃, 2 h | 865 | 0.365 | [ | |
化学活化法 chemical activation | 桉树硫酸盐木质素 eucalyptus kraft lignin | ZnCl2 | A: 500 ℃, 1 h, 1∶2.3* | 1800 | 1.039 | [ |
桉树硫酸盐木质素 eucalyptus kraft lignin | H3PO4 | A: 427 ℃, 2 h, 1∶2* | 1459 | 0.82 | [ | |
水解木质素 hydrolytic lignin | KOH | A: 850 ℃, 15 min, 1∶4* | 2753 | 1.37 | [ |
1 | 范娟, 詹怀宇, 刘明华. 木质素基吸附材料的研究进展[J]. 中国造纸学报, 2004, (2): 186- 192. |
FAN J , ZHAN H Y , ZHANG M H . Research progress of lignin-based adsorption materials[J]. Transactions of China Pulp and Paper, 2004, (2): 186- 192. | |
2 | 张桂梅, 廖双泉, 蔺海兰, 等. 木质素的提取方法及综合利用研究进展[J]. 热带农业科学, 2005, (1): 70- 74, 80. |
ZHANG G M , LIAO S Q , LIN H L , et al. Progress in studying the extraction and comprehensive utilization of lignin[J]. Chinese Journal of Tropical Agriculture, 2005, (1): 70- 74, 80. | |
3 | 徐若愚, 张静, 龚方红. 酸木质素改性酚醛树脂胶粘剂的研究[J]. 林业实用技术, 2011, (11): 60- 62. |
XU R Y , ZHANG J , GONG F H . Study on acid lignin modified phenolic resin adhesive[J]. Forest Science and Technology, 2011, (11): 60- 62. | |
4 | 陈慧泉, 龚运淮, 方舟. 天然高分子物质的利用现状和前景(Ⅰ)——纤维素、木质素和淀粉[J]. 云南化工, 1996, (1): 41- 46, 56. |
CHEN H Q , GONG Y H , FANG Z . The situation and aspect of application for macromolecule(I): Cellulose, lignin and starch[J]. Yunnan Chemical Technology, 1996, (1): 41- 46, 56. | |
5 | 张芝兰, 陆雍森. 木质素混凝剂的性质及其应用研究[J]. 水处理技术, 1997, (1): 40- 46. |
ZHAGN L Z , LU Y S . Properties and application of lignin coagulant[J]. Technology of Water Treatment, 1997, (1): 40- 46. | |
6 | 巨敏, 翁彩珠, 刘军海. 木质素在农业中的应用[J]. 现代农业, 2011, (1): 27- 28. |
JU M , WENG C Z , LIU J H . Application of lignin in agriculture[J]. Modern Agriculture, 2011, (1): 27- 28. | |
7 | 蒋莉, 马飞, 梁国斌, 等. 木质素活性炭的制备及工艺优化[J]. 新型炭材料, 2011, (5): 80- 84. |
JIANG L , MA F , LIANG G B , et al. Preparation and process optimization of lignin activated carbon[J]. New Carbon Materials, 2011, (5): 80- 84. | |
8 |
SUPANCHAIYAMAT N , JETSRISUPARB K , KNIJNENBURG J T N . Lignin materials for adsorption: Current trend, perspectives and opportunities[J]. Bioresource Technology, 2019, 272, 570- 581.
doi: 10.1016/j.biortech.2018.09.139 |
9 |
KWIATKOWSKI M , FIERRO V , CELZARD A . Numerical studies of the effects of process conditions on the development of the porous structure of adsorbents prepared by chemical activation of lignin with alkali hydroxides[J]. Journal of Colloid and Interface Science, 2017, 486, 277- 286.
doi: 10.1016/j.jcis.2016.10.003 |
10 | HASSLER J W . Activated Carbon[M]. New York: Chemical Pub.Co, 1963. |
11 |
GERGOVA K , PETROV N , ESER S . Adsorption properties and microstructure of activated carbons produced from agricultural by-products by steam pyrolysis[J]. Carbon, 1994, 32 (4): 693- 702.
doi: 10.1016/0008-6223(94)90091-4 |
12 |
ORFÃO J J M , ANTUNES F J A , FIGUEIREDO J L . Pyrolysis kinetics of lignocellulosic materials: Three independent reactions model[J]. Fuel, 1999, 78 (3): 349- 358.
doi: 10.1016/S0016-2361(98)00156-2 |
13 |
ZANZI R , SJÖSTRÖM K , BJÖRNBOM E . Rapid pyrolysis of agricultural residues at high temperature[J]. Biomass and Bioenergy, 2002, 23 (5): 357- 366.
doi: 10.1016/S0961-9534(02)00061-2 |
14 |
REED A R , WILLIAMS P T . Thermal processing of biomass natural fibre wastes by pyrolysis[J]. International Journal of Energy Research, 2004, 28 (2): 131- 145.
doi: 10.1002/er.956 |
15 | DEL BAGNO V D, MILLER R L, WATKINS J J. On-site production of activated carbon from kraft black liquor: NTIS PB286488[R]. Washington, D.C. : Environmental Protection Agency, 1978. |
16 | RODRÍGUEZ-MIRASOL J , CORDERO T , RODRIGUEZ J J . Activated carbons from carbon dioxide partial gasification of eucalyptus kraft lignin[J]. Energy & Fuels, 1993, 7 (1): 133- 138. |
17 |
BAKLANOVA O N , PLAKSIN G V , DROZDOV V A . Preparation of microporous sorbents from cedar nutshells and hydrolytic lignin[J]. Carbon, 2003, 41 (9): 1793- 1800.
doi: 10.1016/S0008-6223(03)00149-0 |
18 |
XU B , CHEN Y , WEI G . Activated carbon with high capacitance prepared by NaOH activation for supercapacitors[J]. Materials Chemistry and Physics, 2010, 124 (1): 504- 509.
doi: 10.1016/j.matchemphys.2010.07.002 |
19 | JIN X J , YU Z M , WU Y U . Preparation of activated carbon from lignin obtained by straw pulping by KOH and K2CO3 chemical activation[J]. Cellulose Chemistry and Technology, 2012, 46 (1): 79. |
20 |
SUN Y , WEI J , WANG Y S , et al. Production of activated carbon by K2CO3 activation treatment of cornstalk lignin and its performance in removing phenol and subsequent bioregeneration[J]. Environmental Technology, 2010, 31 (1): 53- 61.
doi: 10.1080/09593330903338411 |
21 |
ZAZO J A , BEDIA J , FIERRO C M . Highly stable Fe on activated carbon catalysts for CWPO upon FeCl3 activation of lignin from black liquors[J]. Catalysis Today, 2012, 187 (1): 115- 121.
doi: 10.1016/j.cattod.2011.10.003 |
22 | GONZALEZ-SERRANO E , CORDERO T , RODRÍGUEZ-MIRASOL J . Development of porosity upon chemical activation of kraft lignin with ZnCl2[J]. Industrial & Engineering Chemistry Research, 1997, 36 (11): 4832- 4838. |
23 |
GONZALEZ-SERRANO E , CORDERO T , RODRÍGUEZ-MIRASOL J . Removal of water pollutants with activated carbons prepared from H3PO4 activation of lignin from kraft black liquors[J]. Water Research, 2004, 38 (13): 3043- 3050.
doi: 10.1016/j.watres.2004.04.048 |
24 | ZOU Y , HAN B X . Preparation of activated carbons from Chinese coal and hydrolysis lignin[J]. Adsorption Science & Technology, 2001, 19 (1): 59- 72. |
25 | SUN Y , YANG G , ZHANG J , et al. Activated carbon preparation from lignin by H3PO4 activation and its application to gas separation[J]. Chemical Engineering & Technology, 2012, 35 (2): 309- 316. |
26 |
左宋林. 磷酸活化法制备活性炭综述(Ⅰ)——磷酸的作用机理[J]. 林产化学与工业, 2017, 37 (3): 1- 9.
doi: 10.3969/j.issn.0253-2417.2017.03.001 |
ZUO S . Review on phosphoric acid activation for preparation of activated carbon(Ⅰ): Roles of phosphoric acid[J]. Chemistry and Industry of Forest Products, 2017, 37 (3): 1- 9.
doi: 10.3969/j.issn.0253-2417.2017.03.001 |
|
27 |
MYGLOVETS M , PODDUBNAYA O I , SEVASTYANOVA O . Preparation of carbon adsorbents from lignosulfonate by phosphoric acid activation for the adsorption of metal ions[J]. Carbon, 2014, 80, 771- 783.
doi: 10.1016/j.carbon.2014.09.032 |
28 |
GAO Y , YUE Q , GAO B . Preparation of high surface area-activated carbon from lignin of papermaking black liquor by KOH activation for Ni(II) adsorption[J]. Chemical Engineering Journal, 2013, 217, 345- 353.
doi: 10.1016/j.cej.2012.09.038 |
29 |
RAYMUNDO-PIÑERO E , AZAÏS P , CACCIAGUERRA T . KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation[J]. Carbon, 2005, 43 (4): 786- 795.
doi: 10.1016/j.carbon.2004.11.005 |
30 | 傅凯放. 造纸黑液木质素活性炭的制备、表征及吸附应用[D]. 济南: 山东大学, 2018. |
FU K F. Preparation、characteriazation and application of lignin-based activated carbons from black liquor[D]. Jinan: Shandong University, 2018 | |
31 | KHEZAMI L , CHETOUANI A , TAOUK B . Production and characterisation of activated carbon from wood components in powder: Cellulose, lignin, xylan[J]. Powder Technology, 2005, 157 (1): 48- 56. |
32 |
MARSH H , YAN D S , O'GRADY T M . Formation of active carbons from cokes using potassium hydroxide[J]. Carbon, 1984, 22 (6): 603- 611.
doi: 10.1016/0008-6223(84)90096-4 |
33 |
CARROTT P J M , SUHAS , CARROTT M M L R . Reactivity and porosity development during pyrolysis and physical activation in CO2 or steam of kraft and hydrolytic lignins[J]. Journal of Analytical and Applied Pyrolysis, 2008, 82 (2): 264- 271.
doi: 10.1016/j.jaap.2008.04.004 |
34 | NANDANWAR R A, CHAUDHARI A R, EKHE J D. Thermocatalytic degradation of industrial waste lignin to prepare activated carbon[C]. AIP Conference Proceedings 2104, [S. l. ]: AIP Publishing, 2019: 2104(1): 020025-020025-5. |
35 |
HAYASHI J , KAZEHAYA A , MUROYAMA K . Preparation of activated carbon from lignin by chemical activation[J]. Carbon, 2000, 38 (13): 1873- 1878.
doi: 10.1016/S0008-6223(00)00027-0 |
36 |
SALINAS-TORRES D , RUIZ-ROSAS R , VALERO-ROMERO M J . Asymmetric capacitors using lignin-based hierarchical porous carbons[J]. Journal of Power Sources, 2016, 326, 641- 651.
doi: 10.1016/j.jpowsour.2016.03.096 |
37 |
QIN H , JIAN R , BAI J . Influence of molecular weight on structure and catalytic characteristics of ordered mesoporous carbon derived from lignin[J]. ACS Omega, 2018, 3 (1): 1350- 1356.
doi: 10.1021/acsomega.7b01870 |
38 |
LI H , YUAN D , TANG C . Lignin-derived interconnected hierarchical porous carbon monolith with large areal/volumetric capacitances for supercapacitor[J]. Carbon, 2016, 100, 151- 157.
doi: 10.1016/j.carbon.2015.12.075 |
39 |
SUHAS , CARROTT P J M , RIBEIRO CARROTT M M L . Lignin-from natural adsorbent to activated carbon: A review[J]. Bioresource Technology, 2007, 98 (12): 2301- 2312.
doi: 10.1016/j.biortech.2006.08.008 |
40 | KARSHEVA M I , HRISTOV J Y , NENKOVA S D . Adsorption of lead from aqueous solutions onto technical hydrolyzed lignin[J]. Hungarian Journal of Industrial Chemistry, 2000, 28 (2): 151- 156. |
41 |
WU Y , ZHANG S , GUO X , et al. Adsorption of chromium(III) on lignin[J]. Bioresource Technology, 2008, 99 (16): 7709- 7715.
doi: 10.1016/j.biortech.2008.01.069 |
42 |
MUSSATTO S I , FERNANDES M , ROCHA G J M . Production, characterization and application of activated carbon from brewer's spent grain lignin[J]. Bioresource Technology, 2010, 101 (7): 2450- 2457.
doi: 10.1016/j.biortech.2009.11.025 |
43 |
CHUENCHOM L , KRAEHNERT R , SMARSLY B M . Recent progress in soft-templating of porous carbon materials[J]. Soft Matter, 2012, 8 (42): 10801- 10812.
doi: 10.1039/c2sm07448f |
44 |
FIERRO C M , GÓRKA J , ZAZO J A . Colloidal templating synthesis and adsorption characteristics of microporous-mesoporous carbons from Kraft lignin[J]. Carbon, 2013, 62, 233- 239.
doi: 10.1016/j.carbon.2013.06.012 |
45 |
WICKRAMARATNE N P , JARONIEC M . Phenolic resin-based carbons with ultra-large mesopores prepared in the presence of poly(ethylene oxide)-poly(butylene oxide)-poly(ethylene oxide) triblock copolymer and trimethyl benzene[J]. Carbon, 2013, 51, 45- 51.
doi: 10.1016/j.carbon.2012.08.007 |
46 |
VINU A , MIYAHARA M , SIVAMURUGAN V . Large pore cage type mesoporous carbon, carbon nanocage: A superior adsorbent for biomaterials[J]. Journal of Materials Chemistry, 2005, 15 (48): 5122- 5127.
doi: 10.1039/b507456h |
47 |
ZHUANG X , WAN Y , FENG C . Highly efficient adsorption of bulky dye molecules in wastewater on ordered mesoporous carbons[J]. Chemistry of Materials, 2009, 21 (4): 706- 716.
doi: 10.1021/cm8028577 |
48 | 王程, 曹强, 张玉全, 等. 活性炭材料作为载体的应用进展[J]. 化工新型材料, 2019, (8): 29- 33. |
WANG C , CAO Q , ZHAGN Y Q , et al. Application progress of activated carbon material as carrier[J]. New Chemical Materials, 2019, (8): 29- 33. | |
49 | LI X , LI P , DING D . One-step preparation of Kraft lignin derived mesoporous carbon as solid acid catalyst for fructose conversion to 5-hydroxymethylfurfural[J]. BioResources, 2018, 13 (2): 4428- 4439. |
50 |
LI L , GAO M , LIU J . Removal of airborne microorganisms emitted from a wastewater treatment oxidation ditch by adsorption on activated carbon[J]. Journal of Environmental Sciences, 2011, 23 (5): 711- 717.
doi: 10.1016/S1001-0742(10)60466-4 |
51 |
姜靓, 王静. 生物质碳材料的制备及其应用研究进展[J]. 山东化工, 2018, (16): 81- 82, 84.
doi: 10.3969/j.issn.1008-021X.2018.16.034 |
JIANG L , WANG J . Research progress on preparation and application of biomass carbon materials[J]. Shandong Chemical Industry, 2018, (16): 81- 82, 84.
doi: 10.3969/j.issn.1008-021X.2018.16.034 |
|
52 |
YU B , CHANG Z , WANG C . The key pre-pyrolysis in lignin-based activated carbon preparation for high performance supercapacitors[J]. Materials Chemistry and Physics, 2016, 181, 187- 193.
doi: 10.1016/j.matchemphys.2016.06.048 |
53 |
RUIZ-ROSAS R , VALERO-ROMERO M J , SALINAS-TORRES D , et al. Electrochemical performance of hierarchical porous carbon materials obtained from the infiltration of lignin into zeolite templates[J]. ChemSusChem, 2014, 7 (5): 1458- 1467.
doi: 10.1002/cssc.201301408 |
54 | WU Y , CAO J P , HAO Z Q , et al. One-step preparation of alkaline lignin-based activated carbons with different activating agents for electric double layer capacitor[J]. International Journal of Electrochemical Science, 2017, 12, 7227- 7239. |
55 | 杨芳, 刘晨, 杨绍斌, 等. 用于超级电容器的煤基活性炭电极材料的研究进展[J]. 硅酸盐学报, 2019, 47 (10): 1499- 1508. |
YANG F , LIU C , YANG S B , et al. Research progress on coal-based activated carbon electrode material for supercapacitor[J]. Journal of the Chinese Ceramic Society, 2019, 47 (10): 1499- 1508. |
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