Chemistry and Industry of Forest Products ›› 2022, Vol. 42 ›› Issue (2): 63-70.doi: 10.3969/j.issn.0253-2417.2022.02.009
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Xing LIU, Zhu YIN, Beili LU(), Fengzhen WU, Biao HUANG
Received:
2021-03-04
Online:
2022-04-28
Published:
2022-05-06
Contact:
Beili LU
E-mail:lubl@fafu.edu.cn
CLC Number:
Xing LIU, Zhu YIN, Beili LU, Fengzhen WU, Biao HUANG. Preparation of Biomass-derived Fe-N-C Porous Carbon Material and Its Catalytic Reduction of Nitrobenzene[J]. Chemistry and Industry of Forest Products, 2022, 42(2): 63-70.
Table 3
Specific surface area and pore structure parameters of Fe-N-C"
样品 sample | SBET/(m2·g-1) | 平均孔径/nm average pore size | Vtot/ (cm3·g-1) | Vmes/ (cm3·g-1) | Vmic/ (cm3·g-1) | 微孔率/% micropore rate |
Fe-N-C-700 | 295 | 2.13 | 0.157 | 0.031 | 0.126 | 80.3 |
Fe-N-C-800 | 529 | 2.54 | 0.337 | 0.126 | 0.211 | 62.6 |
Fe-N-C-900 | 483 | 2.27 | 0.274 | 0.082 | 0.192 | 70.0 |
Fe-N-C-1000 | 512 | 2.18 | 0.280 | 0.099 | 0.181 | 64.6 |
Table 4
Conversion and selectivity of nitrobenzene catalytic reduction under different conditions"
序号 No. | 催化剂 catalyst | 温度/℃ temperature | 时间/h time | 转化率/% conversion rate | 选择性/% selectivity |
1 | Fe-N-C-700 | 55 | 2.5 | 68.1 | >99 |
2 | Fe-N-C-800 | 55 | 2.5 | 87.1 | >99 |
3 | Fe-N-C-900 | 55 | 2.5 | 99.9 | >99 |
4 | Fe-N-C-1000 | 55 | 2.5 | 86.3 | >99 |
5 | C-900 | 55 | 2.5 | 4.8 | >99 |
6 | N-C-900 | 55 | 2.5 | 2.9 | >99 |
7 | Fe-C-900 | 55 | 2.5 | 5.8 | >99 |
8 | Fe-N-C-900 | 25 | 2.5 | 32.8 | >99 |
9 | Fe-N-C-900 | 35 | 2.5 | 68.9 | >99 |
Table 5
Catalytic reduction of nitroaromatics with different substituents by Fe-N-C-900"
序号 No. | 底物 substrate | 产物 product | 时间/h time | 转化率/% conversion rate | 选择性/% selectivity |
1 | 对硝基甲苯1-methyl-4-nitro-benzene | 对氨基甲苯p-tolylamine | 2.5 | >99.0 | >99 |
2 | 3-硝基邻二甲苯1, 2-dimethyl-3-nitro-benzene | 3-氨基邻二甲苯1, 2-dimethyl-3-phenylamine | 2.5 | >99.0 | >99 |
3 | 4-硝基苯胺4-nitro-phenylamine | 4-氨基苯胺4-nitro-phenylamine | 2.5 | >99.0 | >99 |
4 | 4-硝基苯酚4-nitro-phenol | 4-氨基苯酚4-amino-phenol | 2.5 | 97.5 | >99 |
5 | 4-硝基氯苯1-chloro-4-nitro-benzene | 4-氨基氯苯4-chloro-phenylamine | 2.5 | 63.2 | >99 |
4 | 97.3 | >99 | |||
6 | 4-硝基碘苯1-iodo-4-nitro-benzene | 4-氨基碘苯4-iodo-phenylamine | 2.5 | 60.8 | >99 |
4 | 98.5 | >99 |
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