5-氯甲基糠醛水解制备5-羟甲基糠醛的工艺优化及反应动力学研究

doi:10.3969/j.issn.0253-2417.2022.03.009

Abstract

Abstract:

The hydrolysis of 5-chloromethyl furfural(CMF) in pure water or water/acetone system to 5-hydroxymethyl furfural(HMF) was studied. The effects of hydrolysis reaction conditions(such as solvent system, alkali neutralizer, temperature and CMF addition amount) on the hydrolysis of CMF were investigated, and the kinetics of the hydrolysis reaction was analyzed. The results showed that the water/acetone system is helpful to reduce the side reaction of HMF, and the addition of sodium disulfite(Na₂S₂O₄) could further prevent the generation of humus. The optimal hydrolysis conditions are as follows: 1 g CMF was added with 0.35 g CaCO₃ in a mixture of 10 mL water/acetone with volume ratio of 1∶4, and incubated at 353.15 K for 28 min. Under these conditions, the CMF conversion rate was 97%, the yield of HMF was 85%, and the yield of by-product levulinic acid(LA) was 6%. The separation rate of HMF increased from 50% to 86% with the addition of Na₂S₂O₄. The kinetic study results showed that the activation energy of CMF hydrolysis was 12.3 kJ/mol and the hydrolysis rate constant k₁=5.56exp(-1.23×10⁴/RT) in water/acetone system.

Key words: biomass, 5-chloromethylfurfural, hydrolysis, reaction kinetics, separation and purification

CLC Number:

TQ35

Shuai WANG, Xing TANG, Yong SUN, Xianhai ZENG, Lu LIN. Optimization and Kinetics of Hydrolysis of 5-Chloromethylfurfural to 5-Hydroxymethylfurfural[J]. Chemistry and Industry of Forest Products, 2022, 42(3): 65-74.

Figures/Tables 9

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Table 1

References 24

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温度/K temperature	速率常数(k₁)/min^-1 rate constant	速率常数(k₂)/min^-1 rate constant
333.15	0.0672	0.0058
353.15	0.0839	0.0088
373.15	0.1081	0.0141

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Optimization and Kinetics of Hydrolysis of 5-Chloromethylfurfural to 5-Hydroxymethylfurfural

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