富酸油脂无催化快速酯化降酸工艺研究

doi:10.3969/j.issn.0253-2417.2022.03.015

Abstract

Abstract:

Using acid-rich oil as raw materials, the acid value was reduced by esterification with glycerol in the absence of a catalyst. The optimum conditions were obtained as follows: the mole ratio of glycerol to fatty acid was 1.2∶1, the reaction temperature was 240 ℃, and the acid value could be reduced to below 1.66 mg/g for 2 h. The results showed that this process could not only achieve the purpose of fast deacidification within two hours, but also directly produce biodiesel through transesterification. FT-IR analysis confirmed the disappearance of carboxylic acid and the formation of triglyceride. The results of GPC analysis showed that the composition of the oil after deacidification was 21.93% triglyceride, 37.93% diglyceride and 40.14% diglyceride. And the obtained biodiesel was relatively pure fatty acid methyl esters. In addition, the improvement of the process also directly completed the "process roadmap of biodiesel production from oils with different acid values", which had a certain reference value for the development of biodiesel industry.

Key words: oil, fatty acid, transesterification, biodiesel, fatty acid methyl ester

CLC Number:

TQ35
TQ645.8

Ke LI, Jie CHEN, Xiao'an NIE, Jianchun JIANG. Fast Deacidification of Acid-rich Oil by Esterification Without Catalysis[J]. Chemistry and Industry of Forest Products, 2022, 42(3): 111-116.

Figures/Tables 6

References 17

1	VASUDEVAN P T , BRIGGS M . Biodiesel production: Current state of the art and challenges[J]. Journal of Industrial Microbiol & Biotechnology, 2008, 35 (5): 421- 430.
2	忻耀年, SONDERMANNB, EMERSLEBENB. 生物柴油的生产和应用[J]. 中国油脂, 2001, 26 (5): 72- 77.
	XIN Y N , SONDERMANN B , EMERSLEBEN B . Production and application of bio diesel fuel[J]. China Oils and Fats, 2001, 26 (5): 72- 77.
3	袁银南, 江清阳, 孙平, 等. 柴油机燃用生物柴油的排放特性研究[J]. 内燃机学报, 2003, 21 (6): 423- 427. doi: 10.3321/j.issn:1000-0909.2003.06.008
	YUAN Y N , JIANG Q Y , SUN P , et al. Study of emission characteristics of diesel engine fueled with biodiesel[J]. Transactions of Csice, 2003, 21 (6): 423- 427. doi: 10.3321/j.issn:1000-0909.2003.06.008
4	张恬, 袁银南. 生物柴油的环境效益与社会经济效益[J]. 能源环境保护, 2005, 19 (2): 16- 19.
	ZHANG T , YUAN Y N . Environmentai and economic benefit of biodiesel[J]. Energy Environmental Protection, 2005, 19 (2): 16- 19.
5	XUE J , GRIFT T E , HANSEN A C . Effect of biodiesel on engine performances and emissions[J]. Renewable & Sustainable Energy Reviews, 2011, 15 (2): 1098- 1116.
6	ATADASHI I M , AROUA M K , AZIZ A A . High quality biodiesel and its diesel engine application: A review[J]. Renewable & Sustainable Energy Reviews, 2010, 14 (7): 1999- 2008.
7	AGARWAL A K , BIJWE J , DAS L M . Wear assessment in a biodiesel fueled compression ignition engine[J]. Journal of Engineering for Gas Turbines & Power, 2003, 125 (3): 820- 826.
8	AGARWAL A K . Biofuels(alcohols and biodiesel) applications as fuels for internal combustion engines[J]. Progress in Energy & Combustion Science, 2007, 33 (3): 233- 271.
9	AYOUB M , ABDULLAH A Z . Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry[J]. Renewable and Sustainable Energy Reviews, 2012, 16 (5): 2671- 2686. doi: 10.1016/j.rser.2012.01.054
10	BABU P S , MAMILLA V R . Significance of biodiesel use as I.C.engine fuels[J]. International Journal of Advanced Engineering Research and Studies, 2012, 1 (2): 40- 43.
11	赵宗保, 华艳艳, 刘波. 中国如何突破生物柴油产业的原料瓶颈[J]. 中国生物工程杂志, 2005, (11): 1- 6.
	ZHAO Z B , HUA Y Y , LIU B . How to secure triacylglycerol supply for Chinese biodiesel industry[J]. Progress in Biotechnology, 2005, (11): 1- 6.
12	DEMIRBAS A . Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification[J]. Energy Conversion & Management, 2009, 50 (4): 923- 927.
13	ZHENG S , KATES M , DUBÉ M A , et al. Acid-catalyzed production of biodiesel from waste frying oil[J]. Biomass and Bioenergy, 2006, 30 (3): 267- 272. doi: 10.1016/j.biombioe.2005.10.004
14	张勇. 利用地沟油制备生物柴油[J]. 中国油脂, 2008, 33 (11): 48- 50.
	ZHANG Y . Preparation of biodiesel with hogwash oil[J]. China Oils and Fats, 2008, 33 (11): 48- 50.
15	何寿林, 黄奠坤, 张红丽. 多不饱和脂肪酸甘油酯的合成工艺研究[J]. 武汉理工大学学报, 2012, 34 (3): 34- 37.
	HE S L , HUANG D K , ZHANG H L . Research on synthesis technology of PUFAs glyceride[J]. Journal of Wuhan University of Technology, 2012, 34 (3): 34- 37.
16	刘朋, 蒋剑春, 陈水根, 等. 高酸值废弃油脂甘油酯化脱酸研究[J]. 应用化工, 2016, 45 (7): 1242- 1245.
	LIU P , JIANG J C , CHEN S G , et al. Deacidification of high acid value waste oil by esterification with glycerol[J]. Applied Chemical Industry, 2016, 45 (7): 1242- 1245.
17	李科, 李翔宇, 蒋剑春, 等. 质量法——一种计算油脂甲酯化转化率的新方法研究[J]. 林产化学与工业, 2011, 31 (2): 43- 47.
	LI K , LI X Y , JIANG J C , et al. A new approach to calculate conversion rate of methyl ester ification of fatty oil by mass-change method[J]. Chemistry and Industry of Forest Products, 2011, 31 (2): 43- 47.

[1]	Lu LU, Chengjie SHU, Ling GE, Jiechen PAN, Kai ZHU, Baojun SHI. The Antibacterial Activity, Antioxidant and Antityrosinase Activities of Cinnamon Essential Oil and Cinnamaldehyde [J]. Chemistry and Industry of Forest Products, 2022, 42(3): 105-110.
[2]	Qin WANG, Hongmei WANG, Aihua ZHANG, Zhihong XIAO, Changzhu LI. KNO₃-Loaded Mesoporous Carbon Catalyzed Transesterification Reaction of Cornus wilsoniana Oil [J]. Chemistry and Industry of Forest Products, 2021, 41(6): 83-89.
[3]	Qiuhao WU, Yunpu WANG, Shumei ZHANG, Yuan ZENG, Yuhuan LIU, Roger RUAN. Research Progress on Microwave-assisted Catalytic Pyrolysis of Waste Oil for Hydrocarbon-rich Bio-oil [J]. Chemistry and Industry of Forest Products, 2021, 41(6): 127-138.
[4]	Huiyang BIAN, Yanqiao FU, Lidong CHEN, Weisheng YANG, Shuangquan YAO, Hongqi DAI. Preparation and Characterization of Hydrophobic and Lipophilic Lignocellulosic Nanofibrils-based Aerogel [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 45-50.
[5]	Xian CHENG, Liangwu BI, Shengnan LI, Yuxiang CHEN, Zhendong ZHAO, Kailin MO. Effects of Biological Pretreatment on Constituents, Oil Cells Morphology and Endophytic Microbial Communities of Cinnamomum longepaniculatum [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 51-57.
[6]	Huazheng CHEN, Kai ZHU. Antibacterial and Antioxidant Activities of Two Citrus Essential Oils and Their Main Components [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 17-22.
[7]	Jiechen PAN, Yichuan TANG, Chengjie SHU, Baojun SHI, Kai ZHU, Wei LI. High Efficient Separation of Cedrol from Chinese Fir Essential Oil [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 29-34.
[8]	Guoliang LI, Xiangping LIU. Preparation and Slow-release Properties of Cinnamomum cassia Leaves Essential Oil/β-Cyclodextrin Microcapsules [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 35-41.
[9]	Shujie HAO, Meng ZHANG, Lihong HU, Caiying BO, Qi ZHAO, Yonghong ZHOU. Preparation and Performance of a Bio-based Self-healing Material [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 85-91.
[10]	Hongxia CHEN, Hao ZHOU, Jianzhong YE, Ran TAO, Wenjun LI, Chengzhang WANG. Matrix Solid-phase Dispersion Combined with GC-MS for Determination of Chemical Constituents of Essential Oil in Agarwood [J]. Chemistry and Industry of Forest Products, 2021, 41(3): 47-54.
[11]	Le TONG, Le ZHANG, Hui PAN, Huimin ZHU, Junfeng FENG. Research Progress of Hydrodeoxygenation Catalysts for Bio-oil Model Compounds [J]. Chemistry and Industry of Forest Products, 2021, 41(2): 130-140.
[12]	Xian CHENG, Liangwu BI, Shengnan LI, Yuxiang CHEN, Zhendong ZHAO, Kailin MO. Oil Cell Morphology, Essential Oil Constituents and Antioxidant Activity of Cinnamomum longepaniculatum Leaves Harvested in Spring and Autumn [J]. Chemistry and Industry of Forest Products, 2021, 41(1): 38-44.
[13]	Hao ZHOU, Xingying XUE, Hongxia CHEN, Jianzhong YE, Chengzhang WANG. Preparation of Nanoemulsion of Lacquer Seed Oil and Its Anti-oxidation and Anti-UV Activity [J]. Chemistry and Industry of Forest Products, 2021, 41(1): 45-52.
[14]	Chen CHENG, Hongyan SI, Zongde WANG, Shengliang LIAO, Chenyang ZOU, Peng WANG. Preparation Conditions and Properties of O/W Type Litsea cubeba Oil Microemulsion [J]. Chemistry and Industry of Forest Products, 2021, 41(1): 67-76.
[15]	Sansan BAO, Xiqing WANG, Yuchun YANG, Xiaodan WU, Chunjian ZHAO, Yujie FU. Enrichment and Purification Technology of Pinolenic Acid from Pinus koraiensis Seed Oil [J]. Chemistry and Industry of Forest Products, 2020, 40(6): 23-29.

Fast Deacidification of Acid-rich Oil by Esterification Without Catalysis

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 6

References 17

Related Articles 15

Recommended Articles

Metrics

Comments