乙酰丙酸酯催化合成研究进展

doi:10.3969/j.issn.0253-2417.2022.03.018

Abstract

Abstract:

In recent years, levulinic acid has been considered as a key biobased platform compound and attracted wide attention, which can be utilized in the synthesis of many high value-added chemicals. Among them, levulinates, as a class of important chemical products, can be used in alternative fuels, edible spices, plasticizers and other fields, especially as alternative fuels, which provides a feasible reference scheme for sustainable development. In this paper, the recent research progress on the catalytic synthesis of levulinates in the field of biomass conversion was reviewed. The reaction performances and related mechanisms were introduced involving in several approaches, such as the esterification of levulinic acid, the alcoholysis of furfuryl alcohol, the conversion of monosaccharides and cellulosic materials, respectively. The synthesis of levulinates was summarized and prospected.

Key words: levulinate ester, esterification, furfuryl alcohol, monosaccharide, cellulose

CLC Number:

TQ35

Lei LI, Minchao WANG, Jiao MA, Zhanwei XU, Yajing ZHANG, Songyan JIA. Recent Progresses on the Catalytic Synthesis of Levulinate Esters[J]. Chemistry and Industry of Forest Products, 2022, 42(3): 135-146.

Figures/Tables 7

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Table 1

References 72

1	马隆龙, 唐志华, 汪丛伟, 等. 生物质能研究现状及未来发展策略[J]. 中国科学院院刊, 2019, 34 (4): 434- 442.
	MA L L , TANG Z H , WANG C W , et al. Research status and future development strategy of biomass energy[J]. Bulletin of the Chinese Academy of Sciences, 2019, 34 (4): 434- 442.
2	ADITIYA H B , MAHLIA T M I , CHONG W T , et al. Second generation bioethanol production: A critical review[J]. Renewable and Sustainable Energy Reviews, 2016, 66, 631- 653. doi: 10.1016/j.rser.2016.07.015
3	ADEN A, BOZELL J, HOLLADAY J, et al. Top value added chemicals from biomass volume Ⅰ: Results of screening for potential candidates from sugars and synthesis gas[R]. Washington DC: U.S. Department of Energy, 2004.
4	朱仕林, 李静丹, 姜小祥, 等. 5-羟甲基糠醛与乙酰丙酸制备生物基化学品的研究进展[J]. 生物质化学工程, 2016, 50 (4): 53- 59. doi: 10.3969/j.issn.1673-5854.2016.04.010
	ZHU S L , LI J D , JIANG X X , et al. Process of conversion of 5-hydroxymethylfurfural and levulinic acid to biomass-based chemicals[J]. Biomass Chemical Engineering, 2016, 50 (4): 53- 59. doi: 10.3969/j.issn.1673-5854.2016.04.010
5	DUTTA S , YU I K M , TSANG D C W , et al. Green synthesis of gamma-valerolactone(GVL) through hydrogenation of biomass-derived levulinic acid using non-noble metal catalysts: A critical review[J]. Chemical Engineering Journal, 2019, 372, 992- 1006. doi: 10.1016/j.cej.2019.04.199
6	杨佳鑫, 司传领, 刘坤, 等. 木质纤维生物质制备乙酰丙酸及其应用综述[J]. 林业工程学报, 2020, 5 (5): 21- 27.
	YANG J X , SI C L , LIU K , et al. Production of levulinic acid from lignocellulosic biomass and application[J]. Journal of Forestry Engineering, 2020, 5 (5): 21- 27.
7	王子华, 常春, 李攀, 等. 生物质基乙酰丙酸及乙酰丙酸酯的研究进展[J]. 高校化学工程学报, 2020, 34 (2): 290- 300. doi: 10.3969/j.issn.1003-9015.2020.02.002
	WANG Z H , CHANG C , LI P , et al. Research progress of biomass based levulinic acid and levulinate[J]. Journal of Chemical Engineering of Chinese Universities, 2020, 34 (2): 290- 300. doi: 10.3969/j.issn.1003-9015.2020.02.002
8	YAN L , YAO Q , FU Y . Conversion of levulinic acid and alkyl levulinates into biofuels and high-value chemicals[J]. Green Chemistry, 2017, 19 (23): 5527- 5547. doi: 10.1039/C7GC02503C
9	THOMAS F , DOOLEY S , LEAHY J J . Reaction pathway analysis of ethyl levulinate and 5-ethoxymethylfurfural from D-fructose acid hydrolysis in ethanol[J]. Energy & Fuels, 2015, 29, 7554- 7565.
10	JIA S Y , MA J , WANG D P , et al. Fast and efficient upgrading of levulinic acid into long-chain alkyl levulinate fuel additives with a tungsten salt catalyst at low temperature[J]. Sustainable Energy & Fuels, 2020, 4, 2018- 2025.
11	CHRISTENSEN E , WILLIAMS A , PAUL S , et al. Properties and performance of levulinate esters as diesel blend components[J]. Energy & Fuels, 2011, 25, 5422- 5428.
12	MUKHERJEE A , DUMONT M , RAGHAVAN V . Review: Sustainable production of hydroxymethylfurfural and levulinic acid.Challenges and opportunities[J]. Biomass and Bioenergy, 2015, 72, 143- 183. doi: 10.1016/j.biombioe.2014.11.007
13	库松, 谭雪松, 李润东, 等. 两相水合熔盐体系中杂交狼尾草水解制备糠醛和乙酰丙酸[J]. 生物质化学工程, 2021, 55 (3): 29- 34. doi: 10.3969/j.issn.1673-5854.2021.03.005
	KU S , TAN X S , LI R D , et al. Preparation of furfural and levulinic acid from hybrid pennisetum hydrolysis in biphasic hydrated molten salt system[J]. Biomass Chemical Engineering, 2021, 55 (3): 29- 34. doi: 10.3969/j.issn.1673-5854.2021.03.005
14	龚晨, 曹雪娟, 唐兴, 等. 减压蒸馏法从生物质水解液中分离提纯乙酰丙酸[J]. 生物质化学工程, 2020, 54 (1): 9- 15. doi: 10.3969/j.issn.1673-5854.2020.01.002
	GONG C , CAO X J , TANG X , et al. Separation and purification of levulinic acid from hydrolysate of biomass by using compression vacuum distillation[J]. Biomass Chemical Engineering, 2020, 54 (1): 9- 15. doi: 10.3969/j.issn.1673-5854.2020.01.002
15	BART H J , REIDETSCHLÄGER J , SCHATKA K , et al. Kinetics of esterification of levulinic acid with n-butanol by homogeneous catalysis[J]. Industrial & Engineering Chemistry Research, 1994, 33, 21- 25.
16	HUANG Y B , YANG T , CAI B , et al. Highly efficient metal salt catalyst for the esterification of biomass derived levulinic acid under microwave irradiation[J]. RSC Advances, 2016, 6 (3): 2106- 2111. doi: 10.1039/C5RA24305J
17	MARTINS F P , RODRIGUES F A , SILVA M J . Fe₂(SO₄)₃-catalyzed levulinic acid esterifification: Production of fuel bioadditives[J]. Energies, 2018, 11 (5): 1- 11.
18	VILANCULO C B , LELES L C A , SILVA M J . H₄SiW₁₂O₄₀-catalyzed levulinic acid esterification at room temperature for production of fuel bioadditives[J]. Waste and Biomass Valorization, 2020, 11, 1895- 1904. doi: 10.1007/s12649-018-00549-x
19	KALGHATGI S G , BHANAGE B M . Green syntheses of levulinate esters using ionic liquid 1-methylimidazolium hydrogen sulphate[MIM][HSO₄] in solvent free system[J]. Journal of Molecular Liquids, 2019, 281, 70- 80. doi: 10.1016/j.molliq.2019.02.053
20	KONG X J , WU S X , LI X L , et al. Efficient conversion of levulinic acid to ethyl levulinate over a silicotungstic-acid-modified commercially silica-gel sphere catalyst[J]. Energy & Fuels, 2016, 30, 6500- 6504.
21	DESIDERY L , YUSUBOV M S , ZHUIYKOV S , et al. Fully-sulfonated hydrated UiO66 as efficient catalyst for ethyl levulinate production by esterification[J]. Catalysis Communications, 2018, 117, 33- 37. doi: 10.1016/j.catcom.2018.08.020
22	LIU C , ZHANG K , LIU Y , et al. Esterification of levulinic acid into ethyl levulinate catalyzed by sulfonted bagasse-carbonized solid acid[J]. BioResources, 2019, 14 (1): 2186- 2196.
23	ZHAO W H , DING H , ZHU J , et al. Esterification of levulinic acid into n-butyl levulinate catalyzed by sulfonic acid-functionalized lignin-montmorillonite complex[J]. Journal of Bioresources and Bioproducts, 2020, 5, 291- 299. doi: 10.1016/j.jobab.2020.10.008
24	ZHOU S L , JIANG D B , LIU X X , et al. Titanate nanotubes-bonded organosulfonic acid as solid acid catalyst for synthesis of butyl levulinate[J]. RSC Advances, 2018, 8 (7): 3657- 3662. doi: 10.1039/C7RA12994G
25	CHERMAHINI A N , NAZERI M . Esterification of the levulinic acid with n-butyl and isobutyl alcohols over aluminum-containing MCM-41[J]. Fuel Processing Technology, 2017, 167, 442- 450. doi: 10.1016/j.fuproc.2017.07.034
26	BADGUJAR K C , BHANAGE B M . Thermo-chemical energy assessment for production of energy-rich fuel additive compounds by using levulinic acid and immobilized lipase[J]. Fuel Prcoessing Technology, 2015, 138, 139- 146. doi: 10.1016/j.fuproc.2015.05.015
27	ZHOU L Y , HE Y , MA L , et al. Conversion of levulinic acid into alkyl levulinates: Using lipase immobilized on meso-molding three-dimensional macroporous organosilica as catalyst[J]. Bioresource Technology, 2018, 247, 568- 575. doi: 10.1016/j.biortech.2017.08.134
28	DI X H , ZHANG Y , FU J Y , et al. Biocatalytic upgrading of levulinic acid to methyl levulinate in green solvents[J]. Process Biochemistry, 2019, 81, 33- 38. doi: 10.1016/j.procbio.2019.03.024
29	徐艳丽, 常春, 白净, 等. 脂肪酶催化制备生物基化学品乙酰丙酸乙酯的工艺优化[J]. 农业工程学报, 2019, 35 (10): 227- 233. doi: 10.11975/j.issn.1002-6819.2019.10.029
	XU Y L , CHANG C , BAI J , et al. Optimization of preparation of bio-based ethyl levulinate catalysed by lipase[J]. Transactions of the Chinese Society of Agricultural Engineering, 2019, 35 (10): 227- 233. doi: 10.11975/j.issn.1002-6819.2019.10.029
30	BERTARIONE S , BONINO F , CESANO F , et al. Micro-FTIR and micro-Raman studies of a carbon film prepared from furfuryl alcohol polymerization[J]. The Journal of Physical Chemistry B, 2009, 113, 10571- 10574. doi: 10.1021/jp9050534
31	CHADA R R , KOPPADI K S , ENUMULA S S , et al. Continuous synthesis of fuel additives alkyl levulinates via alcoholysis of furfuryl alcohol over silica supported metal oxides[J]. Catalysis Letters, 2018, 148, 1731- 1738. doi: 10.1007/s10562-018-2371-y
32	WANG Y T, ZHAO D Y, TRIANTAFYLLIDIS K S, et al. Microwave-assisted catalytic upgrading of bio-based furfuryl alcohol to alkyl levulinate over commercial non-metal activated carbon[J/OL]. Molecular Catalysis, 2020, 480: 1-7[2021-01-10]. https://doi.org/10.1016/j.mcat.2019.110630.
33	ZHANG Z, YUAN H, WANG Y J, et al. Preparation and characterisation of ordered mesoporous SO₄^2-/Al₂O₃ and its catalytic activity in the conversion of furfuryl alcohol to ethyl levulinate[J/OL]. Journal of Solid State Chemistry, 2019, 280: 1-10[2021-01-10]. https://doi.org/10.1016/j.jssc.2019.120991.
34	GUO Q Q , YANG F , LIU X H , et al. Low-cost synthesis of nanoaggregate SAPO-34 and its application in the catalytic alcoholysis of furfuryl alcohol[J]. Chinese Journal of Catalysis, 2020, 41, 1772- 1781. doi: 10.1016/S1872-2067(20)63604-X
35	ZHANG Z H , DONG K , ZHAO Z B . Efficient conversion of furfuryl alcohol into alkyl levulinates catalyzed by an organic-inorganic hybrid solid acid catalyst[J]. ChemSusChem, 2011, 4 (1): 112- 118. doi: 10.1002/cssc.201000231
36	TIWARI M S, DICKS J S, KEOGH J, et al. Direct conversion of furfuryl alcohol to butyl levulinate using tin exchanged tungstophosphoric acid catalysts[J/OL]. Molecular Catalysis, 2020, 488: 1-9[2021-01-10]. https://doi.org/10.1016/j.mcat.2020.110918.
37	YANG J F , AO Z F , WU H , et al. Waste paper-derived magnetic carbon composite: A novel ecofriendly solid acid for the synthesis of n-butyl levulinate from furfuryl alcohol[J]. Renewable Energy, 2020, 146, 477- 483. doi: 10.1016/j.renene.2019.06.167
38	GUPTA S S R , KANTAM M L . Catalytic conversion of furfuryl alcohol or levulinic acid into alkyl levulinates using a sulfonic acid-functionalized hafnium-based MOF[J]. Catalysis Communications, 2019, 124, 62- 66. doi: 10.1016/j.catcom.2019.03.003
39	常春, 邓琳, 戚小各, 等. 固体催化剂在生物质合成乙酰丙酸和乙酰丙酸酯中的应用研究进展[J]. 林产化学与工业, 2017, 37 (2): 11- 21.
	CHANG C , DENG L , QI X G , et al. Progress of application of solid catalysts in levulinic acid and alkyl levulinates produced from biomass[J]. Chemistry and Industry of Forest Products, 2017, 37 (2): 11- 21.
40	XU G Z , CHEN B L , ZHENG Z B , et al. One-pot ethanolysis of carbohydrates to promising biofuels: 5-Ethoxymethylfurfural and ethyl levulinate[J]. Asia-Pacific Journal of Chemical Engineering, 2017, 12 (4): 527- 535. doi: 10.1002/apj.2095
41	CHEN X L , ZHANG Y X , HOU T , et al. Catalysis performance comparison of a Brønsted acid H₂SO₄ and a Lewis acid Al₂(SO₄)₃ in methyl levulinate production from biomass carbohydrates[J]. Journal of Energy Chemistry, 2018, 27 (2): 552- 558. doi: 10.1016/j.jechem.2017.11.005
42	ZHAO S Q , XU G Z , CHANG C , et al. Direct conversion of carbohydrates into ethyl levulinate with potassium phosphotungstate as an efficient catalyst[J]. Catalysts, 2015, 5, 1897- 1910. doi: 10.3390/catal5041897
43	LIU Y , LIU C L , WU H Z , et al. An efficient catalyst for the conversion of fructose into methyl levulinate[J]. Catalysis Letters, 2013, 143, 1346- 1353. doi: 10.1007/s10562-013-1094-3
44	LIU R L , CHEN J Z , HUANG X , et al. Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials[J]. Green Chemistry, 2013, 15 (10): 2895- 2903. doi: 10.1039/c3gc41139g
45	BABAEI Z, ESMAEILABAD R X, ORASH N, et al. Sulfonated CMK-3: An effective catalyst for the glucose conversion to butyl levulinate as the fuel additive[J/OL]. Biomass Conversion and Biorefinery, 2020, 158: 1-11[2021-01-10]. https://doi.org/10.1007/s13399-020-01072-7.
46	YANG X M, YANG J R, GAO B B, et al. Conversion of glucose to methyl levulinate over Sn-Al-β zeolite: Role of Sn and mesoporosity[J/OL]. Catalysis Coummunications, 2019, 130: 1-4[2021-01-10]. https://doi.org/10.1016/j.catcom.2019.105783.
47	XU G Z , CHANG C , ZHU W N , et al. A comparative study on direct production of ethyl levulinate from glucose in ethanol media catalyzed by different acid catalysts[J]. Chemical Papers, 2013, 67, 1355- 1363.
48	CHANG C , XU G Z , ZHU W N , et al. One-pot production of a liquid biofuel candidate: Ethyl levulinate from glucose and furfural residues using a combination of extremely low sulfuric acid and zeolite USY[J]. Fuel, 2015, 140, 365- 370. doi: 10.1016/j.fuel.2014.09.102
49	NJAGI E C , GENUINO H C , KUO C , et al. High-yield selective conversion of carbohydrates to methyl levulinate using mesoporous sulfated titania-based catalysts[J]. Microprous and Mesoporous Materials, 2015, 202, 68- 72. doi: 10.1016/j.micromeso.2014.09.044
50	刘娣, 林鹿, 曾珊珊, 等. 固体酸SO₄^2-/SnO₂催化转化葡萄糖制备乙酰丙酸丁酯[J]. 林产化学与工业, 2013, 33 (2): 66- 70. doi: 10.3969/j.issn.0253-2417.2013.02.011
	LIU D , LIN L , ZENG S S , et al. Conversion of glucose into butyl levulinate over solid acid SO₄^2-/SnO₂ catalyst[J]. Chemistry and Industry of Forest Products, 2013, 33 (2): 66- 70. doi: 10.3969/j.issn.0253-2417.2013.02.011
51	PAN H , LIU X F , ZHANG H , et al. Multi-SO₃H functionalized mesoporous polymeric acid catalyst for biodiesel production and fructose-to-biodiesel additive conversion[J]. Renewable Energy, 2017, 107, 245- 252. doi: 10.1016/j.renene.2017.02.009
52	LIU J , WANG X Q , YANG B B , et al. Highly efficient conversion of glucose into methyl levulinate catalyzed by tin-exchanged montmorillonite[J]. Renewable Energy, 2018, 120, 231- 240. doi: 10.1016/j.renene.2017.12.104
53	MULIK N, NIPHADKAR P, BOKADE V. Synergetic combination of H₂Zr₁PW₁₂O₄₀ and Sn-Beta as potential solid acid catalyst for direct one-step transformation of glucose to ethyl levulinate, a biofuel additive[J/OL]. Environmental Progress & Sustainable Energy, 2019, 38(5): 1-6[2021-01-10]. https://doi.org/10.1002/ep.13173.
54	BABAEI Z , CHERMAHINI A N , DINARI M . Alumina-coated mesoporous silica SBA-15 as a solid catalyst for catalytic conversion of fructose into liquid biofuel candidate ethyl levulinate[J]. Chemical Engineering Journal, 2018, 352, 45- 52. doi: 10.1016/j.cej.2018.07.004
55	STERN A L . Contributions to the chemistry of cellulose. Ⅰ: Cellulose-sulphuric acid, and the products of its hydrolysis[J]. Journal of the Chemical Society, Transactions, 1895, 67, 74- 90. doi: 10.1039/CT8956700074
56	GURGEL L V A , MARABEZI K , ZANBOM M D , et al. Dilute acid hydrolysis of sugar cane bagasse at high temperatures: A kinetic study of cellulose saccharification and glucose decomposition.Part Ⅰ: Sulfuric acid as the ctalyst[J]. Industrial & Engineering Chemistry Research, 2012, 51, 1173- 1185.
57	KASSAYE S , PANT K K , JAIN S . Synergistic effect of ionic liquid and dilute sulphuric acid in the hydrolysis of microcrystalline cellulose[J]. Fuel Processing Technology, 2016, 148, 289- 294. doi: 10.1016/j.fuproc.2015.12.032
58	WU X Y , FU J , LU X Y . One-pot preparation of methyl levulinate from catalytic alcoholysis of cellulose in near-critical methanol[J]. Carbohydrate Resrarch, 2012, 358, 37- 39. doi: 10.1016/j.carres.2012.07.002
59	LI H , PENG L C , LIN L , et al. Synthesis, isolation and characterization of methyl levulinate from cellulose catalyzed by extremely low concentration acid[J]. Journal of Energy Chemistry, 2013, 22 (6): 895- 901. doi: 10.1016/S2095-4956(14)60269-2
60	贺小亮, 蒋剑春, 冯君锋, 等. 微晶纤维素复合溶剂醇解制备乙酰丙酸甲酯的研究[J]. 现代化工, 2014, 34 (7): 89- 93.
	HE X L , JIANG J C , FENG J F , et al. Conversion of microcrystalline cellulose into methyl levulinate in mixed solvents[J]. Modern Chemical Industry, 2014, 34 (7): 89- 93.
61	TOMINAGA K , MORI A , FUKUSHIMA Y , et al. Mixed-acid systems for the catalytic synthesis of methyl levulinate from cellulose[J]. Green Chemistry, 2011, 13 (4): 810- 812. doi: 10.1039/c0gc00715c
62	DAI J , PENG L C , LI H . Intensified ethyl levulinate production from cellulose using a combination of low loading H₂SO₄ and Al(OTf)₃[J]. Catalysis Communications, 2018, 103, 116- 119. doi: 10.1016/j.catcom.2017.10.007
63	SONG C , LIU S , PENG X , et al. Catalytic conversion of carbohydrates to levulinate ester over heteropolyanion-based ionic liquids[J]. ChemSusChem, 2016, 9 (23): 3307- 3316. doi: 10.1002/cssc.201601080
64	HUANG Y B , YANG T , LIN Y T , et al. Facile and high-yield synthesis of methyl levulinate from cellulose[J]. Green Chemistry, 2018, 20 (6): 1323- 1334. doi: 10.1039/C7GC02883K
65	HUANG Y B , FU Y . Hydrolysis of cellulose to glucose by solid acid catalysts[J]. Green Chemistry, 2013, 15 (5): 1095- 1111. doi: 10.1039/c3gc40136g
66	RATABOUL F , ESSAYEM N . Cellulose reactivity in supercritical methanol in the presence of solid acid catalysts: Direct synthesis of methyl-levulinate[J]. Industrial & Engineering Chemistry Research, 2011, 50, 799- 805.
67	ZHANG X Y , ZHANG H Z , LI Y M , et al. First triple-functional polyoxometalate Cs_10.6[H_2.4GeNb₁₃O₄₁] for highly selective production of methyl levulinate directly from cellulose[J]. Cellulose, 2018, 25, 6405- 6419. doi: 10.1007/s10570-018-2037-3
68	ZHOU S Q , YANG X M , ZHANG Y L , et al. Efficient conversion of cellulose to methyl levulinate over heteropoly acid promoted by Sn-Beta zeolite[J]. Cellulose, 2019, 26, 9135- 9147. doi: 10.1007/s10570-019-02743-z
69	GUAN Q , LEI T Z , WANG Z W , et al. Preparation of ethyl levulinate from wheat straw catalysed by sulfonate ionic liquid[J]. Industrial Crops & Products, 2018, 113, 150- 156.
70	关倩, 蒋剑春, 徐俊明, 等. 小麦秸秆加压液化制备乙酰丙酸乙酯[J]. 林产化学与工业, 2016, 36 (5): 127- 132. doi: 10.3969/j.issn.0253-2417.2016.05.019
	GUAN Q , JIANG J C , XU J M , et al. Preparation of ethyl levulinate by pressurized liquefaction of wheat straw[J]. Chemistry and Industry of Forest Products, 2016, 36 (5): 127- 132. doi: 10.3969/j.issn.0253-2417.2016.05.019
71	CHEN Z J , MA X Y , XU L , et al. Catalytic conversion of duckweed to methyl levulinate in the presence of acidic ionic liquids[J]. Bioresource Technology, 2018, 268, 488- 495. doi: 10.1016/j.biortech.2018.08.033
72	LIU C G , FENG Q N , YANG J R , et al. Catalytic production of levulinic acid and ethyl levulinate from uniconazole-induced duckweed(Lemna minor)[J]. Bioresource Technology, 2018, 255, 50- 57. doi: 10.1016/j.biortech.2018.01.087

原料 feedstock	催化剂 catalyst	反应条件 reaction conditions	产物(收率)¹⁾ product(yield)	文献 reference
小麦秸秆wheat straw	[HSO₃-BMIM]HSO₄	200 ℃，1 h	EL(16.23%)	[69]
小麦秸秆wheat straw	H₂SO₄	190 ℃，1 h	EL(18.11%)	[70]
浮萍duckweed	[C₃H₆SO₃HPy]HSO₄	2 MPa N₂，170 ℃，5 h	ML(73.7%)，EL(59.8%)，PL(51.8%)，BL(56.9%)	[71]
浮萍duckweed	H₂SO₄	200 ℃，3 h	EL(55.2%)	[72]

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Recent Progresses on the Catalytic Synthesis of Levulinate Esters

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